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Units of Measurement for Gases |
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Definition
same units as volume: ml,cc,cm3, L |
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Temperature Units of Gases |
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Definition
gases must be measured in Kalvin: C-K= C+ 273 F-K= [(F+40)5/9]-40+273 |
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occurs at 0 K; all molecular motion ceases |
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STP(Standard Temperate Pressure) Conditions |
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Definition
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Definition
atmosphere(atm), milimeters of mercury(mmHg/torr), pounds per in2(psi), kilopascals/kilopaskals(Kpa) |
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Pressure Unit Conversions |
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Definition
1 atm=760 mmHg/torr=14.7 psi=101.3 Kpa |
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defines as force per unit area : P=F/A |
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Definition
pressure that is exerted by the gas molecules in Earth's atmosphere on its surface |
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Dalton's Law of Partial Pressures |
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Definition
total pressures in any enclosed system is = to the total sum of the partial pressures (Pt=P1+P2+P3...Pn) |
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Definition
explains gas behaviors in terms of molecular motion and distance |
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Four Basic Postulates of KMT |
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Definition
1) gas molecules are spaces far apart; gases are mostly empty space 2)gas molecules are in continuous, rapid, and linear motion(average speed of a gas molecule is 1000m/s) 3)pressure exerted by gases is a result of collision of gases(these are perfectly elastic) and no energy is lost 4) increase in temperature will increase the speed of gas molecules |
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Definition
P1*V1=P2*V2(temperature is the constant variable) *pressure is inversely proportional to volume |
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Definition
V1/T1=V2/T2( pressure is the constant variable) *volume ans temperature are directly proportional |
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Definition
P1/T1=P2/T2(volume is the constant variable) *pressure and temperature are directly porportional |
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Molecular Volume of Gases |
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Definition
*at constant temperature and pressure the volume is proportional to the mass * molar volume is = to molar mass/density[(g/mole)/(g/)=L/mole * all gases at the same temperature& pressure have the same molar volume *molecular masses of 2 gases are in the same ratio as their densities (mm1/mm2=d1/d2) |
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Definition
1 mol of any gas under STP conditions will occupy a vol of 22.4L/mole |
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Ideal Gas Law(used when conditions are unchanging) |
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Definition
*assumes vol is proportional to the # of mols, absolute temp; is inversely proportional to pressure |
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PV=nRT(ideal gas aw equation) |
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Definition
P=pressure(atm), V=volume(L), n=# of mols, T=temperature(K), R= gas constant(0.0821) |
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PVM=gRT(alternate for ideal gas law equation) |
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Definition
*n is substituted by g/M(g=total mass of sample, M=molecular mass) |
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Definition
gases behave ideally at high pressure conditions and low temperature conditions |
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Definition
volume ratio is = to the mole ratio in a balanced chemical equation |
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