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MCAT EK Chemistry Lecture 2
Flashcards for MCAT EK Chemistry Lecture 2
11
Chemistry
Not Applicable
12/02/2011

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Cards

Term
What is STP?
Definition
1 atm and 0 degrees Celsius
Term
Define 'mean free path'
Definition
The distance traveled by a gas molecule between collisions
Term
What are the four characteristics of an ideal gas?
Definition
1. Gas molecules have zero volume

2. Gas molecules exert no forces other than repulsive forces due to collisions

3. Gas molecules make completely elastic collisions

4. The average kinetic energy of gas molecules is directly proportional to the temperature of the gas
Term
What is the equation for the ideal gas law?
Definition
PV = nRT

R = 0.0821 (atm L)/(mol K)

OR

R = 8.314 J/(K mol)
Term
What is 'standard molar volume'?
Definition
One mole of gas at STP occupies 22.4 L
Term
What is Dalton's Law?
Definition
The total pressure exerted by a gaseous mixture is the sum of the partial pressures of each of its gases

Partial Pressure of One Gas = mole fraction of that gas X total pressure of the mixture
Term
What is the equation relating Kinetic Energy and the temperature of a gas?
Definition
KE = (3/2)RT
Term
What are the two equations associated with Graham's Law?
Definition

(v1/v2) = (√m2)/(√m1)

 

(Effusion Rate1/Effusion Rate2) = (√M2)/(√M1)

Term
Explain the difference between Effusion and Diffusion
Definition

Effusion is the spreading of a gas from high pressure to very low pressure through a pinhole (an opening smaller than the average distance between the gas molecules)

 

Diffusion is the spreading of one gas into another gas or into empty space

Term
What two conditions cause gases to deviate from ideal gas behavior?
Definition
High pressure (above 10 atm) or low temperature (near the gas' boiling point)
Term
What two characteristics of gases are affected when they deviate from ideal gas behavior and how?
Definition

Vreal > Videal

 

Preal < Pideal

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