Term
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Definition
oxidation of alkene via 1. Br2/CCl4 which halogenates alkene
2. NaNH2 |
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Term
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Definition
reduction of alkyne
H2/Lindlar for cis
Na/NH3 for trans via radicals
E2 from alkane halide
dehydrate an alkane alcohol with H2SO4 |
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Term
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Definition
hydrohalogenate an alkene
add HX to alcohol, which makes h2o better leaving group and then X adds to carbocation |
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Term
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Definition
hydrate an alkene with H2SO4 and H2O
oxymercuration with Hg(OAc)2, H2O, and NaBH4
hydroboration oxidation for non markovnikovs |
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Term
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Definition
| add OsO4 to alkene with tBuOOH |
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Term
| alkane with hydroxide and Br2 |
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Definition
| add Br2 and H20 to alkene for Br then backside attack from water |
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Term
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Definition
| add strong base to alkyne which removes hydrogen |
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Term
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Definition
| hydration of alkyne with HgSO4, H2O, and H2SO4 via oxymercuration and hydration. C=C double bond undergoes tauterimazation. |
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Term
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Definition
| hydroboration-oxidation with BH3, THF and H2O2, OH- of alkyne for non-markovnikov addition of OH-. C=C double bond tauterimerizes |
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Term
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Definition
| add strong base NaNH2 to alkyne which creates carbon anion and then add organic compound with halide, and carbon anion backside attacks, kicking off the halide. |
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Term
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Definition
| oxidation of alkene via 1. Br2/CCl4 which halogenates alkene |
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Term
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Definition
| hydrohalogenation of alkyne with H-X |
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Term
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Definition
| alkene split by ozonolysis O3/ Me2S |
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Term
| alkane with halide on less substitued |
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Definition
| add HBr and HOOH to alkene for non-markovnikov via radicals |
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