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Oxidation number during oxidation |
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oxidation number during reduction |
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half reaction electrons during oxidation |
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half reaction electrons during reduction |
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Rule 1: oxidation state of free elements |
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Rule 2: oxidation state of monatomic ions |
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Rule 3: sum of atoms oxidation states in a compound |
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Rule 4a: Group I metals have an oxidation state |
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Rule 4b: Group II metals have an oxidation state |
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nonmetals have oxidation states according to the table, F=-1,H=+1, O=-2, group 7a=-1, group 6a=-2,group 5a=-3 |
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reactant that reduces an element in another reactant, contains the element that is oxidized |
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reactant that oxidizes an element in another reactant, contains the element that is reduced |
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where oxidation occurs loses weight positive end of battery attracts anions |
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where reduction occurs attracts cations negative end of battery gains weight where plating takes place |
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1Amp (current) = 1 Coulomb of charge = |
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1 A = 6.242 x 10^18 electrons per second� |
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1 J per Coulomb of charge |
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Amount of force pushing the electrons through the wire |
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difference in potential energy between the anode and the cathode in a voltaic cell
standard emf, Eocell |
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does not participate in reaction, but just provides a surface |
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half-reaction with a strong tendency to occur |
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large positive half-cell potential |
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how electrons will flow when two half-cells are connected |
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half-reaction with the stronger tendency will occurire |
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standard hydrogen electrodels = |
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stronger tendency toward reduction than the SHE |
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stronger tendency toward oxidation than the SHE |
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For oxidation half-reaction |
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Free energy change G < 1 (negative) E > 1 (positive) K > 1 |
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free energy change (G^o)= |
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Electrons will flow from the electrode in the less concentrated solution to the electrode in the more concentrated solution |
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using electrical energy to break a compound apartrire |
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spontaneous oxidation of a metal by chemicals in the environmentl |
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