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Group 4B: C, Si, and Pb
part of speciation and general behavior
25
Chemistry
Undergraduate 4
01/10/2017

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Term
the range of oxidation states of C
Definition
from IV to -IV
Term
some biomolecules that ca be found in soil
Definition
-monosacs, polysacs, and oligosacs
-amino acids, peptides, and proteins
-nucleic acids and antibiotics
-fats, waxes, lipids, phospholipids, and other lipids
-lignins, cutins, and suberins
Term
the products of decomposition of biomolecules
Definition
humic substances
Term
the humic substances
Definition
-humins
-humic acids
-fulvic acids
Term
the behavior of organic compounds and their interactions with other substances in the aqueous and solid phases are controlled by...
Definition
the type and abundance of polar or ionic functional groups and nonpolar structural components
Term
the valence state inorganic C is found in
Definition
CIV
Term
the carbon species in soil solutions that are not discernable from each other
Definition
-dissolved carbon dioxide (CO2 • H2O) -carbonic acid (H2CO3)
Term
the combined term that represents dissolved carbon dioxide (CO2 • H2O) and carbonic acid (H2CO3)
Definition
H2CO3*
Term
polyprotic acid
Definition
acid that can donate more than 1 proton to solution
Term
the particular species of any polyprotic acid, including those of inorganic carbon, in soil solution depends on...
Definition
pH
Term
the ligands of C that form stable stable aqueous complexes with numerous metal cations
Definition
-HCO3- -CO3-2
Term
the C species that's strongly adsorbed by Al and Fe oxyhydrides and clay minerals via ligand-exchange mechanisms
Definition
the HCO3- species
Term
the valence state of Si in soils
Definition
IV
Term
how Si exists in the mineral phase
Definition
as the silicate tetrahedron (SiO4-4
Term
how SiIV links to other metals
Definition
thru the oxygen atom
Term
does SiIV bond with other SiIV atoms?
Definition
no
Term
the dominant Si species in soil solutions
Definition
silicic acid (H4SiO4 or Si(OH)4)
Term
when silicic acid deprotenates
Definition
when pH > 9.86, forming Si(OH)3-
Term
how the concentration of silica in soil solutions is controlled
Definition
kinetically, by the dissolution of primary silicate minerals and the precipitation of secondary silicate minerals
Term
the oxidation Pb has in soil
Definition
II
Term
how Pb occurs in soils
Definition
-trace component of primary minerals
-for Ca in feldspars, pyroxenes, and phosphates
-Fe and Mn in oxyhydrides
Term
how Pb may occur in the soil solution
Definition
as free Pb2+ or as a hydrolysis product, depending on pH
Term
some things Pb2+ forms stable aqueous complexes with
Definition
-OH- -numerous inorganic ligands
Term
something organic in soils Pb=@ may be associated with
Definition
fulvates and other dissolved organic compounds
Term
how Pb is commonly found in soil
Definition
in an adsorbed phase, either exchangeable or strongly complexed by metal oxyhydroxides via proton exchange
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