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Materials Final Marg
Vocab for Materials finals
179
Engineering
Undergraduate 3
12/09/2017

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Term
Activation energy
Definition
The energy required to cause a particular reaction to occur
Term
Age hardening
Definition
three step heat treatment used primarily for non ferrous alloys and stainless steels where the material is heated to a single phase region, quenched to form a supersaturated solid solution and then alloyed to age either naturally at room temperature or artificially at an elevated temp , a type of dispersion strengthening that forms a coherent precipitate
Term
allotropy
Definition
the characteristic of a material being able to exist in more than one crystal structure
Term
Alloy
Definition
a metallic material that is obtained by chemical combinations of different elements, typically have better properties than pure metals
Term
amorphous material
Definition
materials that have no long range order only short range order
Term
anion
Definition
a negatively charged ion produced when an atom usually of a non metal accepts one or more electrons
Term
anisotropic
Definition
having different properties in different directions
Term
annealing
Definition
a heat treatment that typically involves heating a metallic material to a high temperature for an extended period of time in order to lower the dislocation density and impart ductility
Term
artificial aging
Definition
aging at temps greater than room temp but lower than the solvus temp
Term
austenitite
Definition
name for fcc iron,
Term
austenitizing
Definition
heating a steel or cast iron to a temperature where homogeneous austenite can form, first step of most heat treatments for steel and cast iron
Term
bainite
Definition
two phase microconstituent containing ferrite and cementite
Term
binary phase diagram
Definition
a phase diagram that has two components
Term
binding energy
Definition
the energy required to separate two atoms an infinite distance apart, measure of the bond strength
Term
Bioactive
Definition
The ability of a material to bond directly with living tissues when implanted
Term
Biocompatibility
Definition
The condition of being compatible with living tissue or a living system by not being toxic or injurious and not causing immunological rejection
Term
Bravais lattice
Definition
the fourteen possible lattices that can be created using lattice points, examples of some of these include HCP, FCC and BCC
Term
Burgers vector
Definition
the direction and distance a dislocation moves in each step
Term
cast alloys
Definition
alloys that are poured from the molten state into a mold and then allowed to solidify to produce a desired shape
Term
cast iron
Definition
ferrous alloys containing sufficient carbon so that the eutectic reaction occurs during solidification
Term
Cation
Definition
a positively charged ion produced when an atom, usually of a metal, gives up its valence electrons
Term
cementite
Definition
hard, brittle, intermetallic compound Fe3C
Term
ceramic
Definition
an inorganic material with high melting temp and usually hard and brittle
Term
chill zone
Definition
a region of small randomly oriented grains that forms at the surface of a casting as a result of heterogeneous nucleation
Term
close packed directions
Definition
directions in a crystal along which atoms are in contact
Term
coefficient of thermal expansion
Definition
the amount by which a material changes its dimensions when the temperature changes
Term
coherent precipitate
Definition
a crystalline precipitate that forms from solid solution with the orientation that maintains continuity between the crystal lattice of the precipitate and the lattice of the matrix, usually accompanied by some strain in both lattices.
Term
cold working
Definition
deformation of a material below its recrystallization temperature
Term
columnar zone
Definition
a region of elongated grains having a preferred orientation that forms as a result of competitive growth during the solidification of a casting
Term
constituents
Definition
the basic materials that make up a composite material and include matrix, reinforcement and the interface
Term
coordination number
Definition
the number of nearest neighbors to an atom in its atomic arrangement
Term
copolymer
Definition
an addition polymer produced by joining more than one type of monomer
Term
covalent bond
Definition
a very strong type of primary bond formed between two atoms when the atoms share their valence electrons
Term
creep
Definition
time dependent permanent deformation at high temperatures occurring at constant load or constant stress
Term
Crevice Corrosion
Definition
the attack of metal surfaces by a stagnant solution in crevices, for example in nuts and rivet heads. When dust, sand and other corrosive substances are deposited on surfaces, they create an environment where water will accumulate and corrode the part. It can happen between two metals or between a metal and a nonmetal. This causes damage to the metallic part, which is initiated by the concentration gradient in chemicals. Oxygen causes an electrochemical concentration cell outside the crevice. This is a differential aeration cell where the air present is oxygen. In the crevice (the cathode), the pH and the oxygen content increases. However, this is the opposite for the chlorides; they are lower.
Term
critical radius
Definition
the minimum size that must be formed by atoms clustering together in a liquid before a solid particle is stable enough and can grow, less than the critical radius the particle is an embryo, greater than the critical radius the particle is a nucleus
Term
cross-linking
Definition
attaching chains of polymers together to produce a three-dimensional network polymer
Term
cross-slip
Definition
the change in the slip system of a dislocation, ability of Goldie to find a new path
Term
crystal structure
Definition
the arrangement of atoms in a material into a regular repeatable lattice,
Term
crystalline materials
Definition
materials that have long range arrangement of their atoms in a regular and repeatable manner, comprised of many small crystals or grains
Term
degradation temperature
Definition
temperature at which a polymer burns, chars or decomposes
Term
degree of polymerization
Definition
the number of monomers in a polymer; the length of the molecular chain
Term
delamination
Definition
separation of individual plies of a fiber-reinforced composite
Term
dendrite
Definition
the tree like structure of a solid that grows when an undercooled liquid nucleates
Term
devitrification
Definition
crystallization of glass to form glass ceramic
Term
directions of form
Definition
crystallographic directions that all have the same characteristics denoted by <>
Term
dislocation
Definition
a line imperfection in a crystalline material; movement of these helps explain how a metallic material plastically deforms, interference with the movement of these helps explain how metallic materials are strengthened
Term
dispersion strengthening
Definition
increasing the strength of a material by mixing more than one phase
Term
ductility
Definition
the ability of a material to be permanently deformed without breaking
Term
edge dislocation
Definition
a dislocation introduced to the lattice by adding an extra half plane of atoms, the burgers vector for an edge dislocation is perpendicular to the dislocation line
Term
elastic deformation
Definition
deformation that is recovered when the load is removed (not permanent)
Term
elastomers
Definition
polymers possessing exceptional elastic deformation due to the fact that the molecular chains that comprise these materials are highly coiled
Term
electronegativity
Definition
the relative tendency of an atom to accept an electron and become an anion, strongly electronegative atoms readily accept electrons
Term
embryo
Definition
a tiny particle of solid that forms from the liquid as the atoms cluster together but is not stable enough to grow, smaller than the critical radius
Term
engineering strain
Definition
the amount that a material deforms per unit length when pulled or pushed
Term
engineering stress
Definition
the applied load divided by the original cross-sectional area
Term
equiaxed zone
Definition
a region of randomly oriented grains in the center of a casting produced as a result of widespread nucleation
Term
eutectic
Definition
three phase reaction where the liquid phase changes to two solid phases upon cooling
Term
eutectoid
Definition
three phase reaction where a solid phase transforms into two solid phases upon cooling
Term
ferrite
Definition
a solid solution of one or more elements in BCC iron, the BCC phase on the iron carbide phase diagram
Term
filament winding
Definition
process for producing fiber reinforced composites in which continuous fibers are wrapped around a form or mandrel the fibers may be prepregged or the filament wound structure may be impregnated to complete the production of the composite
Term
Frank Read Source
Definition
The microstructural mechanism responsible for dislocation multiplication during strain hardening, a pinned dislocation under applied stress produces additional dislocations
Term
Fretting Corrosion
Definition
gradual wear by means of rubbing or gnawing action between two surfaces. Fretting corrosion is a combined action of fretting as well as corrosion, which involves corrosion at points where two metal surfaces make contact by means of a rubbing action.
Term
glass
Definition
amorphous material derived by cooling a melt
Term
Glass ceramics
Definition
ceramics formed in the glassy state and allowed to partially crystalize during heat treatment, an example of glass ceramic is corning were
Term
glass temperature (Tg)
Definition
the temperature range below which the amorphous polymer assumes a rigid glassy structure also known as glass transition temperature
Term
grain
Definition
a portion of solid material within which the lattice is identical and is oriented in only one direction
Term
Grain boundary diffusion
Definition
diffusion of atoms along a grain boundary
Term
grain refinement
Definition
the addition of heterogeneous nuclei in a controlled manner to increase the number of grains in a casting
Term
growth
Definition
the physical process by which a new phases increases in size
Term
Guinier Preston (GP) zones
Definition
Tiny clusters of atoms that form early on in the age hardening process
Term
hardenability
Definition
A measure of the depth to which a specific ferrous alloy may be hardened by the formation of martensite upon quenching from a temperature above the upper critical temperature, the Jominy Bar test is used to provide a measure of hardenability
Term
hardness test
Definition
a quick easy and cheap test that measures the resistance of a material to penetration by a sharp object, some examples include the Brinell and Rockwell tests
Term
heterogeneous nucleation
Definition
formation of a critically sized solid from the liquid on an impurity surface of the surface of the mold wall
Term
homogeneous nucleation
Definition
formation of a critically sized solid from the spontaneous cluster of atoms due to severe undercooling
Term
honeycomb
Definition
a lightweight but stiff assembly of aluminum strip joined and expanded to form the core of sandwich structure
Term
hot working
Definition
deformation of a material above the recrystallization temperature
Term
Hume-Rothery rules
Definition
necessary but not sufficient conditions that an alloy system must meet in order to display unlimited solubility - includes same crystal structure, similar atomic size, same valence and similar electronegativity
Term
hypereutectic alloy
Definition
for an alloy system displaying a eutectic, an alloy for which the concentration of the solute is greater than the eutectic composition
Term
hypoeutectic alloy
Definition
for an alloy system displaying a eutectic an alloy for which the concentration of the solute is less than the eutectic composition
Term
impact energy
Definition
a measure of the energy absorbed during the fracture of a specimen of standard dimensions and geometry when subjected to very rapid loading, Charpy and Iron tests re used to measure this parameter which is important in assessing the ductile to brittle transition behavior of a material.
Term
inoculation
Definition
the addition of an agent to molten cast iron that provides nucleation sites at which graphite precipitated during solidification
Term
Intergranular corrosion
Definition
This is a corrosion type that attacks the boundaries of the metal crystallites, as opposed to attacking the surface of the metal. Intergranular corrosion can also be referred to as intergranular attack under a condition known as grain boundary depletion
Term
intermetallic compound
Definition
a compound of two or more metals that has unique composition and structure, most intermetallics are hard and brittle
Term
Interstitial defect
Definition
a point defect produced when an atom is placed into the lattice at a site that is normally not a lattice point (in between space)
Term
Interstitial diffusion
Definition
diffusion of different atoms from one interstitial position to another
Term
Interstitial site
Definition
a location between the normal atom or ions in a crystal into which another atom can be placed (in-between spots)
Term
Ionic bond
Definition
The bond formed between two different atoms when on atom donates its valence electrons to the second atom and the two ions are held together by columbic (strong electrostatic attraction) forces.
Term
Isomorphous phase diagram
Definition
a phase diagram that displays unlimited solid solubility (single solid phase)
Term
Isotropy
Definition
Having the same properties in all directions
Term
jominy test
Definition
test used to evaluate hardenability, an austenitized steel bar is quenched atone end only thus producing a range of cooling rates
Term
lattice
Definition
a collection of points that divide space into smaller equally spaced segments, the regular geometrical arrangements of points in crystal space
Term
lattice parameters
Definition
the lengths and sides of the unit cell and the angles between those sides
Term
lever law
Definition
a technique used to determine the amount of each phase in a two phase system
Term
liquidus
Definition
the temperature on a phase diagram at which the first solid begins to form
Term
local solidification time
Definition
The time required for a particular location in a casting to solidify once nucleation has begun
Term
malleable cast iron
Definition
cast iron obtained by a lengthy heat treatment during which cementite decomposes to produce rounded clumps of graphite, good strength, ductility and toughness are obtained
Term
martensite
Definition
a metastable phase formed in steel by diffusionless athermal transformation, this phase is very strong but very brittle
Term
matrix
Definition
the continuous phase in a two phase material or for a composite, the continuous material that holds the reinforcement together and helps to transfer stresses
Term
matrix phase
Definition
the continuous phase in a composite, the composites are named after the continuous phase, holds reinforcement together and helps transfer load
Term
mechanical properties
Definition
properties of a material such as strength that describes a materials response to an applied force, these properties are sensitive to the microstructure of a material
Term
metallic bond
Definition
a type of primary bond where positively charged atom cores are held together by the mutually electrostatic attraction to the negatively charged electron cloud or sea of electrons
Term
miscibility gap
Definition
a region where two liquid phases do not mix or are not soluble in one another
Term
modulus of elasticity
Definition
the slope of the stress strain curve in the elastic region, E
Term
monomer
Definition
the molecule from which a polymer is produced
Term
monotectic
Definition
a three phase reaction in which one liquid transforms to a solid and second liquid on cooling
Term
natural aging
Definition
spontaneous aging of a supersaturated solid solution at room temperature
Term
nitriding
Definition
hardening the surface of steel with nitrogen obtained from a special gas atmosphere
Term
nonferrous alloys
Definition
an alloy based on a metal other than iron
Term
nonstochiometric intermetallic
Definition
an intermetallic that exists at a range of compositions
Term
normalizing
Definition
The steel is then air-cooled, which is a cooling rate of approximately 38 °C (100 °F) per minute. This results in a fine pearlitic structure, and a more-uniform structure. Normalized steel has a higher strength than annealed steel; it has a relatively high strength and ductility
Term
nucleation
Definition
the initial stages in a phase transformation, it is evidenced by the formation of small stable particles of the new phase which are capable of growing
Term
nucleus
Definition
a tiny stable particle of solid that forms from the liquid as atoms cluster together, the radius of the nucleus is greater than some critical radius
Term
offset yield strength
Definition
a yield strength obtained graphically that describes the stress that gives no more than a specified amount of plastic deformation
Term
packing factor
Definition
the fraction of space occupied by atoms
Term
pearlite
Definition
a two phase lamellar microconstituent in steel made up of ferrite and cementite, this microstructure is relatively soft and ductile, formed from slow, near equilibrium cooling rates.
Term
percent elongation
Definition
the total percent increase in length of a specimen during the tensile test
Term
peritectic
Definition
a three phase reaction where a liquid and a solid phases transform to a single solid phase upon cooling
Term
peritectoid
Definition
a three phase reaction where two solid phases transform to a single solid phase upon cooling
Term
phase
Definition
a material having the same composition structure and properties under equilibrium conditions
Term
physical properties
Definition
describe a materials response to an applied field
Term
Pitting Corrosion
Definition
This is a corrosion that occurs in materials that have protective films. It is an attack with localized holes on the metal's surface. The attack can penetrate the metal very rapidly, while some parts of the metal surface remain free from corrosion. Pitting is vigorous when the solution on the metal surface contains chloride, hypochlorite or bromide ions. Other harmful solutions are those that contain fluorides and iodides, while sulfides and water are known to enhance the pitting process
Term
planar growth
Definition
the growth of a smooth solid liquid interface where no undercooling is present
Term
planes of form
Definition
crystallographic planes that have the same characteristics although their orientation is different, denoted by {} generic planes
Term
plastic deformation
Definition
permanent deformation in a material, for metals, plastic deformation occurs by the movement of dislocations through the material (SLIP)
Term
point defects
Definition
zero dimensional imperfections that are located at a single point, examples include vacancies, substitutional and interstitial
Term
polygonized substructure
Definition
a subgrain structure produced during the recovery stages of annealing where the dislocations do not decrease in number but they rearrange themselves into this polygonized substructure
Term
polymer
Definition
polymers are materials made from giant chain like molecules having average molecular weights from 10K to 1 M g/mol built by the joining of many mers or units by chemical bonds...typically carbon based
Term
polymorphism
Definition
allotropy or being able to exist in more than one crystal structure
Term
pouring temperature
Definition
the temperature of a metal when it is poured into a mold
Term
precipitate
Definition
a solid phase that forms during age hardening from the original matrix then the solubility limit is exceeded
Term
prepregs
Definition
layers of fibers in unpolymerized resins, after the prepregs are stacked to form a desired structure, polymerization joins the layers together
Term
process anneal
Definition
a low temp heat treatment used to eliminate all or part of the effects of cold working in steels
Term
recovery
Definition
a stage in the annealing process where the material is subjected to a low temperature heat treatment (below Trc) causing the dislocations to rearrange themselves into that polygonized substructure this stage of annealing eliminates residual stresses, restores electrical conductivity but does not change the strength of the material
Term
recrystallization
Definition
a stage in the annealing process where the material is subjected to a medium temperature heat treatment where the dislocations are removed from the material and new grains nucleate and grow, eliminates all of the effects of strain hardening except the dimensional changes
Term
repeat distance
Definition
the distance from one lattice point to an adjacent lattice point along a specific direction
Term
residual stresses
Definition
tresses that remain in a solid material after the original cause of the stresses has been removed. Residual stress may be desirable or undesirable. For example, laser peening imparts deep beneficial compressive residual stresses into metal components such as turbine engine fan blades
Term
rule of mixtures
Definition
statement that the properties of a composite material are a function of the volume fraction of each material in the composite
Term
sandwich
Definition
a composite material constructed of a lightweight low density material surrounded by dense solid layers, the sandwich combines overall light weight with excellent stiffness
Term
screw dislocation
Definition
a dislocation produced by skewing or shearing the crystal one atomic plane, Burgers vector is parallel to dislocation line
Term
Secondary bond
Definition
Relatively weak bond such as van der waals and hydrogen bonds that typical join molecules to one another
Term
self diffusion
Definition
the random movement of atoms within a pure metal
Term
Shape Memory Alloy
Definition
an alloy, such as Nitinol, that "remembers" its original shape and that when deformed returns to its pre-deformed shape when heated.
Term
slip
Definition
the movement of dislocations in a metal which leads to permanent deformation
Term
solid solution
Definition
a homogeneous crystalline phase that contains two or more chemical species, both substitutional and interstitial solid solutions are possible
Term
solidus
Definition
the temperature on a phase diagram below which all the liquid has completely solidified
Term
solution treatment
Definition
the first step in age hardening where the material is heated above its solvus temperature to form a single phase solid solution by dissolving the precipitate particles
Term
solvus
Definition
a solubility line on a phase diagram that separates a single solid phase region from multiple phase region, indicates the solubility limit of a material
Term
stainless steels
Definition
steels having more than 11% cr, providing excellent corrosion resistance
Term
stoichiometric intermetallic
Definition
an intermetallic compound that exists at a single composition, seen on the phase diagram as a vertical line
Term
Strain hardening
Definition
a method of strengthening a metal by increasing the number of dislocations by plastically deforming the metal
Term
Stress Corrosion Cracking
Definition
progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Structural failure due to SCC can be very unpredictable — failure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for months or even years. Metal components frequently experience SCC, and virtually all alloy systems are susceptible to SCC by specific corrodents under specific conditions
Term
stress relaxation
Definition
a reduction of the stress acting on a material over a period of time at a constant strain due to viscoelastic deformation
Term
substitutional defect
Definition
a point defect in a crystalline material produced an atom is removed from a regular lattice positon and replaced with another type of atom
Term
superheat
Definition
the pouring temperature minus the equilibrium freezing temp
Term
supersaturated solid solution
Definition
solution that contains more of the dissolved material than could be dissolved by the solvent under normal circumstances, forms after a material has been solution treated than quenched in the process of aging
Term
surface defects
Definition
imperfections such as grain boundaries that form a two dimensional plane within the crystal
Term
surface diffusion
Definition
diffusion along the surface of a material, fastest
Term
tacticity
Definition
describes the location in the polymer chain of atoms or atom groups is nonsymmetrical monomers
Term
temper designation
Definition
a shorthand notation used for aluminum and other alloys that explains the heat treatment employed on that material (includes letters O, H,T, F, W)
Term
tempered martenisite
Definition
the microconstituent of ferrite and cementite formed when martensite is tempered.
Term
tempering
Definition
process where a hardened steel or cast iron is reheated to some temperature below the eutectoid temperature for the purpose of decreasing the hardness and increasing the toughness by restoring some of the ductility, in steels tempering is generally done by heating the material to the appropriate temperature and then allowing the material to cool slowly in air
Term
tensile strength
Definition
the stress that corresponds to the maximum load in a tensile test
Term
thermal arrest
Definition
a plateau on the cooling curve during solidification caused by the latent heat of fusion that is emitted during solidification which effectively heats the cooling liquid
Term
thermoplastics
Definition
linear or branched polymers in which chains of molecules are not interconnected to one another, easily processed
Term
thermosets
Definition
polymers that are heavily cross-linked to produce a strong three dimensional network structure
Term
tie line
Definition
a horizontal line drawn in a two phase region of a phase diagram that helps to determine the composition of each phase
Term
total solidification time
Definition
the time required for a casting to solidify after the casting has been poured into the mold
Term
toughness
Definition
a qualitative measure of the impact resistance of a material, a function of the strength and ductility of a material, can be determined from the area under the true stress-strain curve
Term
transition temperature
Definition
the temperature below which a material behaves in a brittle manner in an impact test
Term
undercooling
Definition
the temperature to which a liquid metal must be cooled below the equilibrium freezing temperature before nucleation occurs
Term
unit cell
Definition
a subdivision of the lattice that still retains the overall characteristics of the entire lattice; the basic building block of a crystalline material
Term
vacancy
Definition
a point defect where an atom is missing from a regular lattice site
Term
vacancy diffusion
Definition
mechanism of diffusion where a diffusing atom leaves a regular lattice position to fill a vacancy site
Term
valence
Definition
the number of electrons in an atom that takes place in bonding or chemical reactions
Term
viscoelasticity
Definition
the deformation of a polymer by viscous flow of the chains or segments of the chain where the stress is applied
Term
volume diffusion
Definition
the slowest type of diffusion where the diffusing species moves through the interior of the volume of the grains where the atoms are most efficiently packed
Term
vulcanization
Definition
cross linking elastomer chains of introducing sulfur or other chemicals
Term
Wrought alloys
Definition
alloys that are shaped by a deformation process
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