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Law of Conservation of Matter |
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Law of Definite Composition |
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1859 - Bunsen and Kirchhoff |
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1830 - Liebig, Wohler, Berzelius, Dumas |
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1874 - Van't Hoff and LeBel |
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Dissociation of Electrolytes |
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1931 - Pauling, Heitler, London, and Slater |
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Molecular Orbital (MO) Theory |
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1930 - Hund, Bloch, Mullikin, Huckel |
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Valence-Shell Electron-Pair Repulsion (VSEPR) Theory |
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Cobalt Ammonates Observed |
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Cobalt Ammonates Prepared |
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More Cobalt Ammonates Prepared |
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1851 - Genth, Claudet, Fremy |
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Chain Theory of Ammonates |
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First Definition of the Modern Element |
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Approximate Beginning of Modern Chemistry |
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Three Main Areas of Inorganic Chemistry Covered in the Text |
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Coordination Chemistry, Main Group Elements, Solid State Chemistry |
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Aristotle's Four Elements |
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Approximate Beginning of Inorganic Chemistry |
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Def: Coordination Compound |
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Central Metal Bonded to 2 or More Ligands |
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Molecule or Ion Bonded to Metal in Complex Ion |
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Number of Bonds to Central Metal |
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Ligands Attached Directly to Metal |
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A 0.1 M aqueous solution that has a half-life of greater than 1 minute. |
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A 0.1 M aqueous solution that has a half-life of less than 1 minute. |
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The attacking ligand reacts more quickly than leaving ligand. |
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The RDS is dependent on the attacking group. |
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Decreasing Order of Kinetic Trans-Directing Power: CN-, NH3, NO2-, I-, Cl-, H2O |
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CN- > NO2- > I- > Cl- > NH3 > H2O |
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Which is softer: F- or Br-? |
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Which is softer: CH3CH2- or OH-? |
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Which is harder: H+ or Ag+? |
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Which is harder: CH3Hg+ or CH3Li+? |
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