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z-Ch. 24 Amines and Hetrocycles
CHM2211 Dr. Elsheimer Fall 09
26
Organic Chemistry
Undergraduate 2
11/13/2009
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Term
RCH2X -NaCN->
 Definition
RCH2CN
Term
RCH2X -1.NaCN 2.LiAlH4/H2O->
 Definition
RCH2CH2NH2
Term
RCOOH -1.SOCl2/2.NH3->
 Definition
RCONH2
Term
RCOOH -1.SOCl2/2.NH3-> -1.LiAlH4/2.H2O->
 Definition
RCH2NH2
Term
Ar-NO2 -H2/Pt catalyst->
 Definition
Ar-NH2
Term
Ar-NO2 -1.SnCl2,H3O/2.NaOH->
 Definition
Ar-NH2
Term
RCH2X -NaN3->
 Definition
RCH2N=N=N
Term
RCH2X -NaN3-> -1.LiAlH4/2.H2O->
 Definition
RNH2
Term
RC=OR' -NH3/H2 cat. or NaBH4 or NaBH3CN->
 Definition
RCH(NH2)R'
Term
RC=OCH3 -NH3/H2 Ni or NaBH4->
 Definition
RCH(NH2)CH3
Term
RC=OR' -R"NH2/H2 cat. or NaBH4 or NaBH3CN->
 Definition
RCH(NHR")R'
Term
RC=OR' -R"2NH/H2 cat. or NaBH4 or NaBH3CN->
 Definition
RCH(NR"2)R'
Term
RC=OCl + R'2NH -Pyridine->
 Definition
RC=ONR'2 + HCl
Term
RCONH2 -NaOH,Br2/H2O->
 Definition
RNH2 +CO2
Term
RCOCl -NaN3/ethanol->
 Definition
RCON3
Term
RCOCl -NaN3/ethanol-> -H2O/Heat->
 Definition
RNH2 + CO2 + N2
Term
C-CNR2 -1.CH3I/2.Ag2O,heat->
 Definition
C=C
Term
Ar-NH2 + HNO2 + H2SO4 -->
 Definition
Ar-N2(+) HSO4(-)
Term
Ar-N2 -HCl/CuCl->
 Definition
Ar-Cl
Term
Ar-N2 -HBr/CuBr->
 Definition
Ar-Br
Term
Ar-N2 -NaI->
 Definition
Ar-I
Term
Ar-N2 -KCN/CuCN->
 Definition
Ar-CN
Term
Ar-N2 -Cu2O,H2O/Cu(NO3)2->
 Definition
Ar-OH
Term
Ar-N2 -H3PO2->
 Definition
Ar-H
Term
Ar-N2 + Ar-OH -HSO4(-)->
 Definition
Ar-N=N-Ar-OH (para)
Term
Ar-N2 + Ar-NR2 -HSO4(-)->
 Definition
Ar-N=N-Ar-NR2 (para)
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