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LEADERS Physics - Chapter 2.2
Chapter 2.2 Coal Chemistry
22
Physics
Graduate
06/19/2010

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Term
What is coal's chemical composition affected by?
Definition
1. the differences in the incorporated plant materials
2. the degree of carbonization that has occurred
3. the impurities absorbed from the surroundings during the formation process
Term
In coal, what are two major changes that occur as carbonization goes on?
Definition
1. The percentage of carbon increases
2. The percentage of carbon decreases
Term
Stages in coal formation from lowest carbon content and rank to highest.
Definition
1. Peat (lowest)
2. Lignite
3. Bituminous coal (soft coal)
4. Anthracite (hard coal)
Term
What is the calorific value of anthracite?
Definition
15,400-16,000 Btu/lb
Term
What are some of the elements that are present in coal?
Definition
Carbon, Hydrogen, Oxygen, and Nitrogen
Term
Where do the elements in coal come from?
Definition
Some of the elements were contained in the original plants while others were incorporated during the carbonization process; the latter elements came from minerals deposited at the time of peat formation or from secondary minerals that crystallized by percolating through coal seams
Term
What is important when the environmental impact of coal burning is considered?
Definition
amount of sulfur and ash
Term
What is coal ash?
Definition
The solid residue that is left behind after burning
Term
How much coal ash can there be?
Definition
Can be more than, equal to, or less than the amount of mineral matter in the coal; most coal contains between 5% and 10% ash
Term
What is the basic molecular skeleton of coal?
Definition
Made up of various arrangements of the carbon six ring of aromatic hydrocarbons; the aromatic hydrocarbons may be fused with other rings to form discrete clusters
Term
In the chemical composition of coal, what is found in some of the rings (in place of carbon atoms) or between clusters?
Definition
nitrogen, sulfur, and various metals
Term
In the coal's chemical composition, what are the outer rings of the clusters bonded to?
Definition
Hydrogen atoms or other chemical groups
Term
What does the amount of sulfur in coal depend on?
Definition
The type of plants originally involved and the conditions under which carbonization proceeded
Term
What are the sulfur content ranges of coal?
Definition
less than 1% to about 7% by weight
Term
When does sulfur become a problem in coal?
Definition
When coal is burned
Term
What happens to sulfur during combustion?
Definition
Any sulfur in the coal is converted to gaseous sulfur oxides mainly sulfur dioxide and a small amount of sulfur trioxide
Term
What are sulfur dioxide and sulfur trioxide?
Definition
air pollutant gases that occur during coal combustion; excessive amounts are hazardous to both human health and plant life
Term
What are the 3 approaches to the problems of decreasing sulfur oxide emissions from the coal burning process?
Definition
1. Use only coal that has low sulfur content
2. Remove sulfur from high sulfur coal
3. Remove sulfur oxides after burning high sulfur coal from the exhaust gases before releasing them to the atmosphere
Term
What will coal burned in new power plants have to contain in regards to sulfur?
Definition
Less than .7% sulfur and have a high heat content to meet emission standards if no coal pretreatment or exhaust gas cleanup is used
Term
What is the sulfur standard for new large power plants (coal)?
Definition
0.6 pounds of sulfur for each million Btu of heat obtained
Term
Does the use of low-sulfur coal present a universal solution?
Definition
No
Term
What are the two basic approaches to the problem of sulfur?
Definition
1. Physical cleaning
2. chemical cleaning
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