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LUDI Chemistry of Enamel Caries
n/a
29
Dentistry
Undergraduate 2
04/24/2014

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Cards

Term
What happens to enamel when it is sectioned?
Definition
Prisms break
Term
Calcium Hydroxyapatite chemical formula
Definition
Ca10(PO4)6(OH)2
Term
Why does fluoride subsitution increase the stability of enamel?
Definition
1. Fluoride fits better into the structure
2. Increases electronegativity which pulls Ca2+ and PO3- ions in closer
3. More compact therefore more stable structure
Term
At what angle to hydroxyapatite molecules alternate along a column?
Definition
60 degrees
Term
Better hardness: Enamel or Dentine
Definition
Enamel
Term
Better stifness: Enamel or Dentine
Definition
Enamel
Term
Better compressive strength: Enamel or Dentine
Definition
Dentine
Term
Better tensile strength: Enamel or Dentine
Definition
Enamel
Term
Mohs hardness for Enamel and Dentine
Definition
Enamel: 5
Dentine 4
Term
Where in the tooth is the enamel densest?
Definition
Surface
Term
Where in the tooth is there the highest concentration of magnesium in enamel?
Definition
Amelodentinal junction
Term
Describe the relationship between magnesium and hydroxyapatite density in enamel
Definition
Reverse correlation
Term
Describe fluoride distribution in enamel
Definition
On surface of enamel where toothpaste most easily reaches
Term
Describe the relationship between fluoride distribution and magnesium/carbonate distribution
Definition
Inversely proportionate
Term
Apatite crystals in dentine
Definition
are smaller! but with similar chemistry
Term
Magnesium/Carbonate content of dentine compared to enamel?
Definition
Greater
Term
What are the hydroxyapatite crystals in dentine embedded in?
Definition
Type 1 collagen matrix
Term
Dentine collagen features
Definition
Highly cross-linked and very stable
Term
What is the advantage of dentine being cellular (as compared to enamel)
Definition
It can repair
Term
Protein distribution in enamel
Definition
Most near amelodentinal junction and reside between the prisms
Term
What can proteins in enamel protect against?
Definition
The dissolution of enamel
Term
Concept of supersaturation: ________ materials will only dissolve is surrounding solution is below ___________
Definition
Ionic
saturation
Term
Ionic materials will only __________ if surrounding solution is __________ above
Definition
Precipitate
above
Term
Saturation is achieved when solubility _________ reaches a certain value
Definition
Product
Term
Solubility product equation for binary salt XY
Definition
KSP=[X]x[Y]
Term
Solubility product for Ca10(PO4)6(OH)2
Definition
Ksp=[Ca]^10 x [PO4]^6 x [OH]^2
Term
For a given salt ksp must be __________ for precipitation to occur
Definition
Term
What effect to carbonate/magnesium have on the solubility product?
Definition
Increase
Term
What effect does fluoride have on the solubility product?
Definition
Decrease
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