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Periodic Trends
Chapter Seven of Chemistry: The Central Science 9th edition
30
Chemistry
10th Grade
03/01/2009

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Term
Elements in Groups have...
Definition
Similar properties
Term
Mendeleev and Meyer
Definition
Simultaneously created periodic table idea
Term
Mosley
Definition
developed idea of atomic number
Term
What is Eka-Silicon?
Definition
Mendeleev's prediction of an element based on the periodic table's trends that wasnt discovered then. Later found to be Germanium.
Term
Effective Nuclear Charge
Definition

1. electrons are attracted to the nucleus and repelled by other electrons

2. Z eff = Z - S, Z is atomic number, s is inner core electrons

3. average electrical feild for one electron

Term
How is the size of Atoms determined?
Definition
1. bonding radii (between covalent bonded nucleii)
Term
Trends in Atom Size
Definition

periods = decreasing due to higher Z eff

groups = increasing due to higher n

Term
Size of Ions depends on
Definition

1. nuclear charge AKA how many electrons it has gained/lost

2. number of electrons it has overall

3. what orbitals the electrons are in

Term
Size of Cations
Definition
smaller than parents because outer electrons are removed and thus repulsion goes down
Term
Size of Anions
Definition
larger than parents because electrons are added thus increasing repulsion
Term
Trends in Ion Size
Definition

increases down groups because of an overall increase in size

Term
Isoelectric Series
Definition

1. same number of electrons

2. sizes go down as charge gets higher because the higher the charge, the more electrons lost

Term
Ionization Energy
Definition

1. amount of energy needed to remove otuer electron

2. increases with each new electron removed

 3. increases dramatically in inner core electrons

Term
Trends in Ionization Energy
Definition

1. decreases as you go down groups smaller atoms are less willing to give up their electrons

2. increases across periods because of higher Zeff

Term
Dicontinuities in Ionization Energy
Definition

1. easier to remove from p orbitals than s orbitals.

 2. easier to remove from filled orbital shells (/\,\/)

Term
Electron Affinity
Definition

1. the ease with which an atom gains an electron

2. more (-) an affinity is, the easier it will lose electron

3. (+) affinity is unstable and will not form 

Term
Trends in Eletron Affinity
Definition

1. across periods increases

2. same discontinuities as Ionization

Term
Metal Properties
Definition

1. Shiny

2. good conductor of heat and electricity

3. cations in aqueous solutions

4. metal oxides are basic

5. tend to lose electrons

6. malleable

Term
Non-Metals
Definition

1. not shiny

2. brittle

 3. poor condutor

4. non-metal oxides are molecular and acidic

5. aniona in aqueous soutions

6. gain electrons

Term
Metalliods
Definition

1. characteristics of both metals and non-metals

2. e.g. silicon is shinny but a poor conductor and brittle

Term
Alkali Group Trends
Definition

1. soft metallic

2. only compunds in nature

3. decreasing melting points and densities

4. decreasing ionization energies

5. exo rxns with water

 6. bright colors in flames

7. rxns with O: Li-nothing, K, Rb,Cs-superoxides, others-peroxides

Term
Alkali Earth Metals Trends
Definition

1. Higher densities and melting points than alkalis

2. lower ionization energues than alkalis

3. rxn-ness increases top to bottom

4. rxn w/ H2O: Mg-Steam only, Be-nothing, everything else easily.

Term
Chalcogen Trends
Definition

1. O,Se,S = non-metals

2. Te = ,etaliod

3. Po = Metal

Term
Oxygen Trends
Definition

1. 2 allotropes O2, O3 (dioxygen and ozone)

2. 3 anions O-2,O2-2,O2-1 (oxide, peroxide, superoxide)

3. tends to take elctrons

Term
Sulfur Trends
Definition

1. weaker oxidizer than O

2. allotrop S8 = ring shaped, most stable

Term
Halogen Trends
Definition

1. non-metals

2. large (-) affinities

3. easily oxidized

4. react w/ metals = halidies

Term
Trends in Noble Gases
Definition

1. large ionization energies

2. (+) affinities

3. unreactive

4. monotomic gases

5. Xe = XeF2, XeF4 and XeF6

6. Kr = KrF2

7. HArF - unstable, synthesized in 2000

Term
Trends in Effective Nuclear Charge
Definition

1. Periods- increases because the atomic number increases (total electrons) while the s stays the same

2. Groups- stays basically the same

Term
Rule for losing electrons (electron configuration-wise)
Definition
orbitals with lowest n level first ALWAYS, even if 3d does come after 4s.
Term
Hydrogen
Definition

1. Doesnt really belong to any group

2. Very hard to take it's electron --no sheilding effect/repulsion from other electrons

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