Term
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Definition
HI HClO4 (Perchloric) HBr HCl H2SO4 (Sulfuric) HClO3 (Chloric) HNO3 (Nitric) |
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Term
Definition of a Strong Acid |
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Definition
- A substance that reacts essentially, completely with water to produce H3O+.
- The proton donating power of HA is greater than that of H3O+.
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Term
Definition of a Weak Acid |
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Definition
- A substance that is only partially deprotnated in water.
- The proton donating ability of HA is weaker than that of H3O+
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Term
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Definition
The observation that the stronger an acid/base is, the weaker it's conjugate base/acid will be. |
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Term
Definition of a Strong Base |
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Definition
- A substance that reacts essentially completely with water to produce OH- - it is completely protonated in water.
- The proton accepting power of A- is greater than that of OH-.
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Term
Lewis Acid-Base Definition |
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Definition
- Acid - Any species capable of donating an electron pair.
- Base - Any species capable of donating a pair of electrons.
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Term
Bronsted-Lowry Acid-Base Definition |
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Definition
- Acid - A proton donator.
- Base - A proton acceptor.
- Can be viewed as a special case of Lewis definiton
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Term
Arrhenius Acid-Base Definition |
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Definition
- Acid - A compund that produces H3O+ (hydronium) when dissolved in water.
- Base - A compound that produces OH- (hydroxide) in aqueous solution.
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Term
Definition of a Weak Base |
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Definition
- A substance that is only partially deprotonated in water.
- The proton accepting power of A- is less than that of OH-.
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Term
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Definition
- H3O+ is the strongest acid that can exist in water and OH- is the strongest base that can exist in water.
- An acid/base is strong if it is stronger than the conjugate acid/base of the solvent.
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Term
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Definition
- A buffer solution is any solution that maintains an approximately constant pH despite small additions of acid/base or dilution
- Typically, a buffer contains a weak acid and conjugate weak base in approximately equal concentrations
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Term
Henderson-Hasselbeck Equation |
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Definition
- pH = pKa - log10([HA]o/[A-]o)
- pOH = pKb - log10([A-]o/[HA]o)
- HA and A- represent conjugate acids and bases
- Equation may be applied towards buffers and the early stages of titrations
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Term
Definition of an Indicator |
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Definition
- Typically, a weak acid that has sharply different colors in its associated and dissociated states.
- When pH (of entire soln) = Kin, the concentrations of both states will be equal (both colors)
- When pH>Kin, [In-]>[HIn]
- When pH<Kin, [In-]<[HIn]
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Term
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Definition
- Point in a titration when the acid/base has been completely neutralized by the base/acid.
- CAVA=CBVB
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Term
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Definition
The point in a titration at which the color of the indicator changes. |
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Term
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Definition
- The point in a titration at which exactly half the acid/base has been neutralized by the base/acid.
- pH = pKa
- pOH = pKb
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Term
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Definition
- The pH of an amphiprotic salt solution is equal to the average of the pKa's of the salt and its conjugate acid.
- pH = 1/2(pKa1+pKa2)
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