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WW midterm 2
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81
Civil Engineering
Undergraduate 4
03/01/2011

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Term
What is yield equal to in bacterial growth?
Definition
mass bacteria generated/mass food consumed

=fs/1.42
Term
What two items does the available energy to bacteria go towards?
Definition
Energy for maintenance/upkeep and energy available for new cell growth
Term
What is the equation for calculating the energy used for new cell growth?
Definition
dGs = dGp/K^m + dGc + dGN/K

dGs = energy for cell growth
dGp = energy of converting C-source to pyruvate
dGc = energy to convert pyruvate to cells (+31.4 kJ/(mg-e-)
dGn = energy to convert N-source to NH4+
K = efficiency (typically ~60%)
m = +1 if dGp>0, -1 if dGp<0
Term
What is the equation used to determine the fractions of energy used for upkeep and for synthesis?
Definition
K*dGR (fe/fs) = -dGs

dGR = energy of combination for e-donor to e-acceptor
fe = fraction of energy for upkeep
fs = fraction of energy for synthesis/growth

fe + fs = 1
Term
What is the constant for g COD cell/g VSS?
Definition
1.42 g COD cell/g VSS
Term
What does an anaerobic digester do to organic carbons?
Definition
convert them to CO2 and CH4
Term
About how much of digester gas is methane?
Definition
2/3
Term
About how much of natural gas is methane?
Definition
85%-90%
Term
What is the sequence of biological processes in an anaerobic digester?
Definition
hydrolysis -> acetogenesis -> methanogenesis
Term
What happens in the hydrolysis phase of anaerobic digestion?
Definition
Large organic molecules -> lipids & proteins & carbs -> fatty acids & amino acids
Term
What kind of organisms perform hydrolysis?
Definition
acetogens (bacteria)
Term
What kind of organisms perform acetogenesis?
Definition
acetogens (bacteria)
Term
What happens in the acetogenesis phase of anaerobic digestion?
Definition
fatty acids & amino acids -> acetic acid & H2
Term
What happens during the methanogenesis part of anaerobic digestion?
Definition
CO2 + H2 -> CH4 (H2 is e-donor)
CH3COOH -> CH4 + H2O
Term
What kind of organisms perform methanogenesis?
Definition
Methanogens (Archaea)
Term
What conditions do methanogens prefer?
Definition
pH 6.6-7.6, yet their processes lower the pH, thus they need a lot of alkalinity. Strict anaerobes. slow growing with low yield.
Term
What temperature is mesophilic?
Definition
35 degrees C
Term
What temperature range is thermophilic?
Definition
50-60 degrees C
Term
How does temperature affect growth rate?
Definition
As temperature increases, growth rate increases
Term
What is SRT equivalent to in anaerobic digesters?
Definition
HRT
Term
What does a fatty acid look like?
Definition
Carbon chain with =O and -OH on the end
Term
What is acetate's formula?
Definition
CH3COOH
Term
What does washout mean?
Definition
rate of evacuating cells from a system (with Q) is greater than their rate of growth. => end up with little to no biomass.
Term
What are the characteristics of Class A biosolids?
Definition
coliform < 1000 MPN/g
prepared by a PTRP (process to further reduce pathogens) which consists of composting, incineration, thermophilic digestion. Stabalization processes -> reduce pathogen levels
Term
Can class A biosolids be sold to the public?
Definition
Yes
Term
What are the characteristics of class B biosolids?
Definition
coliform < 2,000,000 MPN/g
PSRP (process to significantly reduce pathogens)
Anaerobic digestion, lime stabilization, air drying
Use has site restrictions
Term
What lad applications are biosolids used for?
Definition
agriculture, forestry
Term
What restrictions and concerns arise with the land application of biosolids?
Definition
Restrictions: setbacks, depth-to-groundwater
Concerns: Heavy metals
Term
What is a lagoon?
Definition
A suspended growth secondary treatment process. Open basin often with an earthen liner (clay), no clarifier
Term
What is the permeability of a lagoon liner?
Definition
<1x10^-9 m/s
Term
If the lagoon depth is less than 2m, what is the typical width of the clay liner?
Definition
200mm
Term
What is the H:W ratio in lagoons?
Definition
1:3
Term
***What kind of liner do lagoons have?
Definition
PVC or HDPE liner, UV stabilized, <2x10^-10 m/s, if lagoon <2m deep, liner ~1mm thick
Term
Which speciation is more toxic, CrVI or CrIII?
Definition
CrVI
Term
Which speciation is more soluble, CrVI or CrIII?
Definition
CrVI
Term
What are some advantages of lagoons?
Definition
Energy efficient, low cost, low operations and management requirement, low skill requirement for operators, can handle shockloads
Term
What are some disadvantages of lagoons?
Definition
large surface area requirement, smells, must dredge periodically, can leak, little control over performance
Term
What factors influence Q in a lagoon?
Definition
evaporation, precipitation, WW flowrate
Term
When do you dredge a lagoon?
Definition
When it's filled with solids at 1/3 depth. Sludge judge!
Term
When is there no discharge from a lagoon?
Definition
When Qin (flow+precipitation) = evaporation
Term
What is required for a lagoon to discharge into a river or a lake?
Definition
NPDES permit
Term
Is an NPDES permit required for a wetland or infiltration pond?
Definition
Maybe not.
Term
How is oxygen supplied in an aerobic lagoon?
Definition
photosynthesis and henry's law (diffusion). May also use mechanical aerators such as surface aerators and coarse/fine bubble diffusers
Term
About how deep is an aerobic lagoon?
Definition
1-1.5m deep
Term
What is the BOD loading for an aerobic lagoon?
Definition
20-80 kg BOD/(acre*d)
Term
How deep are facultative lagoons?
Definition
1-3m
Term
What is the required DO level in an aerobic lagoon?
Definition
DO > 2mg/L
Term
What is a facultative lagoon?
Definition
Has aerobic and anaerobic sections
Term
What is the cycle that occurs in the aerobic portion of facultative lagoons?
Definition
Algae -> (New cells) and O2 -> (+organic waste=) bacteria -> (new cells) and CO2 -> algae
Term
What is the reaction that occurs in the anaerobic section of a facultative lagoon? (like in a digester)
Definition
Organic waste -> organic acids and alcohols -> CO2 + NH3 + H2S + CH4 (offgas into atmosphere)
Term
What is the typical BOD loading for facultative lagoons?
Definition
~10 kg BOD/(acre*day)
Term
What is the retentate?
Definition
What does not pass through the membrane
Term
What is the permeate?
Definition
What passes through the membrane
Term
What is the pore size range for microfiltration (MF)?
Definition
0.08-2 um
Term
What does microfiltration remove?
Definition
turbidity, TSS, protozoa, some bacteria
Term
What is the flux of a MF membrane?
Definition
405-1600 L/(m^2*d)
Term
What is the pore size range for ultrafiltration (UF)?
Definition
0.005-0.2 um
Term
What is the flux of an UF membrane?
Definition
405-815 L/(m^2*d)
Term
What does ultrafiltration remove?
Definition
large molecules, most bacteria, some viruses
Term
What is the pore size range for nanofiltration (NF)?
Definition
1-10 nm
Term
What does nanofiltration remove?
Definition
small molecules, hardness, viruses
Term
What is the flux of a NF membrane?
Definition
405-815 L/(m^2*d)
Term
What is the pore size range for reverse osmosis (RO)?
Definition
0.1-1 nm
Term
What does RO remove?
Definition
very small molecules, ions
Term
Do membranes degrade pollutants?
Definition
No - they only concentrate the pollutants
Term
What is Qf and what does it equal?
Definition
Qf = Qp + Qc
Qf is the dirty water entering the membrane system
Term
What makes water pass through a membrane?
Definition
Pressure exerted or vacuum created on one side to encourage flow
Term
What is TMP?
Definition
Transmembrane Pressure.
TMP = ((Pf + Pc)/2) - Pp
Term
What does a rising TMP indicate?
Definition
membrane fouling. May need backwash
Term
What is the water recovery equal to?
Definition
r = Qp/Qf
Term
What is the pollution rejection rate equal to?
Definition
R = (Cf-Cp)/Cf = 1- Cp/Cf
Term
What is the membrane flux equal to?
Definition
Fw = Qp/A
Term
What is membrane fouling and why is it bad?
Definition
When pores clog. Membranes can rip or detach from housing or support material.
Term
How do you solve membrane fouling?
Definition
Clean the membrane, often via backwashing
Term
How do you select your membrane option?
Definition
Determine feed water type and match with appropriate membrane. Use the SDI.
Term
What is SDI?
Definition
Silt density index. A filtration test where you pass 500 mL of raw water through a 0.45 um pore size filter with 47mm diameter at 210 kPa. Repeat test multiple times using the same filter.
Term
What is the equation for SDI?
Definition
SDI = 100[1-ti/ts]/ttot

ti = time for initial 500mL
tf = time for final 500mL
ttot = sum of all times
Term
What is the SDI range for NF?
Definition
0-2
Term
What is the SDI range for RO with a hollow fiber?
Definition
0-2
Term
What is the SDI range for RO with a spiral wound?
Definition
0-3
Term
How much height do you add to an ion exchange unit?
Definition
1m for inlet, 0.5m for resin support, 1xheight for fluidization
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