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Soil organic nitrogen (fixed N2 pool in the soil): 110 x 10^15 g |
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Atmosphere to soil exchange |
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140 x 10^12 g/yr BIOLOGICAL FIXATION of nitrogen 1/1000 of the N pool in the soil resonance time of 1000 years |
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Lightning nitrogen fixation |
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Converts NO3 to NO2, NO, or NO2 |
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How great is the human impact on annual nitrogen fixation? |
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Increase in farm size from 1700 to 1980 |
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Overuse of nitrogen causes: |
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1. smog 2. forest die-back 3. acidification of water 4. Ozone hole 5. Global warming 6. Eutrophication |
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an increase in the concentration of chemical nutrients in an ecosystem to an extent that increases the primary productivity of the ecosystem. Depending on the degree of eutrophication, subsequent negative environmental effects such as anoxia and severe reductions in water quality, fish, and other animal populations may occur.
Think about example with algae |
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Details and effects of NOx |
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-either NO or NO2 -created by denrification of nitrate (NO3-) -produced by combustion (20Tg/yr) -forms photochemical smog -creates ground level ozone -component of acid rain |
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-GLOBAL ATMOSPHERIC IMPACT -lives for 100 yrs in atmosphere -destroys stratospheric ozone -most destructive force on ozone right now because it is the only unregulated force -radiative forcing contributes to global warming -Causes slightly acidic rain -mostly pollutes ocean shelf and estruaries -About 40% caused by humans |
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-O3 -BAD OZONE -Troposphere contains 10% of all ozone -Toxic to plants and animals, but is usually diluted enough to not matter -It's fluxuations impact how crops and photosynthesis occurs |
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GOOD OZONE -UV shield -Long term declien, particualry in antarctica -N20 eats away at it |
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-One of the first emission regulation cases. -dealt with stratospheric ozone destruction in antarctica -biggest flaw was that it didn't regulate N20 -Hole is causing increased UV rays on surrounding ecosystems that affect all of the southern hemisphere |
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Effects of ozone destruction |
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2% increase in UVB for every 1% decrease in ozone. 2% increase in non-melanoma skin cancer for every 1% increase in UVB |
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LOCAL/REGIONAL ATMOSPHERIC IMPACT -accounted for mostly by combustion (20Tg/yr) -forms photochemical smog everywhere, even in Montreal -creates ground level ozone -component of acid rain -comes mostly from fossil fuel use |
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LOCAL/REGIONAL ATMOSPHERIC IMPACT -ammonia -About 70% is emitted by humans -animal waste accounts for 32 Tg -Volitalization from soil accounts for 10Tg -Forest burning releases 5Tg -Raises the pH of rainwater |
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negative effects of increased nitrification in farms |
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-Nitrogen stays in system for a really long time -can be leeched, released back to atmosphere, come down in acid rain, etc. -effects are spread out and long-lasting -N leaching leads to acidification +Al mobility |
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acidification may explain red spruce decline (due to decreased cold tolerance) and sugar maple dieback on cation-poor soils |
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Hubbard Brook River Experiment |
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How N deposition affects diversity |
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Nitrogen addition leads to nitrate leaching into groundwater. Effects? |
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-denitrication takes nitrogen out of system -leaching makes water undrinkable -10ppm is unhealthy to drink (EPA standard) -farmlands are at the highest risk of this leaching |
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Once N gets into water, where does it go? |
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30-70% of N entering rivers is denitrified 10-80% entering estuaries is denitrified >80% entering shelves is denitrified |
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Hypoxia in coastal waters |
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-algal blooms caused by increased nitrogen due to increased photosynthesis -when algae die, they sink to bottom. Their decomposition takes more oxygen out of the system -*nitrogen doesn't kill anything! They create things like algal blooms. oxygen produced by algal blooms diffuses oxygen out into the atmosphere. Their decomposition removes most or all oxygen from system, causing fish kills and the like |
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Light + CH20 + O2 => CO2 + H20
Decomposition of biomass is opposite (minus the light) |
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What could we about emissions? |
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-Could cut down on fossil fuels and biofuels -We could cut down on farm nitrogen runoff -we don't have the technology to regulate 75% of nitrogen |
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-only <1000 species can fix nitrogen (N2 => NH3) -Key limitation to growth in many systems -N2 is 78% of the atmosphere but is useless biologically -chlorophyll A and B contain Nitrogen at their center -critical in photosynthesis |
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-use of fertilizers (including nitrogen), pesticides, and irrigation -tripled the green production around the world |
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Synthesis of ammonia to create nitrogen fertilizer. MOST IMPORTANT INVENTION OF THIS CENTURY! -the nitrogen fixation reaction of nitrogen gas and hydrogen gas, over an enriched iron catalyst, to produce ammonia -ammonia is oxidized to turn it into nitrates and nitrites for fertilizers -has made population 2x that that it would have been |
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Stratospheric Destruction |
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Sinks 12.5
±2.5
Tg
N
yr‐1 |
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Father of Gren revolution |
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Norman Borlaug (responsible for high yield crops) did shuttle breeding to start the green revolution |
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How much of annual crop yield goes to animals? |
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7.3 kg of feed, 14% yield |
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1.1 kg of feed, 91% yield |
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Almost all increased production of soybeans in Brazil are going to feed pigs in CHina |
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How much do we need to increase food production? How? |
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We need a 50% increase in food production. We need 50% more land, 50% higher yields (through genetically modified organisms), change diet, have fewer people, waste less food |
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Regrowing in developed areas and disappearing in developing regions |
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More fertilizer won't help in most (developed) places (soil is already saturated with it). Giving 1 bag of fertilizer to each farmer in Malawi increased yield though... |
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Percent of crops that are genetically modified in the US |
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>50%
70% of corn, nearly all of soybeans |
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-GMO corns' modified genes can jump to other native corn breeds (creating a homogenized version of corn) 0Weeds become adapted to our pesticides |
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Logistical. Levels out at a particular carrying capacity |
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How do you find carrying capacity? |
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depends on water, energy, demographics, standard of living, etc. |
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Impact = population x affluence x technology
affluence is consumption/capita technology is impact per unit consumption |
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How do you find future populations? |
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P(e^rt)
P is base value, r is current growth rate, T is years into the future |
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Doubling time for anything exponential |
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Low population: high br and high dr As pop increases: lower dr and high birth rate Large pop: low br and dr |
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births/woman much lower in developed world Theories: -GDP/capita and total fertility rates have a correlation -Education and TFR are correlated as well |
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Juxtaposition of Phosphorus |
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-Phosphorus in soil. -usually taken up by plants, excess bonds to clay and iron minerals |
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10 Ttg to start, weathering has doubled that (20Ttg), we started mining (18.5Ttg), so we in a sense quadrupled the amount of phosphorus inputs. ENDS UP WITH 15.5Ttg of P BEING ADDED TO FRESHWATER AND TERRESTRIAL ECOSYSTEMS |
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Time it takes for 'lost' phosphorus to cycle back |
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Natural rate of weathering: |
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Natural output of Phosphorus vs human output of phosphorus |
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.45 x 10^9 kg/yr naturally we put out 1.9x10^9 kg/yr
UNSUSTAINABLE |
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