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Effect of increased pressure on equilibrium (gas system) |
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Definition
Pressure increase is counteracted by decreasing number of gas particles in equilibrium. Thus, equilibrium shifts to the side with smallest number of moles of gas. |
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Effect of increased temperature on equilibrium |
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Equilibrium favours the endothermic reaction |
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In equilibrium reactions, enthalpy change refers to... |
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Addition of unreactive gases/catalyst does what to position of equilibrium? |
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If equilibrium constant is large, what does that say about position of equilibrium? |
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It means there is a large concentration of products compared to reactants so equilibrium favours the forward direction |
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products (to the power of n) ----------------------------- reactants (to the power of n) |
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Increase concentration of products does what to equilibrium? |
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Favours reverse direction |
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Increase concentration of reactants does what to equilibrium? |
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An acid is..... A base is...... |
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Acid: PROTON DONOR Base: PROTON ACCEPTER |
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A reaction where a proton is donated and accepted |
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Strong acids dissociate partially/fully? |
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Weak acids dissociate partially/fully? |
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Soluble bases that form OH- ions in solution |
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Acids and bases can/cannot conduct electricity? |
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CAN - they contain ions that are free to move |
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metal compound + hydrogen gas |
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metal compound + water + carbon dioxide gas |
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Hydrogen ions attach to water molecules to form |
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- conduct better b/c more ions in a given volume - lower pH b/c greater concentration of H3O+ ions - react faster and more vigorously than weak acids |
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- Has a greater tendency to accept protons than weak bases |
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high concentration of H3O+ ions |
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calculating pH of strong base |
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Definition
pH = -log [H3O+ concentration] only a strong base because it fully dissociates |
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Term
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Definition
[concentration of H3O+ ions] x [concentrations OH- ions] = 1 x10-14 |
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