Term
| what makes carbon so special in reactions |
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Definition
tetravalence for carbon to bond ionically it would have to give up or take 4 e- it shares four ways instead |
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Term
| how do you find the outer most electrons of an atom? |
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Definition
| take the highest "coefficients" of the spdf and count up the electrons here |
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Definition
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Definition
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Definition
| 1 s orbital + 3 p orbitals |
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Term
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Definition
(1 s orbital+ 2 p orbitals) + 1 unchanged p |
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Definition
(1 s orbital + 1 p orbital ) + 2 unchanged p |
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Term
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Definition
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Term
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Definition
sp3 but one loop is lone electrons that dont usually wanna bond with anything else |
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Term
| electronegativity pattern |
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Definition
HIGHEST at flourine lessons moving diagonally down to right |
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Term
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Definition
[product] --------- [starting] |
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Definition
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Definition
lower pKa-->stronger acid logKa |
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Definition
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Definition
bronsted-lowry acid: proton donor base:proton acceptor lewis acid:electron acceptor base:electron donor |
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Term
determiners of Lewis acids/bases |
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Definition
Base: extra electrons Acid: vacant--low energy bond, polar bond to H also B and Al (with three bonds) can stretch to make room for another--like a vacant orbital -->acids |
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Term
| what is the amount of rotation for comformational analysis? |
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Definition
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Term
| tortional vs steric strain |
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Definition
steric=bulk such as gauche tortional=eclipsing.bending.torting |
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Definition
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Term
how much E is needed for a chair-chair conversion of cyclohexane? |
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Definition
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Term
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Definition
angle between two H's on a molecule to find, use Newman projection and divide up like a pie |
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Term
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Definition
| gauche like interaction between Hydrogens that are two carbons apart in cyclohexane |
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Term
| what are the two broadest types of reaction and how do we differeniate between them |
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Definition
radical: heterolytic cleavage Polar Covalent: homolytic cleavage |
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Term
| steps to radical reaction |
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Definition
initiation propagation termination |
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Term
| what types of G figures are there for describing reactions? |
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Definition
G noght: change in overall free energy (start point--finish point difference) delta G: describes individual steps G daggar: energy of activation |
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Term
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Definition
| interaction between empty C orbitals and alpha hydrogens |
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Term
| what are the two ways to rearrange carbacations? |
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Definition
hydride shift methyl migration |
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