Term
| Hydration of Alkenes (Non-Markovnikov) |
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Definition
| 1. BH3/THF 2. H2O2/-OH (R-CH=CH-R)->(R-OH-CH-CH2-R) |
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Term
| Hydration of Alkenes (Markovnikov) |
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Definition
| 1. Hg(OAc)2/H2O 2. NaBH4 (R-CH=CH-R)->(R-CH2-CH-OH-R) |
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Term
| Hydroxylation of Alkenes (trans) |
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Definition
| 1. RCO3H/CH2Cl2 2. H3O+ (R-CH=CH-R)->(R-OH-CH-CH-OH-R) TRANS |
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Term
| Hydroxylation of Alkenes (cis) |
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Definition
| 1. OsO4/Pyridine 2. NaHSO3/H2O (R-CH=CH-R)->(R-OH-CH-CH-OH-R) CIS |
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
| Reduction of Aldehydes and Ketones |
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Term
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Definition
| Reduction of Aldehydes, Ketones, Esters, and Carboxylic Acids |
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Term
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Definition
RMgBr + R'C=O -> HO-C-RR'
Does not work with carboxylic acid
RMgBr + R'CO2 -> R'CO2- + MgBr+ + RH |
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Term
| Conversion of Alcohols to Alkyl Halides |
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Definition
| SOCl2/ether PBr3/ether p-TosCl/pyridine |
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Term
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Definition
| Adds Cl to 1* or 2* alcohol. Sn2 attacks opposite side of leaving group. see pg. 618 |
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Term
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Definition
| Adds Br to 1* or 2* alcohol. Sn2 attacks opposite side of leaving group. see pg. 618 |
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Term
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Definition
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Term
| Conversion of Alcohols into Esters |
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Definition
| ROH/Strong Acid, heat or 1.SOCl2/2.CH3OH (R'-C=O-OH -> R'-C=O-O-R) |
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Term
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Definition
| POCl3/Pyridine or H3O+,THF/50 C (not as good) |
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Term
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Definition
Primary alcohol -> Aldehyde -> Carboxylic Acid
Will NOT react with Tertiary alcohols |
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Term
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Definition
| Oxidation. Will convert primary alcohols to aldehydes. |
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Term
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Definition
| Oxidation. Will convert primary alcohols to carbocylic acid. |
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Term
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Definition
| (CH3)3SiCl/(CH3CH2)3N remove with H3O+ |
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Term
| Dehydrogenating an Alcohol |
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Definition
| R-OH Na+H- -> R-O- Na+ H2(gas) |
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Term
| Benzoquinones to Hydroquinone |
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Definition
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Term
| Hydroquinone to Benzoquinones |
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Definition
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Definition
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