Term
What equation do you use to work out the rate of a reaction if it has a distinct end? |
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Definition
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What two things are needed for a reaction to take place? |
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Definition
-energy above the activation energy
-collision of particles at the correct angle or orientation |
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What is Activation Energy? |
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Definition
the minimum amount of energy required for a reaction |
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Term
What is the activated complex? |
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Definition
the unstable intermediate between reactants and products containing partial bonds |
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Term
How do you calculate the enthalpy change of a reaction? |
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Definition
HP- HR
(enthalpy of products - enthalpy of reactants) |
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Term
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Definition
Catalysts lower the activation energy increasing the number of particles able to react |
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Term
How do Heterogeneous catalysts work? |
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Definition
They work by adsorbing reactants onto active sites which weakens their bonds. |
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Term
How does poisoning of catalysts occur? |
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Definition
Poisoning occurs when chemicals are absorbed onto active sites stopping them working |
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Term
How can enzymes be denatured? |
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Definition
Enzymes can be denatured if the pH, temperature or alcohol content is too extreme |
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Term
Define each component /\H=cm/\T
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Definition
ΔH is enthalpy change
c is 4.18 Kj/mol
m is number of kilograms (litres) of water
ΔT is the temperature change |
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Term
What step comes after working out the energy change for a certain mass of compound reacting? |
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Definition
work out how much 1 mole would produce |
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Term
Why does atomic size increase going down a group? |
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Definition
there is an extra energy level moving the electrons further from the nucleus thus increasing the size |
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Term
Why does ionisation energy increase across a period? |
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Definition
It increases across a period as the electrons are closer to the nucleus therefore harder to remove |
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Term
Why does ionisation energy decrease down a group? |
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Definition
It decreases down a group as the electrons are further from the nucleus and shielded from its pull by the inner electrons |
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Term
Why is there a large jump between the first and second ionisation energies? |
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Definition
There is a large jump between the first and second ionisation energies for group 1 metals as you are removing an electron from an energy level closer to the nucleus |
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Term
Why does electronegativity increase going across a period? |
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Definition
It increases across a period as the nuclear charge increases pulling the electrons closer |
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Term
Why does electronegativity decrease down a group? |
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Definition
It decreases down a group as the pull of the nucleus is being shielded by the inner electrons |
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Term
What do atoms with equal electronegativities form? |
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Definition
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Term
What do atoms with different electronegativities form? |
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Definition
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Term
What are the symbols for the atoms with the biggest and lowest electronegativities? |
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Definition
The atoms with the biggest electronegativities have a δ-charge and those with the lowest value have a δ+ charge. |
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Term
Describe metallic bonding |
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Definition
Metallic bonds have positive cores surrounded by delocalised electrons enabling the metals to conduct. |
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Term
Where is metallic bonding found and is it strong? |
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Definition
This force of attraction is very strong and exists in metal elements. |
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Term
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Definition
Ionic bonds are an electrostatic force of attraction between oppositely charged ions. |
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Term
Describe ionic bonding's melting points & structure |
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Definition
They have high melting points and have a crystal lattice structure that must be broken before the ions are free to move and conduct electricity. |
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Term
Are ionic compounds soluble? |
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Definition
Ionic compounds are soluble in polar solvents like water |
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Term
Describe the strength of covalent bonds |
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Definition
Covalent bonds are very strong and difficult to break |
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Term
Describe covalent Network bonding |
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Definition
Covalent network substances have massive structures with millions of bonds which have to be broken to change their state |
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Term
What are covalent molecular's at room temp and what is broken to change their state? |
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Definition
•Covalent molecular substances are usually liquid or gas at room temperature.
•It is weak intermolecular forces that are broken when their state is changed |
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Term
How are dipole-dipole attractions caused? |
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Definition
Dipole –Dipole attractions are caused by molecules that have a permanent dipole
They are stronger than Van der Waals. |
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Term
Describe Van Der Waals Strength. |
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Definition
They are the weakest intermolecular force |
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Term
What will one mole of a substance contain? |
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Definition
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Term
What will one mole of a monatomic element contain? |
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Definition
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Term
What will one mole of a diatomic and covalent molecular substance contain? |
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Definition
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Term
What will one mole of Ionic compounds contain? |
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Definition
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Term
What happens to the molar volume of all gases at constant temperature and pressure? |
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Definition
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Term
How do we work out volume of gases from a balances equation? |
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Definition
We can use simple ratios to work out the volumes of gases from a balanced equation |
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