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Thermochemistry
types of systems & processes , 1st & 2nd law of thermodynamics
9
Chemistry
Undergraduate 1
02/06/2013

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Cards

Term
isolated system def
Definition
NOmatter, heat, work exchanged with surroundings
Term
Closed system def
Definition

exchanges: heat & work

No: matter

Term
Open system def
Definition

CAN exchange everything:

heat 

work

energy

Term
isobaric process
Definition
pressure constant
Term
isothermal def
Definition
temp is constant
Term
adiabatic process
Definition
no heat added or substracted exchanged btwn enviroment & surroundings
Term

Give values for T and P :

 

1.at standard temp & pressure

2. standard conditions

Definition

1. STP = 0C(273K)

1 atm

(ideal gases)

2. standard conditions

T= 25 C (298K)

1 atm

Term

First law of thermodynamics

give formula and name

Definition

law of conservation of energy

ΔU= Q-W

change in internal energy= heat-work done by system

units: J

Term
second law of thermodynamics
Definition

energy spontaneously disperses from being localized to becoming spread out if it is not hindered from doing so.

 

ex hot tea cooling down,

living things dying

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