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| Carbohydrates w/ 4 chiral centers mnemonic |
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Definition
| All altruists gladly make gum in gallon tanks |
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| Carbohydrates w/ 3 chiral centers mnemonic |
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Alpha halogenation
(what -> what, reagents) |
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Definition
carbonyl -> halocarbonyl
acetic acid, H2O |
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Aldol condensation
(what -> what, reagents) |
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Definition
2 carbonyls -> aldol
1. -OH
2. H+ |
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Aldol dehydration
(what -> what, reagents) |
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Definition
aldol -> alkene carbonyl
H2SO4, H2O |
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Aldol reduction
(what -> what, reagents) |
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Definition
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Claisen condensation
(what -> what, reagents) |
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Definition
Ester -> ester with carbonyl on it
1. -OR
2. H+ |
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Azide alkylation
(what -> what, reagents) |
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Definition
Azide -> primary amide
1. RX
2. LAH
3. H+ |
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Secondary aliphatic amine substitution
(what -> what, reagents) |
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Definition
Secondary amine -> R2NN=O
NaNO2, HCl |
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Tertiary aromatic amine substitution
(what -> what, reagents) |
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Definition
Tertiary aromatic amine -> ortho and para nitro tertiary aromatic amine
NaNO2, HCl |
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Primary aromatic amine substitution
(what -> what, reagents) |
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Definition
Primary aromatic amine -> Diazonium salt
NaNO2, HCl |
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Hoffman elimination
(what -> what, reagents) |
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Definition
Primary amine -> Alkene
(least substituted double bond selectivity)
1. Excess CH3I
2. Ag2O, H2O
3. heat |
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Michael Reaction
(what + what, reagents) |
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Definition
Dicarbonyl + alpha, beta unsaturated carbonyl
1. NaOEt
2. alpha, beta unsaturated carbonyl
3. EtOH |
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Acetal formation of carbohydrates
(what -> what, reagents) |
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Definition
carbohydrate -> glycoside
CH3OH, H+ |
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Reduction of carbohydrates
(what -> what, reagents) |
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Definition
carbohydrate -> alditol
1. NaBH4
2. HCl, H2O |
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