Term
| Is delta H affected by temp? |
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Definition
| No, heat of transition (delta H) is not a function of temp and thus will not be effected |
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Term
| When can eq. constant be neg? |
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Definition
| Never, must always be pos. can't even be zero. |
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Term
| equation for eq. constant. |
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Definition
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Term
| value of equilib. constant when rxn favours, reactants, prods, or balance of both. |
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Definition
rxn favours reactants: Keq < 1
rxn balance reactants and prod: Keq =1
rxn favours prod: Keq > 1 |
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Term
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Definition
heat of transistion
measures amount of energy required to compelte transition |
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Term
Le Chatlier's Principle
for how changes in temp after exo and endo reactions. |
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Definition
| exothermic: increase temp: rxn shift left decrease temp: rxn shift right endo: increase temp, rxn shift right decrease temp: rxn shift left |
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Term
| formula for solubility product |
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Definition
for rxn: aA + bB = cC + dD
Ksp = [C]c[D]d
[A]a[B]b |
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Term
| Le Chatelier's Principle on how changes in volume affects gases |
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Definition
decrease volume: partial pressure increases: side with smaller moles of gas favoured
increase volume: partial pressure decreases: side with greater moles of gas favoured |
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Term
| Le Chatelier's common ion effect |
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Definition
| when the molar solubility of slightly soluble salt is decreased by the presence of another solute that supplies a common ion. |
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Term
| the electrochemical cell can be operated at atmospheric rather than high pressure because? |
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Definition
| electrical work serves to drive the reaction |
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Term
given the reaction:
N2(g) + H2(g) ↔ NH3(g)
if ammonia is continuously removed, the reaction is given forward based on whose principle? |
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Definition
Le Chaterlier's principle.
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