Term
What is the energy difference btwn
n=3 , n=4
and
n=1,n=2
Include why? |
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Definition
n=3 and n=4 has a smaller energy difference
(they are farther away from nucleus)
compared to
n=1 and n=2
(closer to nucleus) |
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Term
define the quantum number ' n',
what does a larger n indicate? |
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Definition
principal quantum number that has a integer value
↑n= ↑energy↑ oribtal radius
*remmeber high energy means more unstable (more likely to engage in chemical rxns they have further from nucleus) |
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Term
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Definition
decides the :
shape and number of subshells within a given principal energy level (shell) |
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Term
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Definition
n limits l !
For any given value of n, 'l 'can only have values in the range of :
0 to (n-1)
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Term
If n=1, what does that mean in refernce to:
# subshells
value of 'l'?
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Definition
n=1
1 subshell
(so the 1st principal energy level has only 1 subshell)
l= 0 (only)
(s) |
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Term
If n=2, what does that mean in refernce to:
# subshells
value of 'l'?
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Definition
2 subshells
(the 2nd prinipal energy level)
'l '= 0 and 1
(s) and (p) |
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Term
If n=3, what does that mean in refernce to:
# subshells
value of 'l'and name the oribtal you are in
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Definition
3 shells
(3 principal energy level)
l=0, 1, 2
(s, p, d ) |
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Term
If n=4, what does that mean in refernce to:
# subshells
value of 'l'? |
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Definition
4 subshells
l: 0 (s), 1 (p), 2 (d) ,3 (f) *remember (n-1)= l
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Term
The maximum number of the electrons within the any given subshell?
in reference to n& l?
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Definition
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Term
What does the quantum mumber ml mean? |
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Definition
tells the particular orbital within a subshell where an electron is highly likely to be found at a given time.
(this tells us that , s shell has 1, p shell has 3, etc) |
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Term
What are the values for ml? |
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Definition
integers btwn :
-l to + l
including 0
ex: if l=1
(-1,0,1) |
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Term
Give the l,ml values for the s oribtal |
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Definition
l=0
ml=0
* remember the s shell has 1 oribital |
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Term
Give the l,ml values for the p oribtal |
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Definition
l=1
ml= -1 ,0,1
the p shell oribtal has '3'oribtals |
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Term
give # oribitals in the following subshells:
s,p,d,f |
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Definition
s: 1 orbitals
p: 3
d: 5
f:7
(as you go to next level you add 2) |
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Term
What does the quantum number ms stand for: |
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Definition
magnetic spin of the ELECTRON
has values of : +1/2 to - 1/2 |
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Term
Give the formula how to calculate the energy value of a quantum |
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Definition
E= hf
where h= 6.626 x 10-34 (Planks)
f= frequency of a photon
(could also be v)
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Term
1.Give formula for the frequency of a photon
2. What is the unit for the wavelength
and give the conversion to makeit work in the equation. |
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Definition
f= c
λ
c= 3 x 108 m/s
(speed of light )
λ= wavelength (nm)
need to mult by 109 |
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Term
Give Avagrados constant
Planks
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Definition
avagrados: 6.023 x 1023
(there is a holiday celebrated at 6:02,time is always positive)
planks: 6.626 x 10 -34
(down the plank) |
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Term
Define Hund's rule
Pauli's exclusion principal |
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Definition
Hunds: every orbital in a subshell is singly occupied with 1 electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin.
↑↑ , ↑↑ ,(the blue came first)
Pauli: states that no two electrons can have the same four quantum numbers. The first three may be similar but the four quantum number must be different. |
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Term
Which elements on periodic table have half filled orbitals in order to decrease their stablilites? |
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Definition
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Term
Fix this config for Cr so that is more stable:
[Ar] 3d4 4s2 |
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Definition
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Term
Fix this config for Cu so that is more stable:
[Ar] 3d9 4s2 |
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Definition
[Ar] 3d10 4s1
its adding to that big d instead of having more e- furhther from nucleus, makes it more reactive |
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Term
Fix this config for Ag so that is more stable:
[Kr] 4d9 5s2 |
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Definition
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Term
fix this config so that is more stable:
[Xe] 4f14 5d9 6s2 |
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Definition
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Term
Define 'l'
Define'ml'
Give the example of the p oribital |
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Definition
l: # of subshells and shape for a value of 'n'
ml: tells what specific oribital where you can find an electron in a subshell.
ex
n=2
l= 0,1 (2 subshells)
ml=-1 ,0,3 (3 oribitals) |
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Term
atomic weight def
give unit |
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Definition
weight of an element as an average of the isotopes of a particular element
unit:grams per mole |
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Term
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Definition
a different form of the same element (will have a charge b/c it has gained or lossed electrons)
but has a different # of neutrons
do not confused with cations and anions (these happen with rxns etc) |
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Term
Do isotopes have different # of protons or electrons or both? |
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Definition
no isotopes only differ in the # of neutrons |
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Term
atomic emission spectrum def |
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Definition
spectrum of light created when an atom's electron's fall to to their ground state from a higher energy level
*remember this causes energy to be released (emitted). |
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Term
atomic absorption spectrum def |
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Definition
spectrum of light created when an atom's electron's are excited to higher energy levels
*remember this requires energy to be absorbed |
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Term
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Definition
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Term
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Definition
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Term
heisenberg uncertanity principal def |
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Definition
it is impossible to calc the:
momentum & position of an electron at the SAME time
(remember you can calculate the momentum and velocity at the same time) |
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Term
is an electron always static (referring an energy levels)? |
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Definition
no, even when an electron is in its ground state the electron is not completly static. |
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