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Elements in Groups have... |
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Simultaneously created periodic table idea |
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developed idea of atomic number |
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Mendeleev's prediction of an element based on the periodic table's trends that wasnt discovered then. Later found to be Germanium. |
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1. electrons are attracted to the nucleus and repelled by other electrons 2. Z eff = Z - S, Z is atomic number, s is inner core electrons 3. average electrical feild for one electron |
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How is the size of Atoms determined? |
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1. bonding radii (between covalent bonded nucleii) |
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periods = decreasing due to higher Z eff groups = increasing due to higher n |
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1. nuclear charge AKA how many electrons it has gained/lost 2. number of electrons it has overall 3. what orbitals the electrons are in |
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smaller than parents because outer electrons are removed and thus repulsion goes down |
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larger than parents because electrons are added thus increasing repulsion |
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increases down groups because of an overall increase in size |
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1. same number of electrons 2. sizes go down as charge gets higher because the higher the charge, the more electrons lost |
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1. amount of energy needed to remove otuer electron 2. increases with each new electron removed 3. increases dramatically in inner core electrons |
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Trends in Ionization Energy |
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1. decreases as you go down groups smaller atoms are less willing to give up their electrons 2. increases across periods because of higher Zeff |
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Dicontinuities in Ionization Energy |
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1. easier to remove from p orbitals than s orbitals. 2. easier to remove from filled orbital shells (/\,\/) |
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1. the ease with which an atom gains an electron 2. more (-) an affinity is, the easier it will lose electron 3. (+) affinity is unstable and will not form |
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Trends in Eletron Affinity |
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1. across periods increases 2. same discontinuities as Ionization |
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1. Shiny 2. good conductor of heat and electricity 3. cations in aqueous solutions 4. metal oxides are basic 5. tend to lose electrons 6. malleable |
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1. not shiny 2. brittle 3. poor condutor 4. non-metal oxides are molecular and acidic 5. aniona in aqueous soutions 6. gain electrons |
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1. characteristics of both metals and non-metals 2. e.g. silicon is shinny but a poor conductor and brittle |
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1. soft metallic 2. only compunds in nature 3. decreasing melting points and densities 4. decreasing ionization energies 5. exo rxns with water 6. bright colors in flames 7. rxns with O: Li-nothing, K, Rb,Cs-superoxides, others-peroxides |
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Alkali Earth Metals Trends |
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1. Higher densities and melting points than alkalis 2. lower ionization energues than alkalis 3. rxn-ness increases top to bottom 4. rxn w/ H2O: Mg-Steam only, Be-nothing, everything else easily. |
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1. O,Se,S = non-metals 2. Te = ,etaliod 3. Po = Metal |
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1. 2 allotropes O2, O3 (dioxygen and ozone) 2. 3 anions O-2,O2-2,O2-1 (oxide, peroxide, superoxide) 3. tends to take elctrons |
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1. weaker oxidizer than O 2. allotrop S8 = ring shaped, most stable |
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1. non-metals 2. large (-) affinities 3. easily oxidized 4. react w/ metals = halidies |
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1. large ionization energies 2. (+) affinities 3. unreactive 4. monotomic gases 5. Xe = XeF2, XeF4 and XeF6 6. Kr = KrF2 7. HArF - unstable, synthesized in 2000 |
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Trends in Effective Nuclear Charge |
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1. Periods- increases because the atomic number increases (total electrons) while the s stays the same 2. Groups- stays basically the same |
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Rule for losing electrons (electron configuration-wise) |
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orbitals with lowest n level first ALWAYS, even if 3d does come after 4s. |
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1. Doesnt really belong to any group 2. Very hard to take it's electron --no sheilding effect/repulsion from other electrons |
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