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mass per unit volume [image] |
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force per unit area excerted by the molecules on a surface [image] |
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any change in the pressure applied to a completely enclosed, incompressible fluid is transmitted undiminished to all parts of the fluid and enclosing walls |
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any fluid applies a buoyant force to an object that is partially or completely immersed in it; magnitude of the buoyant force is equal to the weight of the fluid displaced by the object |
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-density does not change with pressure -most liquids are nearly incompressible for common pressure changes |
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-density changes with pressure -in most cases, gases must be treated as highly compressible fluids |
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velocity of fluid particles at any point is constant over time |
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velocity of fluid particles at any point changes as time passes |
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unsteady flow at high speed around obstacles |
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-fluid moves readily -neighboring layers of fluid slide freely past each other -ex: water |
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-fluid does not move readily -neighboring layers of fluid do not slide freely past each other -ex. oil, honey |
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-same speed at all points -paddle wheel won't turn -ex. pipe with low friction walls |
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incompressible and non-viscous |
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matter is made of of atoms that are in continual random motion -atoms exert electromagnetic forces on each other -forces are attractive at large distances, but repulsive at small distances |
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most substances expand when heated and contract when cooled [image] |
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transfers heat by the bulk movement of fluids |
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atom/molecules are so far apart that they don't interact except for when they collide elastically |
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measure of average KE of molecules |
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number of molecules present |
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amount of space occupied by the gas |
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Maxwell distribution of speeds |
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[image]KE = (³/₂)nRT = (³/₂)NkT |
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quantity of matter surrounded by boundaries |
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matter cannot cross boundary |
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matter can cross boundary |
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no heat, work, or matter crosses the boundary |
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changes the state of a system |
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-system changes rapidly -system cannot return along same path |
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-system changes slowly -system can return along same oath |
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series of processes that returns a system to its initial state |
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Term
first law of thermodynamics |
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Definition
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-different speeds at different points -paddle wheel test -ex. river |
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[image] [image] [image] [image] [image] |
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Term
isometric / isochoric heating |
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Definition
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Term
isometric / isochoric cooling |
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Definition
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Term
isometric / isochoric process |
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Definition
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adiabatic compression / heating |
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Definition
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adiabatic expansion / cooling |
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Definition
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second law of thermodynamics |
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Definition
-heat flows spontaneously from high temps to low temps, but does not flow spontaneously in reverse -"natural tendency" for heat to flow from hot to cold |
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ration of the net work done to the heat input [image] |
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most efficient possible heat engine consisting of 2 adiabatic and 2 isothermal processes [image] [image] |
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-measurement of molecular diversity of a system -able to measure energy no longer available to do work isothermal: [image] isobaric: [image] units: J/K |
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