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Organic Chemistry Final Exam
final exam flashcards iowa state fall 10
15
Chemistry
Undergraduate 2
12/14/2010

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Term
R configuration
Definition
Right turn, clockwise configuration
Term
S configuration
Definition
Left turn, counterclockwise configuration
Term
Alkyne + HX ->
Definition
Alkene with H and X on separate carbons
Term
E configuration
Definition
opposite sides of the double bond, can't twist
Term
Z configuration
Definition
ze zame zide of the double bond, can't twist
Term
Alkene to halohydrin (1,2-halo alcohol)
Definition
Add X2 over water, or NBS over water and DMSO
Term
Alkene to alcohol
Definition
add water, H3PO4 catalyst at 250 deg. celcius
Term
alkene to alkane
Definition
Add H2 and a catalyst
Term
alkene to 1,2-diol
Definition
Add Cl2 over water to get halohyrdin, next add base over water, next add hyrdronium (trans)
Term
alkene to carbonyl compound
Definition
Add 1) ozone over 2) zinc and hydronium
Term
alkene to halide
Definition
Add HX
Term
alkene to cyclopropane
Definition
add CHCl3, KOH
Term
alkene to epoxide
Definition
Add Cl2 over water to get halohydrin, next add base over water
Term
alkene to 1,2 dihalide
Definition
Add X2
Term
Hydroboration
Definition
Adding BH3 over THF catalyst, then adding peroxide and hydroxide to give an addition alcohol reaction
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