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Inrto to Ocean Chem
exam 2
49
Chemistry
Undergraduate 3
11/02/2010

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Term
What can isotopes tell us?
Definition
Isotopes can provide clues
about the chemical/physical
state of the ocean in
times past
Term
why is Isotope labeling experiments useful?
Definition
because studying feeding habits and
tracing biological transformations.
Term
Mass spectrometry
Definition
How isotopes measured
Term
Heavy isotope tends to stay in the phase where it is most tightly bound
Definition
solid>liquid>vapor,
Term
Source and cycling of carbon
Definition
(δ13C)
Term
Trophic levels of food webs
Definition
(δ15N)
Term
Tracer of water mass source
Definition
(δD)
Term
Temperature of formation of CaCO3
Definition
(δ18O)
Term
Changes in sea level due to storage
of water on land (as ice)- Glacial
cycles
Definition
(δ18O)
Term
Bonds formed by the ________ isotope are more readily broken than bonds involving the ________ isotope
Definition
light, heavy
Term
The equilibrium fractionation of isotopes is always temperature dependent.
Definition
Oxygen isotopes in paleothermometry
Term
What is Rayleigh Distillation?
Definition
When water evaporates from the surface ocean
Term
the isotopic fractionation between the liquid the vapor becomes more pronounced and the remaining
vapor is very ________.
Definition
light
Term
A progressive enrichment in δ15N and
δ13C is also observed as you move up through trophic levels
Definition
Term
PARTICLES IN THE OCEAN:
Definition
Size distribution is a continuum, with the most particles at the smallest sizes.
Term
“Suspended” Particles
Definition
you can use Pumps, small particles (< 70 µm)
Term
“Sinking” Particles
Definition
Traps, collect bulk sinking material at different depths
Term
Carbon flux __________ with depth due to decomposition
Definition
decreases
Term
Mass flux peaked in March after the spring bloom and rapidly decreased with time. Summer fluxes were much lower
Definition
Time-Series Traps
Term
POC is what?
Definition
Percent of Organic Carbon
Term
what is the major control on the acidity of seawater?
Definition
Carbon dioxide
Term
Long-term trends...
Definition
are greater than the large seasonal
Term
How do we estimate the extent of anthropogenic CO2 in the ocean?
Definition
- Air-sea gas exchange (solubility pump)

- Photosynthesis, respiration & remineralization (soft-tissue pump)

- Formation & dissolution of particulate carbonate (carbonate pump)
Term
How do we estimate the extent of anthropogenic CO2 in the ocean using d13C ?
Definition
-the concentration of atmospheric CO2,
changes in the...
-the d13C of atmospheric CO2,
-the d13C value of DIC in the ocean.
Term
If CO2 dissolved in seawater without reacting, ~__% would remain in the atmosphere. Instead only ~ __% does.
Definition
70%, 55%
Term
Saturation state is ...
Definition
the thermodynamic condition of seawater that describes the degree of supersaturation or undersaturation with respect to the particular phase of the CaCO3 mineral
Term
What are Some carbonate organisms?
Definition
Coral, caccolithaphorids, foraminifer, etc.
Term
What are Coccolithophores?
Definition
Phytoplankton
Term
Coral calcification rates may be reduced by __% - __%
Definition
21%-40%
Term
What will decreasing pH do in the ocean?
Definition
ruin Coral reef habitats
Term
RAER =
Definition
Reasonably Achievable Emission Reductions
Term
Redfield ratio(modified RKR)
Definition
P : N : C = 1 : 16 : 106

138O2+(CH2O)106(NH3)16(H3PO4)-->16NO3-+106CO2+1PO4-3+H2O
Term
P=
Definition
1
Term
N=
Definition
16
Term
N=
Definition
16
Term
C=
Definition
106
Term
O=
Definition
138
Term
POC
Definition
Particulate organic carbon
Term
DOC
Definition
Dissolved organic carbon
Term
Alpha (a) decay -
Definition
Nucleus emits 4He nucleus: mass decreases by 4, atomic number decreases by 2
Term
Beta (b) decay -
Definition
Neutron converted to proton with emission of an electron: mass unchanged, atomic number increases by 1
Term
Gamma (g) decay -
Definition
Electromagnetic radiation emitted as nucleus falls into lower energy state: no change in mass, generally accompanies other decays
Term
Tritium-Helium Age
Definition
(~300 m)
Term
Most important acid:
Definition
CO2(aq) or H2CO3
Term
Most important base:
Definition
HCO3-
Term
Most important base:
Definition
HCO3-
Term
Arrhenius definition (traditional)
Definition
Acid: A substance that can produce H+ions
Bases: A substance that can produce OH-ions
Term
Brønsted–Lowry difinition
Definition
Acid: proton donor
Base: proton acceptor
Term
Lewis definition
Definition
Acid: (Lone electron pair acceptor)
Base: (Lone electron pair donor)
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