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General Chemistry Ch. 1 - Atomic Structure
MCAT
28
Chemistry
Undergraduate 1
05/22/2016

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Term
What charge do protons have?
Definition
1.6 x 10-19 C per proton
Term
What is the single letter abbreviation for atomic number and what does atomic number represent?
Definition
Z and the number of protons
Term
What is the abbreviation for mass number?
Definition
'A' is the abbreviation
Term
isotopes
Definition
atoms that share an atomic number but have different mass numbers
Term
cation
Definition
positive ion
Term
anion
Definition
negative ion
Term
protium
Definition
hydrogen with one proton; mass of 1 amu
Term
deuterium
Definition
hydrogen with 1 proton and 1 neutron; mass of 2 amu
Term
tritium
Definition
hydrogen with one proton and two neutrons; mass of 3 amu
Term
Avogradro's number
Definition
6.02 x 1023; in on mole of an element there are that many atoms of that element
Term
What is the equation to determine the energy of a quantum?
Definition

E = hf

E is the energy of a quantum

H is Planck's constant 6.626 x 10-34 J·s

f is the frequency of the radiation

Term
What equation represents the possible values for the angular momentum of an electron orbiting a hydrogen nucleus?
Definition

L = nh/2π

 

L is angular momentum

n is the principal quantum number (any positive integer)

h is Planck's constant

 

 

Term
What equation describes the energy of a photon?
Definition

E = hc/λ

E is the energy

h is Planck's constant 6.626 x 10-34 J·s

c is the speed of light 3.00 x 108 m/s

Term
Heisenberg uncertainty principle
Definition
it is impossible to simultaneously determine, with perfect accuracy, the momentum and the position of an electron; if we want to assess position of an electron is has to stop thus throwing off momentum and vice versa
Term
Pauli exclusion principle
Definition
no two electrons in a given atom can possess the same set of four quantum numbers
Term
principal quantum number
Definition
denoted by n; any positive integer; higher n equals higher energy level and radius of electron's shell
Term
What is the maximum number of electrons within a shell?
Definition
2n2
Term
azimuthal quantum number
Definition
angular momentum quantum number; denoted by l (lowercase L); describes the shape and number of subshells within a principal energy level (shell); range for l is n-1
Term
What is spectroscopic notation?
Definition

Using a number for the principal quantum number and designated letters for the azimuthal quantum number

  • l = 0 is s
  • l = 1 is p
  • l = 2 is d
  • l = 3 is f
Term
magnetic quantum number
Definition
designated by ml; specifies the particular orbital within a subshell where an electron is most likely to be found; possible values are -l to +l
Term
spin quantum number
Definition
denoted by ms; describes an elecrons spin orientation within an orbital; two possible values of +1/2 and -1/2
Term
Aufbau principle
Definition
each subshell will fill completely before electrons begin to enter the next one
Term
How to do electron configuration for cations and anions
Definition
  • cations - remove electrons from the subshells with highest value for n first, the higher l is the tie breaker
  • anions - just add according to regular rules
Term
Hund's rule
Definition
states that within a given subshell orbitals are filled such that there are a maximum number of half filled orbitals with parallel spins
Term
Half-filled and fully filled orbitals have lower energies (higher stability) than other states. What are the two exceptions to this?
Definition

Chromium (and other elements in its group) and Copper (and other elements in its group)

  • Chromium should be 4s23d4 but is 4s13d5
  • Copper should be 4s23d9 but is 4s13d10
Term
Half-filled and fully filled orbitals have lower energies (higher stability) than other states. What are the two exceptions to this?
Definition

Chromium (and other elements in its group) and Copper (and other elements in its group)

  • Chromium should be 4s23d4 but is 4s13d5
  • Copper should be 4s23d9 but is 4s13d10
Term
paramagnetic
Definition
materials composed of atoms with unpaired electrons will be slightly attracted to magnetic field
Term
diamagnetic
Definition
materials of only paired electrons will be slightly repelled
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