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OpenStax Chemistry: Atoms First 2e Chapter 3 Key Terms
Chapter 3 Key Terms
74
Chemistry
Undergraduate 1
02/01/2022

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Term
actinide
Definition
inner transition metal in the bottom of the bottom two rows of the periodic table
Term
alkali metal
Definition
element in group 1
Term
alkaline earth metal
Definition
element in group 2
Term
atomic orbital
Definition
mathematical function that describes the behavior of an electron in an atom (also called the wavefunction)
Term
Aufbau principle
Definition
procedure in which the electron configuration of the elements is determined by
Term
Bohr
Definition
structural model in which an electron moves around the nucleus only in circular orbits, each with a specific allowed radius
Term
chalcogen
Definition
element in group 16
Term
continuous spectrum
Definition
electromagnetic radiation given off in an unbroken series of wavelengths (e.g., white light from the sun)
Term
core electron
Definition
electron in an atom that occupies the orbitals of the inner shells
Term
covalent bond
Definition
attractive force between the nuclei of a molecule
Term
covalent compound
Definition
(also, molecular compound) composed of molecules formed by atoms of two or more different elements
Term
covalent radius
Definition
one-half the distance between the nuclei of two identical atoms when they are joined by a covalent bond
Term
d
Definition
region of space with high electron density that is either four lobed or contains a dumbbell and torus shape; describes orbitals with
Term
degenerate orbitals
Definition
orbitals that have the same energy
Term
effective nuclear charge
Definition
charge that leads to the Coulomb force exerted by the nucleus on an electron, calculated as the nuclear charge minus shielding
Term
electromagnetic radiation
Definition
energy transmitted by waves that have an electric-field component and a magnetic-field component
Term
electromagnetic spectrum
Definition
range of energies that electromagnetic radiation can comprise, including radio, microwaves, infrared, visible, ultraviolet, X-rays, and gamma rays
Term
electron affinity
Definition
energy change associated with addition of an electron to a gaseous atom or ion
Term
electron configuration
Definition
listing that identifies the electron occupancy of an atom
Term
electron density
Definition
a measure of the probability of locating an electron in a particular region of space, it is equal to the squared absolute value of the wave function
Term
endothermic
Definition
processes that increase the energy of an atom and involve the absorption of light
Term
excited state
Definition
state having an energy greater than the ground-state energy
Term
exothermic
Definition
processes that decrease the energy of an atom and involve the emission of light
Term
f
Definition
multilobed region of space with high electron density, describes orbitals with
Term
frequency (?)
Definition
number of wave cycles (peaks or troughs) that pass a specified point in space per unit time
Term
ground state
Definition
state in which the electrons in an atom, ion, or molecule have the lowest energy possible
Term
group
Definition
vertical column of the periodic table
Term
halogen
Definition
element in group 17
Term
Heisenberg uncertainty principle
Definition
rule stating that it is impossible to exactly determine both certain conjugate dynamical properties such as the momentum and the position of a particle at the same time. The uncertainty principle is a consequence of quantum particles exhibiting wave
Term
hertz (Hz)
Definition
the unit of frequency, which is the number of cycles per second, s?1
Term
Hund
Definition
every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin
Term
inert gas
Definition
(also, noble gas) element in group 18
Term
inner transition metal
Definition
(also, lanthanide or actinide) element in the bottom two rows; if in the first row, also called lanthanide, or if in the second row, also called actinide
Term
ionic bond
Definition
electrostatic forces of attraction between the oppositely charged ions of an ionic compound
Term
ionic compound
Definition
compound composed of cations and anions combined in ratios, yielding an electrically neutral substance
Term
ionization energy
Definition
energy required to remove an electron from a gaseous atom or ion
Term
isoelectronic
Definition
group of ions or atoms that have identical electron configurations
Term
lanthanide
Definition
inner transition metal in the top of the bottom two rows of the periodic table
Term
line spectrum
Definition
electromagnetic radiation emitted at discrete wavelengths by a specific atom (or atoms) in an excited state
Term
magnetic quantum number (ml)
Definition
quantum number signifying the orientation of an atomic orbital around the nucleus
Term
main-group element
Definition
(also, representative element) element in groups 1, 2, and 13
Term
metal
Definition
element that is shiny, malleable, good conductor of heat and electricity
Term
metalloid
Definition
element that conducts heat and electricity moderately well, and possesses some properties of metals and some properties of nonmetals
Term
molecular compound
Definition
(also, covalent compound) composed of molecules formed by atoms of two or more different elements
Term
monatomic ion
Definition
ion composed of a single atom
Term
noble gas
Definition
(also, inert gas) element in group 18
Term
node
Definition
any point of a standing wave with zero amplitude
Term
nonmetal
Definition
element that appears dull, poor conductor of heat and electricity
Term
orbital diagram
Definition
pictorial representation of the electron configuration showing each orbital as a box and each electron as an arrow
Term
oxyanion
Definition
polyatomic anion composed of a central atom bonded to oxygen atoms
Term
p
Definition
dumbbell-shaped region of space with high electron density, describes orbitals with
Term
Pauli exclusion principle
Definition
specifies that no two electrons in an atom can have the same value for all four quantum numbers
Term
period
Definition
(also, series) horizontal row of the periodic table
Term
periodic law
Definition
properties of the elements are periodic function of their atomic numbers
Term
periodic table
Definition
table of the elements that places elements with similar chemical properties close together
Term
photon
Definition
smallest possible packet of electromagnetic radiation, a particle of light
Term
pnictogen
Definition
element in group 15
Term
polyatomic ion
Definition
ion composed of more than one atom
Term
principal quantum number (n)
Definition
quantum number specifying the shell an electron occupies in an atom
Term
quantum mechanics
Definition
field of study that includes quantization of energy, wave-particle duality, and the Heisenberg uncertainty principle to describe matter
Term
quantum number
Definition
number having only specific allowed values and used to characterize the arrangement of electrons in an atom
Term
representative element
Definition
(also, main-group element) element in columns 1, 2, and 12
Term
s
Definition
spherical region of space with high electron density, describes orbitals with
Term
secondary (angular momentum) quantum number (l)
Definition
quantum number distinguishing the different shapes of orbitals; it is also a measure of the orbital angular momentum
Term
series
Definition
(also, period) horizontal row of the period table
Term
shell
Definition
atomic orbitals with the same principal quantum number,
Term
spin quantum number (ms)
Definition
number specifying the electron spin direction, either
Term
subshell
Definition
atomic orbitals with the same values of
Term
transition metal
Definition
element in groups 3
Term
valence electrons
Definition
electrons in the high energy outer shell(s) of an atom
Term
valence shell
Definition
high energy outer shell(s) of an atom
Term
wave
Definition
oscillation of a property over time or space; can transport energy from one point to another
Term
wavefunction (?)
Definition
mathematical description of an atomic orbital that describes the shape of the orbital; it can be used to calculate the probability of finding the electron at any given location in the orbital, as well as dynamical variables such as the energy and the angular momentum
Term
wavelength (?)
Definition
distance between two consecutive peaks or troughs in a wave
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