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LEADERS Physics Chapter 4.1
Chapter 4.1 Nautral Gas General Overview
56
Physics
Graduate
06/26/2010

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Term
Natural gas was first used significantly in London the beginning of the 19th century. What was that use limited to?
Definition
Industrial applications
Term
When was the first US gas franchise granted??
Definition
1816 in Baltimore
Term
What caused an increase in the deman for manufactured gas?
Definition
The inability to transport natural gas
Term
From 1901 to 1925 how much did natural gas sales increase?
Definition
4x
Term
When did manufactured gas use peak?
Definition
mid 1940s
Term
Since WWII, how has natural gas use grown compared to other primary fuels?
Definition
natural gas use has grown faster than any other types of primary fuel
Term
What was the percent increase of natural gas from 1950 to 1970?
Definition
6.6%
Term
What were the rates of increase of consumption from 1950 for natural gas, petroleum, and coal?
Definition
natural gas 6.6%
petroleum 3.9%
coal .3%
Term
How much of the energy used in the US comes from the combustion of natural gas?
Definition
1/3
Term
Natural gas occurs in reservoirs under which geological conditions?
Definition
1. Adequate reservoir rock of appropriate porosity and permeability
2. a relatively impervious cap rock
3. a structural trap to confine the natural gas
(Structural traps are the same as that for petroleum)
Term
Why are natural gas and petroleum often (though not always) found together in the same reservoir?
Definition
because of similarities in reservoir conditions
Term
What is associated natural gas?
Definition
When oil and gas are found together
Term
What is nonassociated natural gas?
Definition
when oil and gas are found alone
Term
What is nonassociated natural gas?
Definition
when oil and gas are found alone
Term
What are 3 types of structural traps for natural gas?
Definition
1. Anticline (hill)
2. Fault (like a crack inside earth)
3. Stratigraphic trap
Term
Describe the density layers of water, oil and natural gas?
Definition
1. water at bottom
2. oil in middle
3. natural gas at the top
Term
What are oil and natural gas?
Definition
hydrocarbons
Term
When he talk about natural gas what are we talking about?
Definition
Methane
Term
How much of commerical natural gas is methane CH4?
Definition
80% to 95% of the natural gas consumption
Term
What are some things present in methane?
Definition
1. other saturated hydrocarbons (propane, butanes, pentanes, etc. some ethane c2h6 is almost always present)
2. Non hydrocarbon gases such as nitrogen and carbon dioxide are also common compoents
3. usually certain undersirable impurities are present
4. and in addition some haeavy, condensable hydrocarbons
Term
What is wet natural gas?
Definition
contains significant amounts of condensable hydrocarbons
Term
What is dry natural gas?
Definition
Contains amounts of condensable hydrocarbons that are too samll for economical recovery
Term
What happens with wet gas?
Definition
Wet gas is converted to dry gas by processing which removes the condensable hydrocarbons
Term
What are recoverable condensable hydrocarbons called?
Definition
NGL Natural gas liquids
Term
What is LPG liquefied petroleum gas?
Definition
the propane and butanes obtained from these liquids
Term
How do you classify crude natural gas?
Definition
1. Wet natural gas
2. Dry natural gas
3. Sour natural gas
4. Sweet natural gas
Term
What is sour natural gas?
Definition
contains sufficient amounts of sulfur compounds and or carbon dioxide to be corrosive or offensive smelling
Term
What is sweet natural gas?
Definition
can be obtained from sour gas by processes which remove the offending components
Term
List the natural gases in order of composition (volume percent) from biggest to smallest
Definition
1. Methane CH4
2. Ethane C2H4
4. Propane C3H6
4. Butane C4H8
5. Pentane C5H10
Term
About how much heating value is in the natural gases?
Definition
About 1050 Btu/cubic foot
Term
What are some undesirable impurities found in crude natural gas?
Definition
1. Carbon dioxide
2. Nitrogen
3. Water vapor
4. Hydrogen sulfides
5. thiols or other organic sulfur compounds
Term
What is required of carbon dioxide and nitrogen in natural gas in some markets?
Definition
In some cases the gas cannot be marketed until the CO2 and N are removed as they usually reduce the heating value of gas
Term
What can reduce the heating value of gas?
Definition
CO2 and N
Term
What can sometimes happen with CO2 if there is enough?
Definition
can be converted to dry ice
Term
About what percent is N usually in natural gas?
Definition
About 1-2%
Term
About what percent in CO2 usually in gas?
Definition
About .4-1%
Term
How are heavy hydrocarbons removed from wet natural gas?
Definition
By scrubbing the gas with a heavy hydrocarbon
Term
What doe the equipment that performs the oil-absorption process consist of?
Definition
1. A tower for absorbing the propanes, butanes, and other heavier hydrocarbons
2. A stripping tower for removing these hydrocarbons from the scrubbing oil
3. A purification system for separting the recovered hydrocarbons which are then converted into marketable materials
Term
How is water removed from natural gas?
Definition
1. Adsorption onto the surface of activated solid drying agents
2. Absorption into hygroscopic liquids
Term
What is adsorption?
Definition
the accumulation of molecules of a gas to form a thin film on the surface of a solid
Term
What 2 liquids possess dehydrtaing properties and are used extensively in the natural gas industry?
Definition
1. diethylene glycol
2. triethylene gycol
Term
What does a glycol dehydration unit consist primarily of?
Definition
1. An absorption tower
2. A generator
3. A solvent reclaimer
Term
What does an absorption tower do?
Definition
Here the glycol stream flows countercurrent to the gas stream
Term
What does a regenerator do?
Definition
The absorbed water is distilled from the glycol
Term
What does a solvent reclaimer do?
Definition
Prevent the buildup of undesirablle impurities in the glycol
Term
What is the method used to remove Carbon dioxide and hydrogenin the US?
Definition
The Girbotol process
Term
What is sometimes used in the Girbotol process?
Definition
an aqueous solution of monoethanolamine (sometimes diethanolamine) are used
Term
What are two dehydrating agents?
Definition
diethylene glycol
triethylene glycol
Term
What are 2 CO2 and H2S removal agents?
Definition
monoethanolamine and diethanolamine
Term
What are two odorizing agents?
Definition
ethanethiol
abutanethiol
Term
What is a thiol?
Definition
Sulfur hydrogen bond (SH)
Term
How do monoethanolamine and diethanolamine differ?
Definition
in their selectivity for H2S and CO2
Term
What is the glycol-amine process?
Definition
a combination of the glycol process and ethanolamine process
Term
Is there an economical process to remove nitrogen from most natural gases?
Definition
No
Term
Processed natural gas is not toxic to plant or animal life without a few exceptions
Definition
eg: Animals kept in an atmosphere containin 25% natural gas for 30 days remained normal in every aspect; plants and tree roots in most cases that were exposed to natural gas were not injured
Term
What is added to natural gas in small amounts to alloiw gas leaks to be detected by smell?
Definition
certain odorizing compounds such as the thiols of ethane, butane, and pentane or other organic sulfides or disulfieds (add SH)
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