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cannot exchange energy nor matter |
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can exchange energy but not matter |
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can exchange energy and matter |
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temperature remains constant |
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pressure remains constant |
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a measure of the average kinetic energy of the particles in a system |
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a specific form of energy which can leave or enter a system |
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equation for heat absorbed or released in a given process: |
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pressure, temperature, volume, enthalpy, entropy, free energy, and internal energy |
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25 degrees C 1 atm and 1 M concentrations |
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NOT equal to standard conditions! |
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0 degrees Celsius and 1 atm |
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change in enthalpy of a process is equal to |
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the heat absorbed or given off by the system |
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standard heat of formation: |
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deltaHf = enthalpy change if one mole of a compound were formed from its elements in their standard state |
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standard heat of formation for a element in its standard state is |
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standard heat of reaction |
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delta H rxn = sum of delta H products - sum of delta H reactants |
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enthalpies of reactions are additive |
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heat required to transform into a gas |
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also called bond dissociation energy; energy required to break a particular type of bond in one mole of gaseous molecules |
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the maximum amount of energy released by a process that is available to perform work |
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nonsponteanous at all temps |
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spontaneous at high temps |
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delta g knot of any element is |
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