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different chemical compounds with identical molecular formulas |
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Structural and Stereoisomers |
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identical molecular formula but different either in the position of a certain substituent or how the same atoms are combined into different functional groups |
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Both the order in which atoms are joined and the functional groups are identical; all that differs is the three-dimensional spatial arrangement of the atoms |
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Types of Structural Isomers |
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Positional and Functional Group Isomers |
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Presence of an atom or chemical group at different positions on the carbon chain |
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same molecular formula but different functional groups |
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waves vibrate in a single plane |
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Optically active substances |
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rotate the plane of vibration of polarized light |
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measured by specific rotation |
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atom in a molecule that has four different groups attached |
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molecule not identical with its mirror image, not superimposable on |
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molecules that are nonsuperimposable mirror images of each other |
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have identical properties |
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rotate plane-polarized light the same number of degrees in opposite directions |
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maximum number of enantiomers possible |
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different ocnfigurations because of the presence of a rigid structure in the molecule |
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stereoisomers that are not enantiomers |
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