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Lignocellulose
Structural composition of lignocellulose
24
Biology
Undergraduate 4
11/24/2011

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Cards

Term
What is the most abundant linear polysaccharide?
Definition
Cellulose
Term
The free C4 end of cellulose is what?
Definition
The non reducing end
Term
The free C1 end of cellulose is what?
Definition
The reducing end
Term
What is the structural rational behind the naming of the reducing end?
Definition
A reducing end is any sugar that has an aldehyde group or is capable of forming one through isomerisation.
Term
Which hemicelluloses are the two most common in softwoods?
Definition
Xylan and mannan
Term
Name the three precursors for lignin
Definition

Coumaryl

Guaiacyl

Syringyl

 

Term
What is the structural difference of between the lignin precursors?
Definition

The number of methoxyl groups (-OCH3) at the meta positions.

Coumaryl=zero, Guaiacyl=2, Syringyl= 3

Term
Which lignin procursor is present in hardwoods but NOT in softwoods?
Definition
Syringyl
Term
What is tha name of the only C6 hemicellulose?
Definition
Mannan
Term
Which two hemicelluloses are most abindant in hardwood and grasses?
Definition
Xylan and arabinan
Term
What are the names of the four most abundant carbohydrate monomers in lignocellulose?
Definition

Glucose

Mannose

Xylose

Arabinose

Term
Which year did Denmark win the European Football Championship?
Definition
1992!
Term
Which two carbohydrate polymers are the most abundant in seeds? 
Definition
Amylose and amylopectin
Term
What are the three main constituents of lignocellulose?
Definition

Cellulose

Hemicellulose

Lignin

Term
Which are the amporphous constitutents of lignocelulose?
Definition
Lignin and hemicellulose
Term
Which sugars in lignocellulose can be fermented by Saccharomyces cerivisiae?
Definition
Glucose and mannose
Term
What is the most common chemical bond between two glucose units?
Definition
the β(1→4) glycosidic bond connecting the C1 and C4 carbons by an oxygen atom. 
Term
 What are the two native polymorphs of cellulose?
Definition

 1α and 1β

 

1α dominates in bacteria and 1β dominates in plants

Term
 What is the repeating unit of cellulose?
Definition
  Cellobiose -consisting of two glucose units
Term
How many reducing and non-reducing ends does a linear polysaccharide have?
Definition
One reducing and one non-reducing end
Term
How many reducing and non-reducing ends do branched polysaccharides have?
Definition
1 reducing end and a variable amount of non-reducing ends
Term
What is the chemical mechanism by which the β 1-4 bonds are cleaved?
Definition
Hydrolysis
Term
How is lignin degraded in vivo
Definition
By oxidation
Term
If you suspend lignocellulose in demineralised water, what will be the pH range?
Definition

pH 4-5

 

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