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1. Articles used for food or drink for man or other animals 2. Chewing gum 3. articles used for components of any such article |
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Articles intended for use in the diagnosis, cure, mitigation, treatment or prevention of disease AND articles other than food intended to affect the structure or any function of the body |
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ability to form gels; gelling |
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ability to stabilize mixtures of oil and water |
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ability to immobilize water |
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ability to stabilize mixtures of gas and liquid |
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ability to encapsulate flavors, colors or nutrients |
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macro constituents of foods |
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water, lipids, carbohydrates, proteins |
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= (wet weight-dry weight)/wet weight |
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water's affects on the properties of foods |
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-susceptibility to microbial growth -rates of enzyme reactions -rates of non-enzymatic reactions -freezing properties -textural properties |
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water's interactions with solute molecules |
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ion-dipole dipole-dipole h-bonding |
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hydration shells (layers) |
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inner hydration shell - chemisorbed and ordered water outer hydration shell - cybotactic region, semi-ordered bulk water - random arrangment |
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solvated individual solute molecules\, i.e. NaCl -> Na+ + Cl- |
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dispersions of particles (clumps of solute in suspension |
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a physical property of a solution which varies as a function of the concentration of solute molecules in that solution
bp fp osmotic pressure vapor pressure |
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BP ( °C) = 100 °C + [ (+ 0.52 °C) X (molarity)] |
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FP ( °C) = 0 °C + [( - 1.86 °C) X (molarity)] |
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tendency of water to move across a semi-permeable membrane toward regions of lower water concentration |
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a quantitative measure of the amount of water that is -not tightly bound to the chemical constituents of a food -not in crystalline form -can easily evaporate from the food |
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relative proportions of free vs bound water
Aw = p/po i.e. equilibrium vp of the food over the equilibrium vp of pure water
Also expressed as Aw = equilibrium relative humidity%/100 |
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total amount of water in a food |
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viscous liquid, the result of the hydrolysis of sucrose into fuctose and glucose |
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3-5 monosaccharide units
ex. stachyose (4 monosaccharides) |
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calories of simple carbohydrates |
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functions of simple carbs |
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calorie sources sweeteners water adsorbents crystalline matrix foaming aids |
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physical formulations of simple carbohydrates |
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coarse crystalline sucrose fine crystalline sucrose concentrated solutions (syrups) |
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polymers of monosaccarides, almost entirely of plant origin (most components of plant cell walls)
All are resistant to digestion by enzymes in the small intestine |
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digestible complex carbohydrates |
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absorbed as mono and disaccharides significant sources of calories |
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non-digestible complex carbohydrates |
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i.e. fiber poorly digested partially fermented in the large intestine not a significant source of calories |
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linear polymer of glucose alpha-1-4 ether bonds 300-1200 glucose molecules per amylose molecule |
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degree of polymerization (DP - HAHAHAHAHA) |
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how many monosaccharides per larger molecule |
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branched polymer of glucose alpha 1-4 bonds AND alpha 1-6 bonds (branches) usually has a higher DP than amylose |
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in plant tissue, starch molecules are packaged in dense particles called granules. Potatoes have the largest |
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most starch amylose/amylopectin compostion |
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20-30% amylose 70-80% amylopectin |
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constituent amylose or amylopectin molecules are inter-mixed in concentric layers within the granules; gives a patterned effect of crystalline (darker) and amorphous (lighter) rings |
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thickening of aqueous solutions
process of absorption of water by starch granules when heated in water (60-90C) |
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a heated solution of hydrated and swollen starch granules |
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loss of viscosity caused by excessive heating or boiling |
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formation of a 3-dimensional, cross-linked network (h-bonds) of solubilized amylose molecules resulting from the cooling of a hot starch paste; starches consisting only of amylopectin will only thicken, not gel |
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alpha amylase - cleaves amylose and amylopectin into glucose and maltose (which can then be cleaved into 2 glucose molecules)
beta-amylase (found in plants) |
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cleaves 1-6 linkage in amylopectin |
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cold-water starches instant rice, potato producs |
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briefly cooked (pre-gelatinized) then spray dried |
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chemically modified starch |
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i.e. carboxymethyl starch
modification alters starch-starch interactions, gelling properties no effect on caloric content (only a small amount of glucoses altered)
thickener (water binding) |
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advantageous properties of all starches |
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colorless virtually tasteless odorless |
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hydrophilic substances that bind water; not true solubility but wettable and dispersible in water |
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pectins beta-glucans gums seaweed polysaccharides |
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found in most fruits, vegetables commercial sources: citrus peels, apple peels
has negative charge gelling agent thickeners (water binding) |
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polymers of glucose, with both beta 1-3 and beta 1-4 ether links
resistant to amylases, other digestive enzymes (because of the beta ether links) |
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xanthan gum, locust bean gums
common thickening ingredients (water binding) |
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polymer of sulfated galactose (has negative charge) short branches gelling agent thickening, binding agent |
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polymer of guluronic acid and mannuronic acid gelling agent |
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common insoluble dietary fibers |
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cellulose chemically modified celluloses hemicellulose lignin synthetic polysaccharides |
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coiled multi-polymer of glucose beta 1-4 bonds, resistant to amylose digestion
bulking agent (non-caloric) very high molecular weight; is polar but virtually insoluble in water because of its large size and coiled nature |
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polymer of xylose and arabinose |
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not a polysaccharide polymer of phenylpropane units |
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synthetic polysaccharides |
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not naturally occurring i.e. polydextrose, randomly polymerized glucose |
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functional properties of dietary fibers |
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gelling agents thickeners (water binding agents bulking agents |
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Effect of acid on pectins |
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removes negative charge, promotes hydrogen bonding between closely aligned pectin molecules which leads to gelling |
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effects of Ca++ on gel formation |
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the positive charge of calcium allows the binding of charged hydrocolloids together to form a gel. Calcium cross linkages make stronger gels |
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total CHO (carbohydrates) |
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Total CHO = [total weight of food] - [H20] - [protein] - [fat] - [minerals (ash)]
all five values determined directly |
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net CHO= [ Total CHO ] - [ Fiber ] |
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general functionalities of proteins in foods |
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sources of nutritionally essential amino acids and provides structure and texture to foods |
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monosodium glutamate, sodium salt of glutamic acid
flavor agent |
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causes of protein denaturation |
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heat changes in pH surface or interfacial tension mechanical shear |
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functional properties of proteins in foods |
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texturizing gelling surfactants (foaming/emulsifying agents) enzymes |
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