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Science foundations
Chapter 3- Atoms
74
Science
Undergraduate 1
12/10/2012

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Term
There are two major parts of an atom. What are they? 
Definition
The nucleus and the electrons.    
Term
Where do we find the vast majority of an atom's mass?
Definition
 In the nucleus.    
Term
What two particles do we find bound together in a nucleus?
Definition
 Protons and neutrons.    
Term
Atoms that are not electrically neutral are called what? 
Definition
Ions.    
Term
The atomic number of an atom tells you how many _______ are in the atom. (Remember, not all atoms are electrically neutral!) 
Definition
Protons. 
Term
The mass number of an atom tells you how many _______ are in the atom. 
Definition
Protons and neutrons.    
Term
All atoms of a given element have the same number of __________ in their nuclei. 
Definition
Protons.    
Term
What are isotopes? 
Definition
Atoms with the same number of protons (i.e. the same element) but a different number of neutrons.    
Term
  1. How many protons and neutrons will you find in an atom of 93 Tc

                                                                                                         43 

Definition
43 protons, 50 neutrons. 
Term
What does it mean to say that a given quantity is conserved?
Definition
 That it does not change over time (or during a process).    
Term
What two quantities are conserved in nuclear reactions?
Definition
 Mass number and atomic number.    
Term
What does the word “transmutation” refer to? 
Definition
The changing of one element into another.    
Term
What do we call very large-scale transmutation? 
Definition
Chemical evolution.    
Term
For nuclear fusion to happen, temperatures must be high enough so that ________________, but low enough that ____________. 
Definition
The neutrons and protons are moving rapidly; protons and neutrons will remain bound. 
Term
What elements were synthesized during the big bang? 
Definition
Hydrogen and helium, mostly. Some lithium and beryllium.    
Term
The first stage of the stellar fuel cycle involves the fusion of ________ into ___________.
Definition
 Hydrogen; helium.    
Term
What is the end product of the triple alpha reaction? 
Definition
Carbon-12.    
Term
What is the end product of the CNO cycle? 
Definition
Helium-4.    
Term
In large stars, fusion reactions can proceed up to what element?  
Definition
 Iron.    
Term
What does the “s” and “r” stand for in s-process and r-process?
Definition
 Slow and rapid.    
Term
When and where was most of the hydrogen in the universe formed? 
Definition
During the big bang, everywhere.    
Term
When and where was most of the carbon in the universe formed?
Definition
 In the cores of stars, during their regular fuel cycle.    
Term
When and where are the heaviest elements in the universe formed?
Definition
 In the cores of stars, during supernovae.    
Term
What were the four elements in Empedocles' model of matter?
Definition
 Earth, water, air, and fire.    
Term
What was the basic premise of Democritus' model of matter?
Definition

 Everything is made of tiny, indivisible pieces called

“atomos”. 

Term
Describe J.J. Thomson's experiments. What was he experimenting with, and what did he observe?
Definition

 Cathode ray

tubes; the rays could be deflected by electromagnetic fields. 

Term
Name and describe the atomic model that was proposed as a result of Thomson's experiments.
Definition

 The plum pudding

model: basically, the atom is a glob of relatively weak positive goo (pudding) with electrons embedded throughout. 

Term
Describe Ernest Rutherford's experiments. What was he experimenting with, and what did he observe?
Definition

 Rutherford

was bombarding a gold foil with high energy alpha particles. Some of the alpha particles bounced back, when it was

fully expected (according to the plum pudding model) that they would travel straight through the foil. 

Term

Complete the phrase: “It was [as] if you fired a 15-inch [artillery] shell at a piece of tissue paper and

____________.” 

Definition
It came back and hit you. 
Term

Name and describe the atomic model that was proposed as a result of Rutherford's experiments. 

Definition

The planetary

model. All of the positive charge and most of the mass of the atom is concentrated in a small region toward the center –

the nucleus – and the atoms orbit around on the outside, not much unlike planets orbiting the Sun. 

Term
What were the two limitations/shortcomings of the planetary model?
Definition

 It predicated that all rarefied gasses should have

an emission spectrum consisting of all colors of visible light; there's no way that an electron in a circular orbit can

maintain a stable orbit, since it will be constantly radiating energy away. 

Term
What was the basic premise of the Bohr model? 
Definition

The electrons must have certain specific energy levels (those levels

were determined by requiring that the electrons had quantized angular momentum). 

Term
How successful was the Bohr model in predicting the emission spectra of rarefied gasses (including hydrogen)?
Definition

 It

predicted the hydrogen spectrum perfectly. It failed miserably for all the other elements. 

Term
Describe our modern picture of the atom (i.e. the quantum mechanical model). 
Definition

The state of an electron (position,

velocity, etc...) are described by probabilities only. The regions of highest probability for finding the electron constitute

“clouds” of various shapes around the nucleus. 

Term
Summarize our present understanding about the electrons in atoms. Where are they found and how do they behave?
Definition

 

They are found in those electron clouds. They behave like both a particle and wave. 

Term
Describe Joseph Priestley's experiments, and explain what was learned from them. 
Definition
Heated mercury calx, got out mercury metal and oxygen. Some substances, like the calx, are combinations of other substances. 
Term
Describe Antoine Lavoisier's experiments, and explain what was learned from them.
Definition
 Combined oxygen with other gasses to form compounds via combustion, found out that the total mass of the gasses was the same before and after combustion. Mass is conserved in chemical reactions. 
Term
Describe Joseph Proust's experiments, and explain what was learned from them. 
Definition
Compared the composition of compounds found in nature with those produced in the laboratory. Discovered that the ratio of one type of element to another in a given compound is constant. This is the law of definite proportions. 
Term
Describe John Dalton's experiments, and explain what was learned from them. 
Definition
Investigated the proportions in which certain gasses mixed when reacting. The elements would combine in specific whole number ratios. This is the law of multiple proportions. 
Term
Summarize the four major parts of Dalton's atomic theory.
Definition
 (1) All matter is composed of indivisible particles called atoms. (2) All atoms of a given element are identical, and those of different elements have different properties. (3) Chemical reactions involve the combining and rearranging of atoms. (4) When elements combine to form compounds, they do so in defined whole number ratios. 
Term
Johann Dobereiner's attempt to organize the elements involved groups of how many elements? 
Definition
Three.    
Term
Complete the phrase: “This insight caused Mendeleyev to __________.” 
Definition

Leave gaps in his initial formulation of the

table. 

Term
What important discovery did William Ramsay make? 
Definition
Argon – one of the noble gasses.    
Term
What is the valence number of the noble gasses? Why are they assigned this number? 
Definition

Zero. They don't typically

react with anything. 

Term
Describe the three types of chemical bonds discussed in the reading. 
Definition

Nonpolar covalent (two atoms with identical

electronegativity sharing electrons), polar covalent (two atoms with different electronegativity sharing electrons), and

ionic (one atom takes an electron away completely from the other). 

Term
If two elements have very different electronegativities, what type of bond is most likely to form?
Definition
 Ionic.    
Term
How can you tell how many chemical bonds a given element typically forms? 
Definition
By it's valence.    
Term
Which type of biologically important molecule has a carbon ring structure? 
Definition
Carbohydrates.    
Term
What elements can be found in carbohydrates? In amino acids? 
Definition

Carbon, hydrogen, and oxygen. For amino acids, add

nitrogen to the list. 

Term
What are the three main parts of a nucleotide? 
Definition
The nucelic acid (nitrogenous base), a sugar, and a phosphate group.
Term
  1. Which of the core concepts below most logically follows from the experiments you conducted in Part I: Priestly?


(a)  Red calx turns into mercury when it is heated.

(b)  Some substances are composed of discrete amounts of two or more other substances.

(c)  All substances can be broken down into simpler materials by heating them. 

Definition
  1. (b)  Some substances are composed of discrete amounts of two or more other substances.

Term
  1. Which of the core concepts below most logically follows from the experiments you conducted in Part II: Lavoisier?

    1. (a)  The total mass of the products of a chemical reaction is greater than the total mass of the reactants.

    2. (b)  The total mass of the products of a chemical reaction is less than the total mass of the reactants.

      (c)  The total mass of the products of a chemical reaction is exactly equal to the total mass of the reactants. 

Definition
(c)  The total mass of the products of a chemical reaction is exactly equal to the total mass of the reactants. 
Term
  1. Which of the core concepts below most logically follows from the experiments you conducted in Part III: Diamond?

    (a) Elements combine in specific, defined ratios in chemical reactions.

    (b) Carbon reacts differently depending on whether it is in the diamond or charcoal form.

 (c) Diamond can form carbon dioxide when neither air nor oxygen is present. 

Definition

(a) Elements combine in specific, defined ratios in chemical reactions.


Term
What did Wilhelm Roentgen discover? 
Definition
X-rays.    
Term
What did Henri Becquerel discover?
Definition
 Natural radioactivity.    
Term
What did Marie and Pierre Curie discover?
Definition

 Radioactivity ionizes air; techniques for isolating radioisotopes; radium

and polonium. 

Term
What did Rutherford's investigations discover about radioactivity?
Definition

 There are distinct types; activity is described by

half life; radioactivity is the spontaneous decay of atoms. 

Term
An alpha particle is a nucleus of what isotope?
Definition
 Helium-4.    
Term
What is a beta minus particle?
Definition
 An electron.    
Term
What is a beta plus particle? 
Definition
A positron (positively charged electron).    
Term
At a fundamental level, beta minus decay involves a ________ turning into a ________ and ________. 
Definition

Neutron;

proton; electron. 

Term
At a fundamental level, beta plus decay involves a ________ turning into a ________ and ________. 
Definition

Proton; neutron;

positron. 

Term
What happens in an electron capture process?
Definition

 An atomic electron combines with a proton to form a neutron and a

neutrino. 

Term
Atoms with excess energy generally release that energy in the form of what?
Definition
 Gamma rays.    
Term

Rank order the particles emitted in the types of radioactive decay discussed in the reading by ascending

penetrability. 

Definition
Alpha, beta, gamma. 
Term
  1. Rank order the particles emitted in the types of radioactive decay discussed in the reading by relative biological

    effectiveness. 

Definition
Gamma/beta, alpha. 
Term
Complete the phrase: “The [radioactive decay] process continues until a ______________ is produced.” 
Definition

Stable

isotope. 

Term
How many radioactive decays happen in the process of 238U turning into 206Pb? 
Definition

Fourteen. You need to count them on

the diagram. 

Term
Heavy isotopes tend to decay by which process?
Definition
 Alpha decay.    
Term
Neutron rich isotopes tend to decay by which process?
Definition
 Beta minus decay.    
Term
Proton rich isotopes tend to decay by which process?
Definition
 Beta plus or electron capture.    
Term
What is meant by the “half-life” of a radioactive isotope? 
Definition

The amount of time it takes for half of a given sample to

decay. 

Term
Complete the phrase: “You ________ predict when a single atom will decay.” 
Definition
Cannot.   
Term
What effect do physical conditions and chemical bonding have on the half-life of a radioactive isotope?
Definition

 None

whatsoever. No Earth conditions change the half life. This concept will be important in section 4.2. 

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