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GWS 410 midterm study guide
study guide
113
Chemistry
Undergraduate 4
10/25/2010

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Term
Acetaldehyde
Definition
CH3CHO The most important aldehyde in wine, and the toxic substance into which ethanol is converted in your liver.
Green apples, sour, metallic, flat, tired, maderized
Term
Ethyl Acetate
Definition
In wine, the result of acetic acid and ethanol resulting in a fingernail polish remover odor.
Term
Tyrene threshold
Definition
1.5-4ppb
Term
chemical contaminant
Definition
100% fault, lead, TCA,
Term
areas of the brain that hold odor patterns
Definition
Limbic and neocortex
Term
olfactory bulb
Definition
A multi cellular, multi-layered structure in the top of the nasal cavity that receives stimuli from the millions of olfactory receptor neurons filtering them through the intermediation of the Glomeruli and forwarding signals to the brain. There is a suggestion bidirectionality in the circuit – both sides of the snyapses are dendrites that can release neurotransmitters – allowing the brain to regulate sensitivity and discrimination of odors.
Term
Exteroreceptor
Definition
Relates to a sense organ, although it can be just a receptor on the tongue, that receives stimuli from outside the body
Term

perception threshold

Definition
concentration at which 50% of humans can detect an odor
Term
recognition threshold
Definition
concentration at which 50% of humans can identify an odor.
Term
Glomerulus
Definition
the basic unit in the odor map of the olfactory bulb. Each odor activates a different pattern of glomeruli, such that, simply by analyzing the different sets of activated glomeruli, one could, in theory, decode the identity of the odor.
Term
meaning of volatile
Definition
For our purposes, compounds that evaporate at normal temperature and pressure.
Term
Pyrazine
Definition
In wine, refers to a class of heterocylic aromatic compounds (Methoxypyrazine—A class of pyrazines usually having vegetable) (IBMP--(3-isobutyl-2-methoxypyrazine) The pyrazine associated with “Green Bell Pepper” odor. In slight amounts, not a fault.
Term
area (sq.cm.) of olfactory bulb
Definition
10 sq. cm. (4inch)
Term
function of saliva
Definition
Slightly alkaline, contains enzymes that break down foods, It also distributes the taste to all the tongue.
Term
Umami
Definition
(Japanese for savory or tasty) he taste of salts of glutamic acids or glutamates associated with MSG. not associated with wine tasting so far.
Term
types of receptors for sweet and bitter
Definition
Signaled through G protein-couple receptors
Term
types of receptors for sour and salty
Definition
Ion channels
Term
Diacetyl
Definition
Bi-product of mali-latic fermentation, gives wine a buttery taste
Term
afferent nerve
Definition
The means by which impulses are carried from sense receptors to the central nervous system.
Term
location on tongue where saltiness is sensed
Definition
Everywhere????
Term
fungiform papilla
Definition
Mushroom shaped taste buds that cover most of the tongue and sense the five tastes..
Term
function of mucus in nose
Definition
Contains enzymes that break down senses, Captured and sensed by fine collecting hairs of the olfactory lining.
Term
mouth feel
Definition
The effect of wine on the mechanoreceptors of the mouth.
Term
taste vs odor
Definition
Odor—The result of volatilized chemical compounds fitting into nasal receptor cells and stimulating the limbic system.
G protein-coupled receptors—Receptors in the tongue that signal to a nerve when bitter, sweet or savory is tasted.
Term
mechano-receptor
Definition
Mechanical stimuli receptors that sense touch, pressure, streaching and motion. As many as 100/cm.2 on the tongue.
Term
mechano-receptor
Definition
Mechanical stimuli receptors that sense touch, pressure, streaching and motion. As many as 100/cm.2 on the tongue.
Term
thermo-afferent receptor
Definition
A very aromatic class of hydrocarbons (derived from isoprenes) responsible for many of the odors we associate with Riesling, Gewurztraminer, Muscat and other flowery wines. When a terpene’s carbon chain is modified or oxidized, it is called a terpenoid (see Linalool and Norisoprenoid
Term
alkaline
Definition
Salt/Base
Term
Zygosaccharomyces bailli
Definition
Zygosaccharomyces is a genus of yeast in the family Saccharomycetaceae. It was first described under the Saccharomyces genus but in 1983 it was reclassified to its current name in the work by Barnett et al. The yeast has a long history as a spoilage yeast within the food industry. This is mainly because it is tolerant to many of the common food preservation methods. The biochemical properties it possesses to achieve this includes
high sugar tolerance (50-60%),
high ethanol tolerance (up to 18%),
high acetic acid tolerance (2.0-2.5%),
very high sorbic and benzoic acidtolerance (up to 800–1000 mg/L),
very high molecular SO2 tolerance
Term
casse
Definition
A haze caused by insoluble metal salts; iron and copper are the most common causes.
Term
anthocyanins
Definition
of many water-soluble red to violet plant pigments related to the flavonoids
Term
tannins
Definition
A polyphenol that imparts astringency to wine. They are reactive with proteins and various other organic compounds including amino alkaloids and amino acids.
Term
effect of pH on wine color
Definition
Think of it as the “power of the Hydrogen ion” in wine. (It is actually an approximation of the negative logarithmic scale of a molar concentration of Hydronium ions (H3O+).) Most important for winemaking is, while TA measures the concentration of acid in a wine, pH measures the “activity” or power of those acids. That power helps to keep wine sound. The lower the pH the higher the concentration of Hydronium ions. On pH’s 0-14 scale, water and blood at 7.0 are neutral. Wine, which runs from pH 4.0-3.0 is 1,000 to 10,000 times more acidic than water. Got that? The measurement of pH in soils is a different topic
Term
cross adaptation
Definition
Cross adaptation is a well-documented psychophysical phenomenon. In this context, one odorant may partially or fully block the perception of another odorant.
Specifically, a pleasant odorant may cross adapt and thus screen the sensation of a sweaty malodorant. It is highly probable that a specific mixture of odorants will perform this cross adaptation task for particular malodorants more effectively than others, providing a product such as Odor Screen a unique advantage
something that has been modified to suit different conditions or a different purpose
Term
Heterocyclic
.
Definition
Most comonly a benzene ring with at least one non-carbon element and at least one carbon (usually 4-5). But it can be a ring with three to eight atoms that are not all the same
Term
Pediococcus
Definition
A very common species of LAB that tends to produce high acetic acid. Also associated with “mousiness.”
Term
causes of hazes
Definition
Not all hazes are caused by adulterants:
Protein (proteinaceous) ((all + charges)) – more common in micro beers—These are caused in white wines by chitinase and thaumatin which clump into light-dispersing particles.
Phenolic hazes: yellow (and darker) hazes develop because
excessive use of oak chips or incoporation of MOG in must.
Metal haze
Reddish cast: in white wines
Term
flaw vs fault
Definition
Flaw:: Not overwhelimg; Fault:: Too much, overtakes the wine components
Term
fixed acids
Definition
In wine, the non-volatile acids such as malic, tartaric, succinic and citric acids. (Sometimes confusingly called organic acids.)
Term
Esters
Definition
Chemicals formed when alcohols and acids condense; they are often fragrant.
Term
Terpenes
Definition
A very aromatic class of hydrocarbons (derived from isoprenes) responsible for many of the odors we associate with Riesling, Gewurztraminer, Muscat and other flowery wines. When a terpene’s carbon chain is modified or oxidized, it is called a terpenoid (see Linalool and Norisoprenoid).
Term
phenols
Definition
A class of chemicals related to esters and alcohol (a hydroxyl group—OH) that bond to aromatic hydrocarbons. In wine they form the polyphenols (flavanoids, non-flavanoids, tannins etc.) and oak imparted eugenol, guaiacol and gallic acid..
Term
lactones
Definition
No, the result of esterification (see esters) in the grape or during fermentation. Some may be associated with certain grape varieties (similar in function to terpines). Others result from aging in wood: like the coconut odor of the cis isomer of ßmethyl-ץ-octolactone.
Term
OAV and how to figure it
Definition
Also called flavor activity; this measures how much an odorous compound will affect the bouquet of a solution;;; Recognition threshold; CONCENTRATION/THRESHOLD
Term
Benzene rings
Definition
The beautiful hexagon ring C6H6 with three double-bonds between carbons. Their most common representation in wine are the phenolics and tannins.
Term
number of identified volatile aroma compounds
Definition
over 100
Term
Furfural
Definition
An aromatic aldehyde (sweet, almond, bread) contributed to wine usually by oak aging.
Term
Vanillin
Definition
A nonflavonoid phenol in wine derived from oak aging.
Term
isoamyl
Definition
Isoamyl Alcohol—A higher alcohol (boiling point 131°C). See fusel alcohols.
Isoamyl acetate—Formed from the above and acetic acid, it has a fruity, banana odor.
Term
Ethyl Hexanoate
Definition
Ethyl decanoate and Ethyl hexanoate—two important esters found in chardonnay and thought to be scalped by plastic (bottles, fermenters, closures).
Term
high sugar as a problem
Definition
chances of 2ndary fermentation, Higher pH so it is more sustectiable to bacterias (brett), low fixed acids, overripe plumy flavors
Term
avoiding high Alcohol
Definition
blending, amelioration with water, pick at lower brix, remove it with spinning cones or cross flow filtration, or leaving RS in your wine (sweet wines)
Term
Glycerol
Definition
also glycerin/glycerine) after ethnanol and water, the most abundant substance in wine. A viscous (alcohol-like) polyol that is thought to give mouth feel and a sweetness to wines (although there is no evidence for this) glycerol’s qualities are varied, forming the backbone of triglycerides, a substitute for ethylene glycol and the basis of nitroglycerine.
Term
physiological ripeness
Definition
Color of seeds, how the grapes pull off pedestal, texture of skin
Term
amelioration
Definition
(to make something better), A way of avoiding High alcohol by adding water, can legally water down to 22 brix.
Term
glutathione
Definition
A tripeptide (containing three amino acids) that assists (along with the enzyme acetaldehyde dehydrogenase ) in reducing acetaldehyde to an acetate. Glutathione contributes the amino acid cysteine to the process.
can reverse the oxidation
The ratio of glutathione/Caftaric acid varies by variety
Riesling is lacking in glutathion
…so take out the caftaric acid… with O2
Term
dehydrogenase
Definition
Acetaldehyde dehydrogenase—a group of enzymes that help convert acetaldehyde into acetate in the liver.
Term
SO2 stands for??
Definition
i n wine as an antimicrobial/antioxidant agent. It binds with aldehydes and other constituents making wine more “stable.” As one of the sulfites its effectiveness is greater at a lower pH.
Term
amounts of acetaldehyde in sherry? red wine?
Definition
Sherry 90-500mg/L. Red Wine: 4-212mg/L
Term
Polyols
Definition
Higher alcohols (boil at higher temperature than ethanol) sometimes called sugar alcohols. See Glycerin
Term
fusel oils
Definition
Higher alcohols (more than two carbons) which include propanols, butanols, amyl alcohol, and although not an alcohol, furfural is often included in the group. They are common in the “tails” of distillation, whence the German name for “bad liquor.”
Term
formulae for ethanol, methanol & acetaldehyde
Definition
DRAW!!!
Term
esterfication
Definition
when acids, alcohols and
phenols mix to form smelly esters.
Term
hangtime
Definition
The amount of (extra) time grapes are left on the vine past normal (24 Brix) sugar accumulation (Nick Dokoozlian –Napa Valley Grape Growers –2004 symposium). This is thought to add different (better?) flavors to the wine that is produced.
Term
recognition threshold of acetaldehyde
Definition
100-125ppm
Term
organoleptic description of acetaldehyde
Definition
Organoleptic—Dealing with sensory analysis of wine through taste, smell and sight.
Green apples, sour, metallic, flat, tired, maderized
Term
cross-flow filteration
.
Definition
In wine, filter system in which the permeate (water, alcohol, acetic acid) can be eliminated. In the case of wine with high VA, the permeate is pumped through a + charged resin and returned to the wine
Term
spinning cones
Definition
A machine that takes alcohol out of wine using centrifugal force
Term
causes of acetaldehyde
Definition
To avoid oxidation and its effect, we add SO2
Problematic … want to reduce need for high additions of SO2.
Likely that the spoilage yeast Brettanomyces (usually aerobic) can use Acetaldehyde as site to reproduce anaerobically.
Acetaldehyde can bind to proteins and DNA potentially causing mutagenesis and carcinogenesis.
Term
hydrolysis
Definition
the effect of water (+NaOH) turning the esters back into an acids.
Term
Erythritol Aribitol Sorbitol Manitol
Definition
Higher alcohols (boil at higher temperature than ethanol) sometimes called sugar alcohols.
Erythritol—One of many non-fermentable sugars found in wine. It has 60-70% sweetness of sucrose and is non-caloric.
Manitol—A sugar alcohol (Polyol) that is a byproduct of MLF, especially if fructose was present. Contributes a viscous, sweet and irritating finish.
Sorbitol—A sugar alcohol that is minor in wine, but sometimes added to wine illegally
Term
heterocyclic compounds
Definition
Most comonly a benzene ring with at least one non-carbon element and at least one carbon (usually 4-5). But it can be a ring with three to eight atoms that are not all the same.
Term
Laccase
Definition
Laccase enzyme—Enters the grape with Botrytis Cineria infections and can cause problems, especially in red wine, during fermentation, causing red pigments to brown.
Term
Botrytis cineria
Definition
A necrotrophic fungus that grows on grapes which in the right conditions raises sugar (lowers water content) and in humid conditions, can ruin a crop with sour off-flavors.
Term
YAN level necessary for yeast growth
Definition
140mg/L
Term
MALB
Definition
Multicolored Asian Lady Beetle—( Harmonia axyridis) similar to the American “Lady Bug” was introduced to the Americas to control aphids.
Term
What is 3-isobytyl-2-methoxypyrazine (and its threshold)
Definition
bell pepper: in slight amounts not a fault
Term
Refractometer
Definition
Measures Brix
Term
fixed acid vs volatile acid
Definition
FIXED ACIDS: wine, the non-volatile acids such as malic, tartaric, succinic and citric acids
In wine, mostly acetic acid and sometimes small amounts of ethyl acetate which, if detected, are considered faults.
Term
how to sample grapes
Definition
1) visual and tactile assessment,
Berry color at attachment (pedicel) the last to develop color.
How easily does the berry come off the pedicel?
Squeeze berry: firm and elastic, or does it stay deformed?
(2) pulp-tasting,
Put several berries in mouth, crush on roof of mouth.
Is the pulp gelatinous (sticking to seeds) or “juicy?”
Is the fruit SWEET? SOUR? HERBACEOUS? FRUITY? (make a note)
3) skin-tasting.
Chew the skins 15 times (the same for all samples!)
Are the skins tough, or are they becoming mush?
Rub the chewed skins on the roof of your mount, then move them to between your upper lip and gum.
How does your tongue move along the roof of your mouth?
smoothly, or roughly?
Swallow or spit out the skins. Can you taste (feel) the tannins along your upper gums?
(4) seed-tasting.
How brown are the seeds? Green? Mottled? Dark?
Put seeds in your mouth and crunch.
Are they bitter, with green taste.? Crunchy, coffee taste?
Term
Poly-vinyl-poly-pyrrolidone
Definition
The cross linked version—Crospovidone—is used as a non-soluble fining agent that links to phenolic compounds that cause browning in white wine. It also “softens” red wine by removing tannins.
Term
Gelatin
Definition
A positively charged (in most wines) fining agent made of animal collagen (bones and skin).
Term
isinglass
Definition
A fining agent made from the airbladder of fish.
Term
isinglass
Definition
A fining agent made from the airbladder of fish.
Term
egg whites
Definition
Used as a gentle fining agent in wine.
Term
silicon dioxide
Definition
“ Kieselsol” is used as a colloidal fining agent.It can be manufactured with either charge.
Term
bulls blood
Definition
A fining agent but not used because of mad cow disease.
Term
Saturnine gout
Definition
Lead poisoning from wine enhanced with Sapa or Defrutum. The disease seemed to fit the character of the planet.
Term
THQ, LEAD, Copper, Zinc, Iron and Aluminum: how they get in wine?
Definition
THQ level--Target Hazard Quotients were developed by the U.S. Environmental Protection Agency to determine safe limit values of pollutants for long-term exposure to top soils at waste sites. The scale has also been used to determine the long-term health risk of eating fish containing heavy metals. Naughton and Petroczi (2008) applied the scale to wines. That the scale is a “dimensionless index of risk” (ibid.) and assumes continued exposure (ie: drinking the same metal-contaminated wine every day for the rest of your life) lessens its realistic value for wine fault studies.
Term
sapa or defratum
.
Definition
Grape juice boiled down to one-third its content and used to sweeten wine in early Rome. Defrutum was the juice reduced by 50%. Because the Romans preferred using lead pots to boil the juice (the lead seemed to sweeten it more) the suffered from Saturine gout
Term
diethylene glycol (DEG)
Definition
A toxic solvent that can impart a sweet taste if added to food or wine.
Term
pathways for methoxypyrazines
Definition
1st Viticultural : Vegetative growth – as leaves mature MP reduces, Soil moisture – extends leaf growth, no decrease of MP, Leaf maturity –ditto, Fruit exposure to light – increased sunlight to fruit, berry set to veraison mostly, Crop load and rate of fruit maturation, Uneven fruit ripening --Poor Fruit set, etc.
2nd Pathway: MOG (materials other than grapes) removal, Basal leaves contain three to five times IBMP that is found in the grape clusters., Stem separation, IBMP, are found in Cabernet Sauvignon stems (53%), seeds (31%), skins (15%), and flesh (1%), If destemmer is only 80% effective, need sorting table., Cap management, Cabernet Sauvignon, the skins contain about 72% of the fruit IBMP, and the seeds about 24% -- maybe delestage??!!, Microoxygenation, Seems to improve herbal flaw, but maybe as a result of removing Thiols., Thermovinification
Lady Beatle
Term
Polycarbonate
Definition
BPA: can disprut endocrine functioning
Term
what does HDPE stand for? PET? PP? PVC? LDPE? the advantages of each?
Definition
HDPE: high density poly eth… (does not diteriate chemical odors; used for fermentation).
PET: plastics used for water bottles, bag in a box. Make white wines oxidize faster, now coated with metallic fused polyester. Thinker but lighter material. Completely recyclable:: Polyethylene terephthalate) is a hard thermoformed polyester plastic used for wine bottles in some countries. Differing from the ubiquitous PET soft drink bottle, wine bottles must be lined with an O2 barrier to keep the wine from becoming oxidized.
PP: Polypropylene A thermoplastic that is not used much for fermentation or wine products (possibly grape lugs) heat resistant and great for sterilizing
PVC: polyvinyl chloride:: Contains chlorine, used for pipes, cheap. Desirable because it allows come o2 transfer
LDPE: LDPE-- Low density polyethylene. Low-density polyethylene (LDPE) is a thermoplastic made from petroleum.
Term
proteinaceous haze
Definition
Protein (proteinaceous) – more common in micro beers—These are caused in white wines by chitinase and thaumatin which clump into light-dispersing particles.
Term
phenolic haze
Definition
Phenolic hazes: yellow (and darker) hazes develop because excessive use of oak chips or incoporation of MOG in must.
Term
# taste cells in a taste bud?
Definition
50-100
Term
procymidone
Definition
Pesticide, often used to kill ferns or nettles: Bordeaux spray:: A carcinogen, developmental/reproductive toxin and an endocrine inhibitor
Term
somatosensory fibers
Definition
The somatosensory system carries general somatic sensory information to the central nervous system. For example, it carries pain or touch sensations from different parts of the body.
Spicy hotness: caused by ethanol
Term
factors affecting taste odor adaptation and odor fatigue
Definition
Odor adaption, adaption is slower if more than 1 odor, the detection threshold limits change, faster when high intensity odors are involved. Odor fatigue, happens occurs with total adaption with prolonged exposure
Age, illness and effects of medication, cultural background/state of mind, color perception, history of smoking
Adaption for repetition, the power of suggestion, environment/contextual
Term
Ageusia
Definition
loss of taste
Term
survival reasons for taste
Definition
Bitter: avoiding potentially toxic plant alkaloids
Sour: (bad milk)
Term
Quinine units
Definition
Bittering Units
Term
transmembrane proteins
Definition
1.admit ions (salty and sour)
2. bind to molecules that give rise to sour, sweet & umami.
Term
geraniol, linaloöl and nerol
Definition
Linalool—A terpenoid alcohol associated with Muscat and other flowery wines.
Geraniol- Unsaturated aliphatic alcohols
Term
Cis-rose oxide
Definition
having two atoms or groups on the same side of a double bond between carbon atoms
Rose oxide also contributes to the flavor of some fruits such as lychee andGewürztraminer.
Term
Trimethyldihydronaphthalene
Definition
-“petrol” (kerosene) smell associated with Riesling. It accumulates in bottle aging of good Rieslings. Considered a fault most places.
Term
secondary metabolites
Definition
Products of cell metabolism that are not essential to cell growth and reproductivity. Anthocyanins are an example.
Term
what does “phenolic” mean?
Definition
Several hundred affect taste, color, and mouthfeel of any wine. These come mostly from the skin of the grape, but can come from seeds and oak(if used). There are secondard metabolites, but the polyphenols associated with color (anthocyanins) probably serve to protect the grade from ultraviolet radiation, insects and fungus.
Non-flavonoids, such as resveratrol (the life-extending antioxidant)
Flavonoids, which include tannins, anthocyanins, flavonols, and catechings compounds from the grapes.
Most take form of benzene rings
Term
Ion channel
Definition
Taste receptors on the tongue that sense sour and saltiness
Term
Glutamates
Definition
salts created by glutamic acids which are associated with MSG
Term
most common pesticide residual found in wine?
Definition
Sulfur/ sterile inhibitors
Term
Dysgeusia
Definition
abnormal taste
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