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Modern Chemistry Chapter 15 Acids and Bases
Acids and Bases terms
75
Chemistry
11th Grade
05/13/2009

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Term
What contains acetic acid?
Definition
Vinegar
Term
What contains lactic acid?
Definition
sour milk
Term
What does phosphoric acid do to many carbonated beverages?
Definition
It gives a tart flavor
Term
What foods contain citric acid?
Definition
Lemons, oranges, grapefruits
Term
What contains malic acid?
Definition
Apples
Term
What contains tartaric acid?
Definition
Grapejuice
Term
What is the common name for Sodium Hydroxide NaOH?
Definition
lye
Term
Acids were first recognized as what?
Definition
a distinct class of compounds because of the common properties of their acqeous solutions.
Term
What are the properties of an acid?
Definition
1. Acqeous solutions of acids have a sour taste.
2. Acids change the color of acid-base indicators.
3. Some acids react w/active metals to release hydrogen gas, H2.
4. Acuds react with bases to produce salts and water. (salt- the reaction products are water and an ionic compound called a salt).
5. Some acids conduct electric current.
6. Contains H30
Term
What is a binary acid?
Definition
An acid that contains only two different elements: hydrogen and one of the more electronegative elements. ex: HF, HCl, HBr, and HI.
Term
How do you name binary acids?
Definition
by using the Binary Acid Nomenclature:
1. THe name of a binary acid begins with the prefix, hydro-.
2. The root of the name of the second element follows this prefix.
3. The name that ends with the suffix -ic.
Ex: HF- Hyrdrofluoric acid, HCl-hydrochloric acid, HI- Hydroiodic acid, H2S- Hydrosulfuric acid
Term
What is an oxyacid?
Definition
An acid that is a compound of hydrogen, oxygen, and a third element, usually a nonmetal. Ex: HNO3 (nitric acid)
Term
What kind of class does oxyacids belong to?
Definition
Ternary acids- which are acids that contain three different elements.
Term
What does an oxyacid's name depend on?
Definition
it is based on its anion
Term
What are the five common industrial acids?
Definition
sulfuric acid, nitric acid, phosporic acid, hydrochloric acid, and acetic acid
Term
What is the most commonly produced industrial chemical in the world? What are some uses of this acid? Why is this acid effective?
Definition
Sulfuric acid. It is used in large quantities in petroleum refining and metallurgy as well as in the manufacture of fertilizer. Production of metals, paper, paint, dyes. Because it attracts water, concentrated sulfuric acid is an effective dehydration (water removing) agent.
Term
What is Nitric Acid? What is its characteristics? what is it used for? what happens when it is left standing?
Definition
it is a volatile, unstable liquid that is rarely used in industry or laboratories. Dissolving the acid in water provides stabilitu. It also turns proteins yellow. Use to make explosives, rubber, platics, dyes, and pharmaceuticals. Usually the solutions are colorless, but left standing, they become yellow because of slight decompisition to brown nitrogen dioxide gas.
Term
Along w/nitrogen and potassium, Phosporus is what? What is phosphoric acid used for?
Definition
It is an essential element for plants and animals. Most of the phosporic acid produced each year is directly for manufacturing fertilizers and animal feed. Dilute p.acid has a pleasant but sour taste that is not toxic. It is used in flavoring agents in beverages. It is important in the manufacture of detergents and ceramics.
Term
What is hydrochloric acid used for? Industrially? and what about its dilute solution?
Definition
HCl is produced by the stomack to aid digestion. Industrially, it is used for "pickling" (immerison of metals in a. solutions to remove surface impurities) iron and steel. It is used as a cleaning agent, food processing, activation of oil wells, recover Mg from sea water. The dilute solution is referred to as muriatic acid (found in hardware stores. to maintain the correct acidity in swimming pools)
Term
What are some characteristics of acetic acid? What is its concetrated solution called? How does it get its name? How is it used?
Definition
Concentrated acetic acid is clear, colorless, pungent smelling liquid called glacial acetic acid. the name derives from the fact that pure acetic acid has freezing point of only 17C. IT can form crystals in a cold room. The fermentation of plants sometimes produce this acid. It is important industrially in synthesizing chemicals used in the manufacture of plastics. It is also used as a fungicide.
Term
How do bases differ from acids? What are its characteristics?
Definition
1. Aqueous solutions of bases taste bitter.
2. Bases change the color of acid-base indicators.
3. Dilute acqeous solutions feel slippery.
4. Bases react with acids to produce salts and water.
5. Bases conduct electric current.
6. It contains OH
Term
Who is Svante Arrhenius?
Definition
A Swedish chemist who lived from 1859-1927, understood that acqeous solutions of acids and bases conduct electric current. He came up w/the Arrhenius acids and bases.
Term
What is an Arrhenius acid?
Definition
A chemical compound that increases the concentration of hydrogen ions. H+, in acqeous solutions. An acid will ionize in solution, increasing the number of hydrogens present.
Term
What is an Arrhenius base?
Definition
a substance that increases the concentration of hydroxide ions OH-, in acqeous solutions. These bases dissociate in solution to release OH ions into the solutions.
Term
What are all pure acqeous acids?
Definition
electrolytes
Term
Why do acids form hydronium?
Definition
because acid molecules are polar, so that one or more hydrogen ions are attracted by ater molecules. Negatively charged anions are left behind.
Ex: HNO3 + H2O = H3O + NO3
Term
What is a strong acid?
Definition
One that ionizes completely in acqeous solutions.
Ex: HCl (hydrochloric acid), HClO4 (perchloric acid), HNO3 (nitric acid).

Ex: H2SO4 + H2O = H3O + HSO4
Term
What do strength of acids depend on?
Definition
the polarity of the bond between hydrogen and the element to which it is bonded and the ease with which that bond can be broken. Acid strength increases with increasing polarity and decreasing bond energy.
Term
What are weak acids?
Definition
Acids that are weak electrolytes. The aqeous solution of weak acid contains hydronium ions, anions, and dissolved acid molecules.
Ex: Hydrocyanic acid (HCN)
Ex: HSO4 + H2O = H3O + SO4
Term
What do organic acids contain?
Definition
the acidic carboxyl grou: COOH.
Term
How many hydrogen atoms does a molecule of acetic acid contain? What is its characteristics?
Definition
contains four. Only one of the hydrogen atoms is ionizable. The hydrogen atom in the carboxyl group in acetic acid is the one that is acidic and forms the hydronium ion.
Term
What are most bases?
Definition
They are ionic compounds containing metal cations and the OH anion. because these bases are ionic, they dissociate to some extent.
Term
When a base completely dissociates in water to yiel aqueous OH- ions, the solution is referred to as...?
Definition
Alkaline.
Ex: Sodium hydroxide (NaOH) is the common laboratory base.
NaOH - Na + OH
Term
What other hydroxides form alkaline solutions?
Definition
Li, Na, K, Rb, and Cs
Term
What is a base commonly used in household cleaners?
Definition
NH3. Ammonia is a base because it produces hydroxide ions when it reacts with water molecules.
Term
What do the strength of bases depend on?
Definition
the extent to which the base dissociates, or adds hydroxide ions to the solutions.
Ex of strong base: KOH.
- Strong bases are strong electrolytes.
Ex: Ca(OH)2 = Ca + 2OH
Weak base: NH3 + H2O = NH4 + OH
Term
What happens when a base is not very soluble?
Definition
They do not produce a large number of hydroxie ions when added to water. ex: Cu(OH)2.
Term
What do the alkalinity of aqueous solutions depend on?
Definition
The concentration of OH ions in solution.
Term
Who expanded the Arrhenius acid definition?
Definition
(1923) Danish chemist JN Bronsted and English chemist TM Lowry.
Term
What is a Bronsted-Lowry acid?
Definition
A molecule or ion that is a proton donor. Like hydrogen chloride and water.
Ex: HCl + NH3 = NH4 + Cl
Ex: H2O + NH3 = NH4 + OH
Term
What is a bronsted-lowry base?
Definition
a molecule or ion that is a proton acceptor. The arrhenius hydroxide base such as NaOH is not a bronsted-lowry base because its species cannot accept a proton.
Term
What happens in a Bronsted-Lowry acid-base reaction?
Definition
protons are transferred from one reactant (the acid) to another (the base).
Term
What is a monoprotic acid?
Definition
An acid that can donate only one proton (hydrogen ion) per molecule.
Ex: Perchloric acid (HClO4), hydrochloric acid (HCl), and nitric acid (HNO3).
Ex: HCl + H2O = H3O + Cl
Term
What is a polyprotic acid?
Definition
an acid that can donate more than one proton per molecule.
Ex: Sulfuric acid (H2SO4) and phosphoric acid (H3PO4).
Term
The ionization of polyprotic acid occur in what?
Definition
Stages
because an acid can only donate a hydrogen atom one at a time.
Term
What is a diprotic acid?
Definition
can donate two protons per molecule.
Ex of ionization:(sulfuric acid)
H2SO4 + H20 = H30 + HSO4-
HSO4 + H20 = H30 + SO4 2-
Term
What is a triprotic acid?
Definition
An acid able to donate three protons per molecule.
Ex: H3PO4 + H20 = H30 + H2PO4 -
H2PO4 + H20 = H30 + HPO4 2-
HPO4 + H20 = H30 + PO4 3-
Term
Which stage of ionization is greatest concentration of ions formed with most polyprotic acids
Definition
the first
Term
What is the third classifcation of acids and bases based on?
Definition
the bonding and structure. includes substances that do not contain hydrogen at all.
Term
Who was GN Lewis?
Definition
The American chemist whose name was give to electron dot structures and famous for third classification.
Term
What is a Lewis Acid?
Definition
An atom, ion, or molecule that accpets and electron pair to form a covalent bond.
Term
which of the three acid definitions is the broadest? Explain.
Definition
The Lewis definition is the broadest of the 3 acid definitions. It applies to any species that can accept an electron pair to form a covalent bond iwht another species.
Ex: H + NH3 = NH4
Ag + 2NH3 = Ag(NH3)2
Term
Any compound in which the central atom has 3 valence electrons and forms three covalent bonds can react as a ___? How does it do it?
Definition
Lewis acid. It odes so by accepting a pair of electrons to form a fourth covalent bond, completing an electron octet.
Term
What is a Lewis base?
Definition
An atom, ion, or molecule that donates an electron pair to form a covalent bond.
Ex: BF3 + F = BF4
Term
what is a Lewis acid-base reaction?
Definition
It is the formation of one or more covalent bonds between an electron pair donor and an electron pair acceptor.
Term
The Bronsted-Lowry definitions of acids and bases provide a bases for ___?
Definition
studying proton transfer reaction.
Term
What is the conjugate base?
Definition
the species that remains after a Bronsted-Lowry acid has given up a proton.
Ex: HF (acid) + H20 = F (conj b) + H30
Term
What is the conjugate acid?
Definition
The species that is formed when a Bronsted-Lowry base gains a proton.
Term
What is mean when it is siad that Bronsted-Lowry acid-base reaction are equilibrium system?
Definition
That both and forward reverse reactions occur. They involve two acid-base pairs, known as conjugate acid-base pairs.
HF (acid 1) + H20 (base 2) = F (base 1) + H30 (acid 2)
Term
In every conjugate acid-base pair, the acid has __ more proton than its conjugate base.
Definition
one
Term
The extent of the reaction between a bronsted-lowry acid and base depend on ___.
Definition
the relative strenghts of the acids and bases involved.
Term
What is the relationship between the strength of an acid and that of its conjugate base?
Definition
the stronger an acid is, the weaker its conjugate base.
Term
What is the relationship between the strength of a base and its conjugate acid?
Definition
the stronger a base is, the weaker its conjugate acid.
Term
Proton-transfer reactions favor the production of ____.
Definition
weaker acid and weaker base.
Term
A violent proton transfer reaction could result from ____.
Definition
bringing together a very strong acid and very strong base in certain proportions becaus the reaction has almost no tendency to go in the reverse direction.
Term
What is amphoteric?
Definition
Any species that can react as either an acid or a base is described.
Ex: H2S04 (acid) + H20 = H30 = HS04.
NH3 + H20 = NH4 + 0H
Term
Molecular compounds containing -OH groups can be ___ and ____.
Definition
Acidic or amphoteric
Term
What is a hydroxyle group?
Definition
it is the covalently bonded OH group in an acid.
Term
What needs to happen for the compound to be acidic?
Definition
a water molecule must be able to attract a hydrogen atom from a hydroxyl group.
Term
Where are the small, more electronegative atoms of nonmetals located?
Definition
at the upper right in the periodic table. form compounds with acidic hydroxyl group.
Term
The behavior of a compound is affected by the number of ___.
Definition
oxygen atoms bonded to the atom connected to the -OH group.
Term
The larger the number of such oxygen atoms is ___
Definition
the more acidic the compound is likely to be.
Term
An acid-base reaction occurs in aqueous solution between ____.
Definition
hydrochloric acid, a strong acid that completely dissociates to produce H30 and sodium hydroxide, a strong base that completely dissociates to produce OH.
Term
What is neutralization?
Definition
The reaction of hydronium ions and hydroxide ions to form water molecules.
Term
Water is not hte only product of a neutralization. A salt is also produced. What is a salt?
Definition
an ionic compound composed of a cation from a base and an anion from an acid.
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