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Quiz 2 - Chem1410
Covering from stoichiometry to electron configuration
59
Chemistry
Undergraduate 1
10/15/2012

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Term
Li+
Definition
Always soluble
Term
Na+
Definition
Always soluble
Term
K+
Definition
Always soluble
Term
NH4^+
Definition
Always soluble
Term
NO3^-
Definition
Always soluble
Term
C2H3O2^-
Definition
Always soluble
Term
Cl-
Definition
Insoluble when paired with Ag+, Hg2^2+, or Pb^2+.
Term
Br-
Definition
Insoluble when paired with Ag+, Hg2^2+, or Pb^2+.
Term
I-
Definition
Insoluble when paired with Ag+, Hg2^2+, or Pb^2+.
Term
SO4^2-
Definition
Insoluble when paired with Sr^2+, Ba^2+, Pb^2+, Ag+, or Ca^2+.
Term
OH-
Definition
Soluble when paired with Li+, Na+, K+, NH4^+. Slightly soluble with Ca^2+, Sr^2+, and Ba^2+.
Term
s^2-
Definition
Soluble when paired with Li+, Na+, K+, NH4^+, Ca^2+, Sr^2+, and Ba^2+.
Term
CO3^2-
Definition
Soluble with Li+, Na+, K+, or NH4^+.
Term
PO4^3-
Definition
Soluble with Li+, Na+, K+, or NH4^+.
Term
Oxidation
Definition
loss of electrons
Term
Reduction
Definition
Gain of electrons
Term
The oxidation state of an atom in a free element
Definition
0
Term
Oxidation state of monoatomic ion
Definition
equal to its charge. E.g. Ca^2+ has an oxidation state of +2.
Term
Sum of oxidation state of all atoms in neutral molecule or formula unit.
Definition
0
Term
Sum of oxidation states of all atoms in ion.
Definition
Equal to its charge. E.g. NO3^- has an overall oxidation state of -1.
Term
Oxidation state of group 1A metals
Definition
+1
Term
Oxidation state of group 2A metals
Definition
+2
Term
Oxidation state of F
Definition
-1 (priority - 1)
Term
Oxidation state of H
Definition
+1 (priority - 2)
Term
Oxidation state of O
Definition
-2 (priority - 3)
Term
Oxidation state of group 7A
Definition
-1 (priority - 4)
Term
Oxidation state of group 6A
Definition
-2 (priority - 5)
Term
Oxidation state of group 5A
Definition
-3 (priority - 6)
Term
Frequency in relation to wavelength
Definition
V = c/l
Term
Electromagnetic spectrum from highest energy to lowest
Definition
Gamma, X, Ultraviolet, Visible light, Infrared, Microwave, Radio
Term
Constructive interference
Definition
Two in phase electromagnetic waves combining to form wave with 2X the amplitude.
Term
Energy of photon in terms of wavelength
Definition
E = hc/l
Term
Threshold frequency condition
Definition
Energy of photon = Binding energy of emitted electron: hv=phi.
Term
Emission spectrum
Definition
Graphic representation of the wavelengths of light which when applied to specific elements results in the emission of electrons.
Term
Bohr model
Definition
The idea that electrons exist in "stationary states". Changes in energy only occur when they jump from one stationary state to another.
Term
deBroglie relation
Definition
l=h/mv (l=wavelength, m=mass, v=velocity of electron)
Term
Complementary properties
Definition
properties which inherently exclude each other. I.e. the position, and velocity of a particle. Also, position and energy of a particle. Position has to do with particle nature of electron, whereas energy and velocity relate to wave nature of electrons.
Term
Heisenberg's uncertainty principle
Definition
deltax * m*deltav >= h/4pi. Here we simply need to know that the more accurately you know the position of an electron, the less accurately you know its velocity.
Term
Orbital
Definition
probability distribution map showing where an electron is likely to be found
Term
Principal quantum number
Definition
n. Determines overall size and energy of orbital. Ranges from 1 to infinity.
Term
Angular momentum quantum number
Definition
l. Determines shape of orbital. l=1, s orbital: l=2, p orbital. l=3, d orbital. l=4, f orbital. Ranges from 0 to n-1.
Term
Magnetic quantum number
Definition
m(l). Specifies orientation of orbital. Ranges from -l, to +l.
Term
Orbital with equal values n are said to be in the same:
Definition
Principal level (or principal shell)
Term
Orbitals with equal values of n and l are said to be in the same:
Definition
Sublevel (or subshell)
Term
Number of sublevels in any level:
Definition
equals n.
Term
Number of orbitals in any sublevel:
Definition
2l + 1
Term
Number of orbitals in any level:
Definition
n^2
Term
Wavelength of photon in relation to its energy
Definition
l=hc/E
Term
Node
Definition
A point where the wave function = 0. In other words a point where the probability of an electron being present = 0.
Term
Spin quantum number
Definition
m(s). A quantum number which determines whether an electron has an up spin (+1/2) or a down spin (-1/2). electrons with up spin will be equal to electrons with down spin within an atom.
Term
Ground state
Definition
The lowest energy state of an atom
Term
Pauli exclusion principle
Definition
No two electrons in an atom can have the same four quantum numbers.
Term
Effective nuclear charge
Definition
The charge of the nucleus, minus the charge of all electrons shielding it from whatever we are attempting to calculate the Effective nuclear charge of.
Term
Aufbau principle
Definition
The combined ideas that electrons will always fill lower energy orbitals first, and that only two electrons are allowed in each orbital.
Term
Hund's rule
Definition
when filling degenerate orbitals, electrons fill them singly first, with parallel spins.
Term
No. of orbitals (and electrons) in f sublevel
Definition
7 - sublevels, 14 - electrons
Term
No. of orbitals (and electrons) in d sublevel
Definition
5 - sublevels, 10 - electrons
Term
No. of orbitals (and electrons) in p sublevel
Definition
3 - sublevels, 6 - electrons
Term
No. of orbitals (and electrons) in s sublevel
Definition
1 - sublevel, 2 - electrons
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