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FS 410 intro/water
Elements of water (activity, moisture content, etc)
41
Chemistry
Undergraduate 3
10/06/2010

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Term
Definition of food chemistry
Definition
the study of the physical and chemical properties of food constituents and their interactions during processing and storage of food.
Term
Major constituents
Definition

water

proteins

carbohydrates

lipids

 

Term
minor constituents
Definition

vitamins

minerals

pigments

Term
Other constituents
Definition

phenolics

flavanoids

alkaloids

terpenols

sulfur compounds

Term
types of reactions
Definition

non-enzymatic browning (maillard browning)

enzymatic browning

oxidation

hydrolysis

metal interactions

lipid isomerizatin

lipid polymerization

Term
where water is important
Definition

biological tissues

foods

Term
water and food
Definition

structure/texture

taste/appearance

stability

spoilage

heat transfer medium

Term
water and biological tissues
Definition

regulates body temperature

solvent for biological processes

carrier of nutrients and waste

reactant in hydrolysis

induces formation of structures

mediates enzyme activity

Term
number of anomalies of water
Definition
41!
Term
is it easy or hard to break bonds between water molecules
Definition
it is difficult to break one bond, but once one is broken it is easier to break more and more (same with formation)
Term
Thermal conductivity of ice VS. water
Definition
Thermal conductivity of ice is 4 times greater than water
Term
electrical conductivity of ice vs water
Definition
electrical conductivity of ice is lower than water
Term
diffusivity of water vs. ice
Definition
water is 9 times more diffusive than ice
Term
Cybotactic region
Definition
The region in the neighborhood of a solute in which the ordering of the solvent molecules is modified by the solute molecule
Term

The positive change in delta G results from a decrease in the entropy of the system.

Definition
This decrease is partly due to alteration in the orientation of water molecules in the hydration shell.
Term
Fugacity
Definition

the tendency of a molecule to escape from a solution

 

ie. water molecules to "escape" into water vapor

Term
plasticization
Definition
water seeps in and breaks the hydrogen bonds
Term
J-type isotherms
Definition
Foods NOT rich in polymeric materials exhibit these types of isotherms
Term

Foods rich in polymeric materials exhibit this type of isotherm

 

ie. proteins, and polysaccharides

Definition
sigmoidal-type isotherm
Term
No heat goes in or out of the system
Definition
Adiabatic system
Term
Importance of Aw in foods
Definition

  • Helps to predict the Moisture content of foods
  • Affects Chemical stability and shelf-life
  • influences physical stability
  • affects Microbial growth
  • helps in designing intermediate moisture foods
  • useful in designing packaging (moisture protection)

Term
Intermediate Moisture Food
Definition

where the food can be on the shelf and not go bad or have microbial growth occur.

 

Can get the right Aw but adjusting the pH, temperature, or adding preservatives

Term

Intermediate Moisture Foods 

 

Aw range

and how to reduce Aw

Definition

Range: .6-.8

 

Add solutes (sugar, salt, etc), use microbial agents to further lower Aw so that yeast and mold don't grow

Term
How to lower Aw
Definition

  • Increase conc. of hydrophilic solutes that bind to water
  • Decrease moisture content of foods/dehydration
  • Freeze Foods (Ice/glassy water not available to react)

Term
Reasons for Hysteresis
Definition

Collapse of capillaries and cellular structures during desorption

 

Possible phase change in the material

Term
Desorption
Definition
cause the release of an adsorbed substance from a surface
Term
Adsorption
Definition
hold molecules as a thin film on a surface
Term
desorption vs. resorption
Definition
If a food is more prone to phase transitions then resorption is preferable
Term
Foods undergo phase changes during storage (T or F)
Definition

True

 

Water activity can change and will change which can cause phase changes during storage

Term
Molecules display 3 types of motions
Definition

Vibrational

 

Rotational

 

Translational

Term
In the glassy state...
Definition

Molecular mobility is greatly reduced

 

therefore diffusion-limited processes become more stable

Term
As ice crystalizes out of a solution what happens to the %solute?
Definition
The percent solute will go down but the temperature of the solution will stay the same unless the solution is adiabatic.  If it is, the temperature will go up as the percent solute goes down
Term
Why does temperature go up when ice crystalizes?
Definition
Because the formation of ice releases heat
Term
Eutectic Point
Definition

Where maximum solubility is

 

Saturated solution, crystalline solute and crystalline solvent are all in equilibrium

 

also the lowest melting point of ice

Term
When T = Tg
Definition
isothermal melting causes 10^3 fold decrease in viscosity and the material becomes rubbery
Term
When T>Tg
Definition

Viscosity is decreased so much the material enters the glassy state

 

Free volume increases

Term
 low Viscocity = ???
Definition
Low viscosity = fast moving molecules
Term

All diffusion limited processes are very slow in the glassy state

 

(T or F)

Definition
True
Term
Plasticize
Definition
to make plastic or moldable
Term

Molecular entanglement can...

Definition

 Slow rates of water crystallization in frozen foods.
slow moisture migration in bakery foods/gel-type products.
These are related to polymer behavior in an entangled network and interaction of water molecules with the network.

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