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Geography
Undergraduate 3
10/22/2010

Additional Geography Flashcards

 


 

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Term
Argillic
Definition

-Accumulation of silicate clays(illuviated or formed in place)

-Reddish, waxy, translocated(proof of illuvation)

-Not completely 1:1 clays

-Forms waxy clay coats.

 

Term
Natric
Definition

-2:1 clay rich

-lots of sodium; natrium is latin for sodium.

-Arid/Semi arid areas.

Columnar Structure

Term
Kandic
Definition

-Clay rich; All 1:1 Clays(Kalonite)"K-Horizon"

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Term
What are the 3 clay-rich subsurface horizons?
Definition
-Argillic, Natric, Kandic
Term
What are the 2 organic colloids?
Definition
Spodic & Sombric
Term
Spodic
Definition

-Illuvial Horizon: Accumulation of colloidal organic matter & ALUMINUM OXIDE!

-Where: Found in Highly leached forest soils of cool humid climates.

Term
Sombric
Definition

Illuvial Horizon: Accumulation of organic matter

-Dark color

Low BASE SATURATION

-Where: Cool moist soils of high plateaus & Mtns in TROPICS.

Term
Oxic Horizon
Definition

Old, thick soil.

-Extremely weathered only iron & aluminum oxides left behind.

-Gibbsite/Goethite dominated.

Term
Albic
Definition

Special horizon between A & B.

(Adnormal LIGHT color A horizon)

-Light color because clay & iron oxides have been removed.

-Texture defined by leftover sand/silt particles.

 

Term

What are the 3 salt rich horizons?

 

Definition

Calcic, gypsic, salic

-evaporaion of water(deserts), accumulates in B horizon, no rain to wash it(eluviate) down.

Term
Calcic
Definition

-Most common

-CALCIUM CARBONATE

-Color:White

-Acid poured on it makes bubbles.

Term
Gypsic
Definition

-Calcium Sulfate

-Heavy source of sulfate required nearby

 

Term
Salic
Definition

-Salt(Sodium Chloride)

-Found in arid regions.

 

Term
What are the soil moisture regimes?
Definition

Aquic-Fully underwater, no oxygen(Tidal Marshes)

"Ud"ic- Not dry more than 90 days/yr, humid climate(heavy rainfall)

Ustic- In between Arid/Udic, suitable for plant growth, 3 months or more of rainfall, dry summer.

Aridic- Dry, desert, hot, 50% or more of yr.

Xeric- Mediterranean climate, moist cool winter, warm dry summer

 

Term
Entisol
Definition

NEW, little development(USUALLY OCHRIC EPIDON)

 

Term
Alfisols
Definition

-Rich Organic Matter, FERTILE(Forest vegatation)

-CLAY accumulation-Moderately leached(Whitish A horizon)

-HIGH SATURATION

 

 

Term
Andisols
Definition

-Think Andes Mtns(Volcanic)

-Melanic Epipedon

 

Term
Aridisols
Definition

-Arid/Dry regions

-Salt-rich subsurface horizons

-Some clay-rich

-1/3 of Earth

-Suborders: calcids(calcium), gypsic, salic

Term
Gelisols
Definition

-Frozen, permafrost, frost churning.

-Suborders include: histels, orthels(no specific feature), Turbels(cryoturbation- churns soil)

Term
Histosol
Definition

-Histology: Study of tissues

-ORGANIC RICH!

-Marshes, bogs or used to be

-Lots of PEAT, 0 horizon accounts for over 1/2 of soil.

Suborders: Fibrist:plant fibers, Folist:leaves, Hemist:fibers partly decomposed, saprist:not recognizable.

Term
Cambric horizon
Definition

-Subsurface horizon w/ loamy very fine sand or smaller

-some weatherable minerals

-CHARACTERIZED by alteration or removal of mineral material.

-not enough illuviation to be argillic or spodic. Weakly developed, few characteristics.

Term
Inceptisols
Definition

-Young, new soil but not as new as entisols.

-Very little illuviation

-Too weak to classify in another order.

-Ochric horizon/umbric epipedon

 

Term
Mollisols
Definition

Dark, soft, high base saturation

-Grassland soil, fertile from roots.

Term
Oxisols
Definition

Warm/wet(tropical climates)

-Very old, weathered.

 

Term
Spodosols
Definition
-ACIDIC(Pine forests), Humid/cool temp.
-subsurface illuvial accumulationof organic matter & iron/aluminum.
Term
Ultisols
Definition

-HIGHLY WEATHERED/LEACHED

-LOTS of 1:1 Clays(Red clay soil), Kandic horizon

-Low Base Saturation

-Bad soil for agriculture

 

Term
Vertisols
Definition

-LOTS of Shrink/Swelling: Churns soils.

-2:1 Clays

-LOTS of cracks

 

Term
What are the most common minerals?
Definition
Silicates(quartz), carbonates(Calcite), Oxides(hematite), suflides(pyrite), sulfates(gypsum)
Term
What is a mineral
Definition
Naturally occuring, solid crystalline substance that is inorganic w/ specific chemical composition.
Term
Carbonic Acid
Definition
Main agent responsible for chemical weathering reactions along side water.
-Produced by rainwater that reacted w/ CO2 in atmosphere.
-H20 + CO2 -> H2CO3(Carbonic Acid)-> H+ + HCO3-(bicarbonate ion). H+(being a small ion; See isomorphic Substitution, can easily enter crystal structures, releasing other ions into the water.
Term
Hydrolysis
Definition
H+ or OH- replaces ion in mineral.
Term
Oxidation
Definition
O2 reaction minerals to change state of an ion.
-Electron transferred from IRON TO OXYGEN, MAKING IRON POSITVIVE ION.
-VERY BRITTLE, CHEMICAL WEATHERING.
-Common in iron bearing minerals since it has several oxidation states: Fe, Fe+2, Fe+3
Term
Clorpt Equation
Definition
Soils = (Cl)imate + (O)rganisms + (R)elif or Terrain(elevation/slope) + (P)arent material + (T)ime.
Term
What is Gibbsite? Why is it important?
Definition
-Building block of clays:Forms stacked sheets of linked octahedrons of aluminum hydroxide w/ +3 charge. This bonds to six octahedrons w/ -1 bonds. CREATES "Glue" to keep sheets together. -Found sandwiched between silicate sheets in clay:Illite,kaolinite,montmorillinite.

-Aluminum hydroxide; Al(OH)+3

-0:1 Clay, what all minerals eventually weather down to, aluminum all that remains.

-ACCUMULATES IN B ZONE.

 

-

Term
What is the difference between 2:1 & 1:1 Clays
Definition

-Both clays are silica/aluminum bonds

 -1:1 clays have stronger(Hydrogen) bond(i.e. Kaolinite), no shrink/swelling, MADE CLEAN(no charge)

-2:1 clays use van der waals forces(electrostatic charge between chains w/ lots of surface area for contact.)

 

Term
Isomorphic Subsitution
Definition

-Occurs during C. weathering.

-If clay is negatively charged then it attracts positive(cations

-Ex. of 4 balls squeezed togeter w/ space in middle. Small balls= small space, vise versa.

-Space= Tetrahedral/octohedral site(will have larger site)

-More Oxygen = larger size in middle(octo bigger than tetra)

-More Subsitutions = more negative, can't go positive

-Si, Al, Mg, Fe

Term
Importance of Isomorphic Subsitution
Definition

Primary source of positive & negative changes in clay.

-I.e. Mg+2 can replace Al+3(similar size) = -1 Net Charge

***2:1 Clays use Isomorphic subsitution, 1:1 Clays have almost no charge.

Term
Smectite
Definition

-Group of 2:1 expanding clays

-SHRINK/SWELLS ALOT

-This is due to the bond, Van der waals force, being so weak that water gets inbetween and expands.

-Different bonds= different shrink/swells

-Different analogies for oreo cream bond: Ex. Montmorilinite(Mayo)= Water Polarity

-Not a smectite(Has strong bonds)= Illinite IS A MICA(Peanuts make me ill)=Potassium or Vermiculture(Worm Magazine)= Magnesium

Term
Bowen's Reaction on stability of minerals
Definition

-Shows stability of minerals through melting; More complex mineral = higher melting pt.

-In order of least to most complex:-Olivine -> Pyroxene -> Amphibole -> Biotite(mica) -> Quartz

-Shows that minerals like stability @ different temperatures.

-Ex. Olivine stable hot/not cold(unstable= try to change in Chem reaction w/ water)

-Discontinuous: Mafic-Low SiO4(Silicate tetrahedrals)

-Continuous: Feldspar-High SiO4

 

 

 

Term
What is difference between Physical & Chemical Weathering? How do they work together?
Definition

-Physical likes cold/dry, Chemical likes warm/wet

-Physical caused by physical interactions, chemical through chemical reactions on surface.

-Physical weathering opens up new surface area for chemical weathering; Chemical allows rocks to break by weakening bonds.

Term
Le Chatelier's Principle
Definition

-Used to predict effect of change in conditions on chemical equilibrium

-A always wants to equal B (A->B)

-Any change in status quo prompts an opposing reaction in responding system.

-If a change is imposed on a system at equilibrium, the position of the equilibrium will shift in a direction that tends to reduce the effect of that change.

Term
Chelation
Definition

-Means "Claw", forms protective lobster claw around metals. Cationic micronuitrients reacting w/ certain organic molecules(humic acid) to form chelates.

-Increases availability of metallic nuitrients/Protects from leaching.

-Forms protective ring, still accessible by plants.

-Protects IRON

-Common chelators: HUMIC ACID/Proteins -Used to clear up pollutants in soils, i.e. heavy metals like Oil spills.
Term
Mollic
Definition
HIGH BASE SATURATION, Soft, organic, C-Rich,grassland soil(very fertile)
Term
Umbric
Definition
Umbrella- Dark/shaded; LOW BASE SATURATION(Umbrellas don't saturate);
-Grasslands depleted of cations, HIGH RAINFALL(Illuviation/Leaching)
-PARENT MATERIAL LOW IN CALCIUM/MAGNESIUM.
Term
Ochric
Definition
Ostrich(egg)- Pale
-Catch all term:stuff that doesn't fit into other epipedons
-too thin or light or low in organics to be mollic/umbric,
-Ex. Sand dune w/ some surface change.
Term
Melanic
Definition
Melanin- Black, black due to HIGH ORGANIC MATTER
-Volcanic soils.
-LIGHT & FLUFFY
-Made of glass not crystalline clays
Term
Histic
Definition
Histos= Tissue
-HIGHLY ORGANIC- PEATS
-Thick O Horizon 50 PERCENT OR MORE!
-Formed in wetlands, anaerobic areas.
Term
Plaggen
Definition
PLOWED LAND
Term
What are the soil temperature regimes?
Definition
In order of cold to hot: Cryic(Almost permafrost; commonly churned by frost), Frigid, Mesic, Thermic, hypothermic.
-If "Iso" precedes name then summer/winter differ by less than 6 degrees celcius.
Term
Humic & Fulvic acids
Definition
-Formed by organisms(messy eaters)
-eat leaves/roots/organic debris.
-They take simple molecules like sugar(glucose), proteins, amino acids & make them complex(Humic/Fulvic acid).
-Used to move Fe & Al(usually insoluble) through Kilation.
-Humic acid/not soluble, Fulvic acid/soluble- makes tea brown!
Term
chelation(Importance of Humic/Fulvic acids)
Definition
-Makes Al+3 & Fe+3 soluble by using the organic acids(humic/fulvic) produced by organisms.
-Breaks down metals by oxidizing them.
Term
How are clays translocated?
Definition
MUST HAVE PRESENCE OF WATER!: Move w/ water through pore spaces(must be big enough).
-Must be weathered(precipitation), have low base saturation.
-Illuviates from upper layers down to B horizon, can cause drainage problems w/ accumulation.


-
Term
What is the difference between Flocculation and Disperal?
Definition
Flocculation is when a bunch of individual clay particles attach together to make aggreagates of big particles through van der waals forces. Occur in high base saturation areas because there is not enough repulsion to separate the cations.
-Disperal is opposite of flocculation, occurs in leached soils w/ low base saturation & high acidity. The organic acids(H+) get between the van der waals forces of clays, dispersing them from one another. clays separate/dispers Soils w/ low NA = large clay aggregates & vise versa.
Term
Laeritic Soil profile
Definition
-OXIC HORIZON(HIGHLY WEATHERED)
-Wet/hot environments(Most primary minerals washed out, illuviated)
-Rich in Al & Iron oxides
-VERY LOW BASE SATURATION
-EQUATORIAL/TROPICAL SOIL- MUST BE VERY OLD IN ADDITION TO TROPICAL.
-Nuitrients in soil do not replenish; Biomass retains them so they are not illuviated. Leaf falls, gets eaten fast.
Term
Samm
Definition
Sand
Term
Torri
Definition
Hot
Term
"Alb"
Definition
Albino-White, presence of Albic horizon.
Term
Fluv
Definition
Flood plain
Term
Orth
Definition
Common ones
Term
Vitr
Definition
Presence of glass
Term
Haplo
Definition
Minimum horizon development
Term
Flocculation
Definition
When clays are drawn together because of light charges & Forms "clumps" or flocs.
Term
Humic Acid:Where; What role does chelation play?
Definition
-Common in grassland soils(rich O horizon); contributes to high base satu.
-Liter w/ high C:N ratio & Ca/pH decomposes more slowly because of CHELATION!(Alfisols/Spodisols lack)
-Humic reactions leave ions to bind onto Ca or clay( increaes base saturation)
Term
In situ
Definition
Forming in place; decomposing roots; common in grasslands. No illuviation needed for organic matter to get in soil.
Term
"els"
Definition
Gellisol abvreviation- COLD
Term
How does clay accumulation occur?
Definition
-loss of energy, rain elluviates down, dries up, doesn't rain for awhile.
-Flocculation:
-Pores get too small to go any further.
-Very moist areas down not have clay horizons(Bt)
Term
"Ist"
Definition
Histosol
Term
ept
Definition
Inceptisol
Term
Od
Definition
Spodisol
Term
ar(not to be confused w/ arg)
Definition
Ploughed.
Term
rend
Definition
high in carbonates
Term
ud
Definition
Humid climate
Term
ust
Definition
dry climate
Term
What is THE basic building block?
Definition
silicate ions: SiO4(4-)
Term
Chain silicates: how many oxygens shared?
Definition
-2 or 3 oxygen shared
-ex. Pyroxene
Term
Double chain: what happens to the ferromagnesium from previous chains?
Definition
Fm/Si ratio=7:8 because less room for magnesium to wriggle in and bond w/ crystal.
-more complex/less reactant
Term
Sheet silicate:examples, what is it made of?(previous structures..)
Definition
-a bunch of connected chain silicates
-Examples:biotite/muscovite
Term
Framework silicates: O to Si sharing? examples? hot or col?
Definition
-In framework silicates, every O is shared w/ 2 Si tetrahedra?
-ex: quartz/feldspar
-LIKES IT COLD: most complex, so many loose bonds, easy to break in heat.
Term
What are 1:1 clays and what bonds them together? How is this different from 2:1 clays? What are some 2:1 clays?
Definition
1:1 clays= kaolinite, hydrogen bonds, made clean, low charge.
2:1 clays are bound by van der waals forces making them smectits(expanding clay); montmorillinite-mayo; illite-potassium;vermiculite-magnesium.
Term
Incongruent dissolution formula & what it provides
Definition
Potassium + acid + water = clay + silica + ions. Makes the montmorillinte.
Feldspar+proton+water=Montmorillinite + silica + potassium ions
Term
Importance of hydroysis
Definition
Water + Silicate(SiO2) YIELDS a silica tetrahedron w/ hydrogens attached. MAKES IT PLANT SOLUBLE.
Term
Dissolution reactions: How does pH affect?
Definition
idea is I take some rock(quartz), grind it up & put in a beaker and measure concentration of silica(in case of quartz) in water until it becomes constant(equilibrium concentration).
-***ph Determines solubility of a mineral in a dissolution reaction.
DUE TO CHATELIERS PRINCIPLE!
Term
Le chateliers principle, pH & dissolution?
Definition
A=B; Fundamental principle of equilibrium equations.
-In soils, reason why pH affects the dissolution of minerals solubility. A high pH means that one side of the reaction is out of equilibirum and it will dissolve a mineral to restore the equilibrium by driving equation in opposite direction.
Term
Low ph means what? What does it break down easily?
Definition
low pH= lots of acid(H+); breaks down calcium carbonate! When iron/aluminum are soluble this can be dangerous because it's toxic to plants.
Term
Carbonation
Definition
reaction of some rock with CO2 & water.
-Water & CO2 react to make carbonic acid.
-calcium gets kicked off so carbonate can get protons.
Term
Oxidation states; olivine example
Definition
-Iron/Manganese(common olivine reaction)
-As olivine weathers, iron comes out and is very unstable & reacts w/ oxygen to form hematite or other things.
Term
Ferric/Ferros iron: sex # example(2 or 3)
Definition
Ferros- two is us in sex
ferric- three of us is Icky.
Term
Why are organic acids important
Definition
-Weathering process.
-Acids = protons(H+) IT'S WHY ORGANIC MOLECULES HAVE HIGH CEC, Protons fall off.
-Chelation: CLAW, acid attaches all over a cation. Plants making an investiment, get rid of carbon to make carboxilic acids that cause calcium/iron/etc get into solution easier and move into roots.
-Dead organic matter releases carboxilic acid increasing CEC through chelation.
Term
Weathering of Feldspar to make clay
Definition
Orthoclase + acid + Water yields illite + silicates + protons.
-pH Dependent for reactions, La Chateliers principle required(need protons in soil to weather faster)
Eventually weathers down to make kaolinite.
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