Shared Flashcard Set

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ORGO Final
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16
Chemistry
Undergraduate 1
04/29/2013

Additional Chemistry Flashcards

 


 

Cards

Term
Hydrogenation
Definition

Syn addition

 

add 2H's

 

H2, pt

Term
Hydrohalogenation
Definition

markovnikov

rearrangement

 

add a H and X

Term
Hydration
Definition

markovnikov

rearrangement

 

add OH and H

Term
Halogenation
Definition

anti-addition

 

add 2X's

Term
Hydroboration-Oxidation
Definition

anti-markovnikov

syn addition

 

add OH and H

Term

Acid catalized hydration

 

Definition

rearrangement

markovnikov

 

H2SO4/H20

 

add OH and H

Term
Oxymercuration-reduction
Definition

no rearrangement

markovnikov

 

Hg(OAc), H20/ NaBH4

 

add OH and H

Term
Hydrobromo Oxidation
Definition

no rearrangement

non markovnikov


BH3/ H2O2, NaOH


add OH and H

Term
HBr addition
Definition

markovnikov

rearrangement

 

add H and Br

Term
HBr with peroxide
Definition

non markovnikov

 

HBr/ peroxide

 

add H and Br

Term
Br2 addition
Definition

anti addition

 

/CH2Cl2

 

add 2Br or 2Cl

Term
HOBr- halohydrin
Definition

Markovnikov

anti addition

 

Br2, H20/

 

Add OH and Br

 

OH is more electronegative

Term
Allylic Bromination
Definition

H and Br exchange

 

CH2 Cl2/ HV

Term
OSO4
Definition

syn addition

no rearrangement

 

2OH is added on the double bond

Term
Ozone
Definition

cleaves double bond and adds carbonyls in place

 

O3/ (CH3)2S

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