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Reagents
Reagents and their affect on molecules
24
Chemistry
Undergraduate 4
06/21/2015

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Term

H2O

Na2CO3

Definition
Substitutes OH in allylic position
Term
Br2
Definition
Adds a Br
Term

X2

UV light

Definition

Free radical halogenation

Breaks double bond and attaches two halogens

Term

NBS

Heat, Light, Peroxides

Definition

Free Radical Addition

Adds a single Br allylically

Term
HX (one mol)
Definition
Adds a single halogen by breaking a double bond
Term
CH3OH
Definition
Adds OCH3 to allylic carbocation by substitution
Term

H2

(Metal Catalyst)

Definition
Breaks all double bonds in Benzene
Term

KMnO4

NaOH, H2O, Heat, HCl

Definition
Adds COOH in benzyllic position
Term

Na2Cr2O7

H2SO4, H2O

Definition
Adds COOH in benzyllic position
Term

H2CrO7

Heat

Definition
Adds COOH in benzyllic position
Term

Cl2

FeCl3

Definition
Adds Cl to ring structure
Term

I2

HNO3

Definition
Adds I to structure
Term

I2

CH3COOOH

Definition
Adds I to structure
Term

I-O

Acetone

Definition
Adds I to structure
Term

H2SO4

SO3

Definition
Adds SO3H
Term

Cyclohexene

HF

Definition
Attaches cyclohexane to benzne ring
Term

Zn(Hg)

Concentrated HCl, Heat

Definition
Removes double bonded oxygen
Term

H2NNH2, KOH

Heat

Definition
Removes double bonded oxygen
Term

HNO3

H2SO4

Definition
Adds Nitro group (NO2)
Term

CH3O

CH3ONa/CH3OH

Definition

Subtitutes OCH3 in place of halogen

(or other L.G.)

Term
CH3NH2
Definition

Subtitutes methylamine (CH3NH2) for a halogen

(or other L.G.)

Term
Mg0
Definition
Removes Iodine
Term

KO t-butyl, DMSO

Heat

Definition
Removes leaving group creating double bond
Term

R-Cl

AlCl3

Definition
Alkylates via Friedel-Craft mechanism
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