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how are elements in the same period arranged? |
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Definition
Each sequential element has one more proton and one electron
(as you go from left to right) |
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how are elements in the same group related ? |
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Definition
they have a same valence config & have similar chemical properties |
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B,Si,Ge, As,Sb,Te,Po are called |
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Term
effective nuclear charge def |
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Definition
as the nucleus becomes ↑ positive,
all electrons experience a stronger pull toward the center.
"how strong a particular element pulls electrons" |
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Term
Why do cations vs (anions /neutral) have a higher effective nuclear charge? |
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Definition
cations: have more protons than electrons, therefore they are strongly attracted to electrons
(aka they really want to get rid of their positive charge).
anions: have more elecs will have a slightly lower effective nuclear charge.
neutral: have an equal # of protons and elecs
(have the lowest eff. nuc charge) |
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Term
Who has a larger effective nuclear charge(Zeff):
Na or Mg? |
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Definition
Mg
effective nuclear charge increaes as you go across elements in the same period. |
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Term
Who will have a bigger prinicipal quantum number H or Fr?
whos electrtons will be held less tightly? |
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Definition
Fr ;
as you go DOWN a grp prinicipal quantum number increases
its valence e- will be held less tightly to nucleus
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Tell who has a bigger atomic radius K or Mn? |
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Definition
K ;
atomic radii decreases as you go across a period
(recall zeff increases) |
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Term
Ionization energy/potential (IE) def |
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Definition
energy required to remove an electron from a gaseous atom or ion
(this requires energy (endothermic)) |
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Term
If the effective nuclear charge is high :
describe the location of the valence e-
the ionization energy
the electron affinity
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Definition
high zeff=
valence e- tightly bound to nucleus
HIGH ionization energy
HIGH electron affinity
(aka it takes it alot energy to remove these electrons) |
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Term
Why is the second ionization energy always higher than the 1st ionization energy? |
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Definition
Recall an element doesn't want to have a postive charge it wants to gain e- in order to have a full octet,
so it takes alot more energy to remove the 2nd e- b/c the element is becoming increasingly positive. |
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Term
Why do grps 1 & 2 have low electron affinties?
Why do grp 7 have high? |
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Definition
grps 1 & 2 (alkali metals &alkali earth metals) need to lose 1 or 2 e- to achieve their octet.
grp 7 (halogens): only need to gain 1 more e- to achieve their octet so they are the greediest. |
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Term
electron affinity def
electronegativity def |
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Definition
1.energy released when atom recieves an electron
*(remember if an element is closer to its octet its energy will be lower hence released , that is a very good thing)
2. is a measure of the attractive force that an atom will excert in an electron in a chemical bond, aka its attraction for bonding electrons |
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what is another name for electronegativity? |
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Definition
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True or False: metals have a low density & high melting points |
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Definition
metals have a high density
high melting point |
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Term
For metals in general give high/low for the following:
zeff (effective nuclear charge)
electronegativity
atomic radius
ionization energy |
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Definition
↓zeff (effective nuclear charge)
↑electronegativity
↑atomic radius
↓ionization energy |
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Term
What do the previous characterisitcs allow metals to do? |
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Definition
donate one or more electrons |
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Term
Why are metals good conductors of heat and electricity? |
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Definition
their valence electrons are not bound tightly, they can move freely. |
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Term
-
For non metals in general give high/low for the following:
zeff (effective nuclear charge)
electronegativity
electron affinity
atomic radius
ionization energy
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Definition
zeff (effective nuclear charge)
↑electronegativity,electron affinity
↓atomic radius
↑ionization energy |
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True or False:
Non metals are good conductors of electricity and heat |
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Definition
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Which metals are the most reactive? |
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Definition
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alkali metals typically have an oxidation state of? |
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Definition
+1
(they often lose 1 e- to complete their octet) |
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what is the oxidation state of alkaline earth metals |
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Definition
+2
(they like to lose 2 electrons in order to complete their 'octet')
"full outer shell" |
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Definition
-1
(prefer to gain 1 e- to complete their octet)
*remember they have 7 electrons |
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true or false: halogens have the highest electronegativities |
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Definition
yes, remember they only need one more e- to complete their octet |
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Term
Noble gases:
Why are they stable?
tell high/low:
ionization energy
electronegativites |
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Definition
their valence shell is complete (8e-)
↑ionization energy
almost zero electronegativites |
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Term
describe the oxidation states of transition metals
give 2 ex |
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Definition
transition metals have many positive oxidation states
Fe: +1 ,+2
Mn: +2,+3,+6,+7 |
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Term
transition metals have many positive oxidation states, what does this allow them to do? |
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Definition
form many differnt ionic compounds
ex hydration complexes (water)
highly colored solutes and compounds(enchances the low solubility of some compounds) |
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Term
hemogloblin has what significance regarding this chapter? |
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Definition
hemogloblin features Fe which changes it state in order to carry out its fcn. |
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Term
Why does P have a lower electron affinity than Si?
(this goes agaist the periodic table trend ) |
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Definition
P's electronegativity gives a very stable half filled p oribital
vs
Si only needs 1 more electron to fill its p orbital and therefore is very greedy. |
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Term
the grp next to the halogens is called |
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Definition
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Term
which will have a bigger atomic radius?
anion or cation vs a neutral atom |
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Definition
K- (bigger)
than K
b/c its has gained more e- |
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