Shared Flashcard Set

Details

Opt 213 Biochem
Carbohydrates
38
Other
Not Applicable
10/23/2007

Additional Other Flashcards

 


 

Cards

Term
What is a Schiff base?
Definition

A functional group that constains a Carbon Nitrogen double bond the a an aryl or alkyl group attached the Nitrogen but not a Hydrogen

Term
What does glucose bind with to form the green complex in determining the relative amount of glucose in the blood and the urine?
Definition
o-toluidine
Term
What two sugars make up lactose?
Definition

Beta-Galactosyl (1-4) Beta-Glucose

Term
What two sugars make up maltose?
Definition
alpha-glucosyl (1-4) Beta-Glucose
Term
What two sugars make up sucrose?
Definition
alpha-glucosyl (1-2) Beta-Fructose
Term
What is the preferred term for saccharides of more than 10 units?
Definition
polysaccharides or glycan
Term
What are the two most common storage forms of carbohydrates in plants?
Definition
amylose and amylopectin
Term
Which plant storage polysaccharide has no alpha 1-6 linkages?
Definition
amylose
Term
Which storage polysaccharide has more alpha 1-6 linkages, amylopectin or glycogen?
Definition

glycogen, these alpha 1-6 linkages occuring every 6-21 carbons are what allows the glycogen molecule to be very compact

Term
In what part of the liver or muscle cell is glycogen stored?
Definition
the cytoplasm
Term
Name two types of cells in the eye that maintain glycogen stores?
Definition
corneal epithelial cells and retinal Mueller cells
Term
Name two types of cell in the eye that do not store glycogen?
Definition
corneal endothelial cells and the retinal photoreceptors
Term

In what conditions can the use of proteins and lipids to make ATP be patholoical to tissues due to being excessive?

Definition
diabetes or starvation
Term
Which reactions in carbohydrate metabolism occur in the cytoplasm of the cell?
Definition
Up to the generation of ATP all reactions occur in the cytoplasm of the cell.  After that, they all occur in the mitochondria.
Term

What is the purpose of the first step of glycolysis, when the carbohydrate is phosphorylated by hexokinase?

Definition
to keep the carbohydrate inside the cell
Term
Where does glyceraldehyde 3 phosphate get its phosphate group?
Definition

Free phosphate in the cytoplasm, not ATP

Term
What causes swelling in the eye and other tissues as a result of increased glycolysis under anerobic conditions?
Definition
increased lactate concentration in epithelial tissues and anterior stromal tissues of the cornea
Term
Would you expect a cell with a partial Oxygen pressure of 155 mm Hg to be swollen?
Definition
no, but at night or during hard contact lens wear the partial pressure of oxygen can dip to 55 mm Hg
Term
What are the best contacts to keep oxygen pressure higher?
Definition
Rigid Gas Permeable>Soft lens>hard contact lens
Term
Where does the Krebs cycle occur?
Definition
mitochondrial matrix
Term
What is the primary purpose of the Kreb's cycle in energy production?
Definition

to supply electrons for the production of ATP

Term
How many reactions occur in one turn of the Kreb's cycle?
Definition
nine
Term
How many carbons are lost as CO2 in one turn of the Kreb's cycle?
Definition
2
Term
Which lipid soluble quinone wiht a long hydrocarbon tail shuttle electrons shuttles electrons between protein complex 1 and 3 and also between protein complex 2 and 3 as separate reactions in the inner membrane of the mitochondria?
Definition
Coenzyme Q
Term
What small lipophilic protein (13,000 D) shuttles electrons between protein complex III and protein complex IV in the inner layer of the mitochondria?
Definition
cytocrhome C
Term
Which molecule ferries electrons to protein complex 1in the inner membrane of the mitochondria?
Definition
NADH, with NAD+ given off
Term
What molecule ferries electrons to protein complex II in the mitochondria?
Definition

FADH with FAD given off

Term
What is the energy gained in protein complexes 1, 3, and 4 used to do in the inner membrane of the mitochondria?
Definition
Pump H+ ions from the matrix to the inter membrane space of the mitochondria to create an electrochemical gradient
Term
What protein complex is ATP synthase?
Definition
Protein complex 4
Term
How many protons need to pass from the intermembrane space of the mitochondria to the matrix through ATP synthase (complex 5) to create 1 molecule of ATP?
Definition
3 H+
Term
How many ATP are produced from the movement of 2 electrons from NADH to water?
Definition
3 molecules of ATP
Term
How many ATP are produced by the movement of 2 electrons from FADH2 to water?
Definition
2 molecules of ATP
Term
How many electrons are pumped out of the inner mitochondrial membrane when NADH2 is the source?
Definition
9 H+
Term
How many electrons are pumped out of the inner membrane when FADH2 is the source?
Definition
6 H+
Term

What molecule is borrwowed from the Embden Meyerhoff pathway by the reaction with NADH?

Definition
Dihydroxy acetone phosphate which is converted to glycerol 3 phosphate by glycerol 3 phosphate dehydrogenase.
Term
Where does the glycerol 3 phosphate shuttle take place?
Definition
the brain cells and muscle cells
Term
Where does the malate aspartate shuttle commonly occur in the body?
Definition
liver, kidney, and heart
Term
Name one important difference in the glycerol phosphate and malate aspartate shuttles?
Definition
The final electron acceptor in the malate asparatate is NADH rather than FADH2 allowing the cell to gain an additional ATP from each two carbon electron donor.
Supporting users have an ad free experience!