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photosynthesis 1
photosynthesis: light reactions
9
Biochemistry
Undergraduate 4
04/09/2011

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Term
thylakoid membrane
Definition
site of light photosynthesis. has 4 e- transport complexes. uses NADP as a terminal e- acceptor.
Term
Z scheme
Definition
2 H2O + 2 NADP+ → O2 + 2 NADPH + 2H+ ΔGo’= +440 kJ/mol
Electrons are moving from +Eo’ to –Eo’.
energy is needed to make this favorable.
light energy excites the electron in P680 (PS2) and this electron is transferred to P700 (PS1). another photon excited the e- again and this goes into the Calvin Cycle
Term
chlorophyll a
Definition
cyclic tetrapyrrole similar to heme
co-ordinated Mg atom
Light in wavelength range of 680 to 700 nm is effective in triggering light reactions
Term
accessory pigments
Definition
Accessory chlorophylls and carotenoids absorb photons and pass this energy to the reaction center via resonance
Reaction center is a special pair of chlorophyll molecules bound to a pair of protein subunits
Term
4 enzyme complexes
Definition
PSII, Cyto bf, PSI and ferredoxin-NADP+ reductase
Term
3 intermediate e- carriers
Definition
Plastoquinone (PQ), plastocyanin (Pc), and Ferredoxin (Fd)
Term
plastoquinone (PQ)
Definition
Highly similar to ubiquinone in oxidative phosphorylation
Carries 2e-/mole from PSII to cyto bf
Term
Plastocyanin (Pc)
Definition
Monomeric peripheral membrane protein on thylakoid space (lumen) side of membrane
Contains single Cu atom that carries 1 e-
Carries electrons from Cyto bf to PSI
Term
Ferredoxin (Fd)
Definition
Monomeric peripheral membrane protein on stromal side of membrane
Contains Iron-sulfur cluster (2Fe2S)
Carries electrons from PSI to Fd-NADP+ reductase
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