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Periodicity and Atomic Structure
light, orbitals, etc
20
Chemistry
Undergraduate 1
03/09/2010

Additional Chemistry Flashcards

 


 

Cards

Term
Wavelength
Definition
The distance from one peak to the next measures in m or mm
Term
frequency
Definition

number of peaks that pass a specified point in one second

 

S^-1 OR 1/S OR Hz

Term
equation for wavelength
Definition

λ=C/ν

wavelength=speed of light ÷ frequency

Term
speed of light
Definition
3.00 X 10^8 m/s
Term

Define amplitude.

 

What does amplitude dictate?

Definition

intensity or height of a wave

 

brightness

Term
Types of rays in order from highest energy to lowest
Definition

gamma 10-12

x-rays 10-10

UV 10-8

visible

infrared 10-6

micro 10-4

radio 10-2

(great xylophonists use vintage instruments made rarely)

Term
Heinsberg Uncertainty Principle
Definition
It is impossible to know an electrons position AND momentum at the same time
Term
Ψ
Definition
psi; wave function; refers to the probability of finding an electron is a certain region of space
Term
Each wave function contains four quantum numbers.  What are the four types of quantum numbers?
Definition

principal quantum (n)

angular momentum (l)

magnetic quantum(Ml)

spin quantum (Ms)

Term

principal quantum number

Definition
  • refers to the energy level or size of the orbital
  • shells
  • "n"=1,2,3, etc...
Term
angular momentum quantum number
Definition
  • refers to the 3D shape of the orbital
  • "l"=any value from 0 to (n-1)
  • s=0, p=(0,1) d=(0,1,2) f=(0,1,2,3) g=(0,1,2,3,4).... 

 

Term
magnetic quantum number
Definition
  • defines the orientation of the orbital
  • Ml = ±l
  • ex) if l=3 (or g), Mequals -3,-2,-1,0,1,2,3, which means there are 7 orientations
Term

spin quantum number

Definition

refers to the direction of an electron's spin

 

Ms= +1/2 or -1/2

Term
pauli exclusion principle
Definition
states that no to electrons in the same atom can have the exact same four quantum numbers
Term
where electrons will rest
Definition

1S                                        1S

2S                                        2S 2P

2P 3S                                   3S 3P 3D

3P 4S                                   4S 4P 4D 4F

3D 4P 5S                              5S 5P 5D 5F 5G 

 

Term

orientations of

s

p

d

f

 

Definition

s has one orientation

p has 3 orientations

d has five orientations

f has seven orientations

Term
Noble Gas Configuration
Definition
if you have already written out the electron configuration for an atom of a certain charge, find the noble gas before that atom on the periodic table and then write out only the orbitals of electrons not covered by the noble gas.
Term
rules for writing electron configurations of ions
Definition

for negative ions- add electrons to the highest unfilled orbital. usually electrons are added so that the elctron configuration is the same as the nearest noble gas.

 

for positive ions- remove electrons from the orbital with the highest value of n first. usually, electrons are removed so that the remaining orbitals are either filled or half filled.

Term
isoelectronic
Definition

when a noble gas has the same number of electrons and same electron configuration as an ion

 

ex) Argon is isoelectronic to

S2-, Ca2+, Cl1-

Term
Visible Light Spectrum
Definition

400nm to 700 nm

 

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