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Gases
chapter 10
25
Chemistry
12th Grade
10/27/2012

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Term
vapors
Definition
gaseous state of any substance that normally exists as a liquid or a solid
Term
pressure
Definition
a measure of the force exerted on a unit area. In chemistry, pressure if often expressed in units of atmospheres (atm) or torr: 760 torr = 1 atm; in SI units, pressure is expressed in pascals (Pa)
Term
pascals
Definition
the SI unit of pressure: 1 Pa = 1 N/(m^2)
Term
bar
Definition
a unit of pressure equal to 100 kPa
Term
standard atmospheric pressure
Definition
defined as 760 torr or, in SI units, 101.325 kPa
Term
atmosphere (atm)
Definition
a unit of pressure equal to 760 torr; 1 atm = 101.325 kPa
Term
torr
Definition
a unit of pressure (1 torr= 1 mm Hg)
Term
Boyle's law
Definition
a law stating that at constant temperature, the product of the volume and pressure of a given amount of gas is constant
Term
Charles's law
Definition
a law stating that at constant pressure, the volume of a given quantity of gas is proportional to absolute temperature (K)
Term
Avogadro's hypothesis
Definition
a statement that equal volumes of gases at the same temperature and pressure contain equal numbers of molecules
Term
Avogadro's law
Definition
a statement that the volume of a gas maintained at constant temperature and pressure is directly proportional to the number of moles of the gas
Term
ideal-gas equation
Definition
an equation of state for gases that embodies Boyle's law, Charles's law, and Avogadro's hypothesis in the form PV=nRT
Term
ideal gas
Definition
a hypothetical gas whose pressure, volume, and temperature behavior is completely described by the ideal-gas equation
Term
gas constant (R)
Definition
the constant of proportionality in the ideal-gas equation
Term
standard temperature and pressure (STP)
Definition
defined as 0* C and 1 atm pressure; frequently used as reference conditions for a gas
Term
partial pressures
Definition
the pressure exerted by a particular gas in a mixture
Term
Dalton's law of partial pressures
Definition
a law stating that the total pressure of a mixture of gases is the sum of the pressures that each gas would exert if it were present alone
Term
mole fraction
Definition
the ration of the number of moles of one component of a mixture to the total moles of all components; abbreviated X, with a subscript to identify the component
Term
kinetic-molecular theory of gases
Definition
a set of assumptions about the nature of gases. These assumptions, we translated into mathematical form, yield the ideal-gas equation
Term
root-mean-square (rms) speed
Definition
the square root of the average of the squared speeds of the gas molecules in a gas sample
Term
effusion
Definition
the escape of a gas through and orifice or a hole
Term
Graham's law
Definition
a law stating that the rate of effusion of a gas is inversely proportion to the square root of its molecular weight
Term
diffusion
Definition
the spreading of one substance through a space occupied by one or more other substances
Term
mean free path
Definition
the average distance traveled by a gas molecule between collisions
Term
van der Waals equation
Definition
an equation of state for nonideal gases that is based on adding corrections of the ideal-gas equation. The correction terms account for intermolecular forces of attraction and for the volumes occupied by the gas molecules themselves
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