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Force applied per given area. |
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standard temp and pressure Table A 237 K ~ 0 C 1 atm ~ 101.3 kPa 760 torr or 760 mmhg |
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kinetic molecular theory of gases |
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the gas molecules move in a continuous straight line w/ random movement. |
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there are no forces of attraction between molecules |
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molecules are so small they essentially have no volume. |
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collisions are elastic between gas molecules (elastic indicates no energy expanded) |
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there is a direct relationship between temperature and ave kinetic energy of a particle |
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which gases most resemble an ideal gas under most conditions: He |
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The lighter the gas, the more ideal it will act (therefore H2 and He act the most idea. |
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low volume low temperature low pressure |
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high volume high temperature high pressure |
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relationship between pressure and volume of gas at constant temp and number of particles. A increase in pressure causes a decrease in volume. |
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relationship between and volume of a gas At constant pressure and number of particles. An increase in temperature causes an increase in volume. |
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relationship between temp and pressure of gas. At constant volume and number of particles and an increase in pressure causes an increase of temperature. |
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By combining all the laws for an ideal gas, we can solve for all 3 variables (P1 X V1)/T1 = (P2 X V2)/T2 |
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1. Pressure that is exerted the container walls as collisions occur. 2. The greater the temperature the greater the vapor pressure |
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Temperature goes up pressure goes up |
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What is the boiling point of water? |
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100 C Mt Everest P525 torr 7 BP is lower because there are less air molecules applying pressure. Molecules vaporize more quickly. |
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If something is volatile does i have a low vapor pressure or a high vapor pressure? |
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High vapor pressure-it vaporizes quickly *unstable and volatile substance have high vapor point. |
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1. The point at which all the molecules have enough energy to change into vapor. 2. When the vapor pressure of the liquid equals or exceeds atmosphere pressure, the boiling occurs. |
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What is Avogadro's hypothesis? |
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Under the same conditions of temperature and pressure equal volumes of gasses contain the same number of particles. |
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unit number of particles 1. 1 mole of particles equals the formula mass of the substance express in grams 2. 1 mole refers to 6.02 x 10 (23) particles. |
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1 mole of any gas will occupy a volume of 22.4 liters @stp |
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Which does not have a molar volume of 22.4 liters? |
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Graham's Law of Diffusion |
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At a given temperature and pressure the great the density of the gas the slow the gas diffuses. Effusion is the process of a gas escaping through small pores/openings. This pollows the same principle. |
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What is the law of partial pressure? |
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The total pressure in a container is equal to the sum of all the partial pressures of the gasses in the container. |
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