Term
How to balance a redox reaction |
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Definition
- Separate into ox and red half-reactions
- Mass balance
- Add oxygen by adding H2O
- Balance oxygen with H+
- Add electrons to balance charges on both sides
- Multiply both sides by opposite number of electrons
- Add half-reactions together
- IF IN BASIC SOLUTION- add OH- to neutralize H+ on both sides (so H2O will be on one side, OH- on the other)
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Term
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Definition
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Term
Bond Order (molecular orbital theory) |
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Definition
# electrons in bonding orb's - # electrons in antibonding
2 |
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Term
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Definition
HI, HBr, HCl, H2SO4, HNO3, HClO4 |
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Term
What makes a strong acid a strong acid? |
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Definition
Completely dissociates in aqueous solution |
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Term
Difference between strong acid/weak acid rxns and strong base/weak base rxns |
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Definition
Use a --> for strong acids/ bases because they dissociate/associate completely. Use <==> for weak acids and bases since they have an equilibrium |
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Term
Dissociation of HOAc in water |
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Definition
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Term
Spectator ions: cations and anions |
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Definition
Cations: Group I and IIA
Anions: Bases of strong acids |
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Term
strong bases (yield weak acids when you add a proton) |
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Definition
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Term
Acid strength: bond polarity |
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Definition
In H-X bonds, the more polar the bond is (more electronegative X is) then the stronger the acid
(F>O>N) |
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Term
Strength of acids: bond strength |
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Definition
Weaker bond --> better acid
as size increases, bond strength decreases, acid strength increases |
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Term
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Definition
More oxygens (higher oxidation state of Y in HO-Y), then stronger acid |
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Term
Acid strength: metal ions |
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Definition
Smaller the metal with the same charge, stronger acid
Co+3 is smaller than Fe+3, so stronger acid |
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Term
Acid strength: substituents |
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Definition
Electron withdrawing (electronegative (CF3)) are stronger acids |
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Term
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Definition
If there are too many big ligands on a base, then it will become less basic
This can compensate for base strengthening effects, such as addition of methyl groups (which donate electrons)
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Term
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Definition
Small with large positive charge ( mostly +3 or larger)
H+, Li+, Na+, K+, Be+2, Mg+2, Ba+2, Al+3, Me3Al, AlCl3, Cr+3, Mn+2, Fe+3, Co+3 |
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Term
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Definition
More electrons and larger size
I-, H2S, HS-, S-2, SCN-, CN-, CO, PR3, R3As |
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Term
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Definition
BH3, Cu+, Ag+, Au+, Pd+2, Pt+2, Pd+4 |
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Term
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Definition
F-, Cl-, H2O, OH-, O-2, NO3-, ClO4-, NH3, RHN2, N2H4 |
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Term
Bigger oxidation state:
Bigger size: |
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Definition
Bigger oxidation state: hard
Bigger size: soft |
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Term
Molecular Orbital Diagram |
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Definition
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