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Final Exam
Chapters 1-11
59
Chemistry
Undergraduate 1
12/14/2013

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Term
JJ Thompson's cathode ray tube determined
Definition
electrons existed in atoms
Term
the gold foil experiment determined
Definition
that protons existed in atoms
Term
An experiment performed by Robert ----- in 1909 determined the size of the charge on an electron
Definition
milikan
Term
A
X
Z
Definition
A-mass number
Z-atomic number
X-element symbol
Term
Periodic table mass is the
weighted ----
of all of
the isotopes of each element
Definition
average
Term
according to the electromagnetic spectrum, visible light ranges from _____ (left end) to ____ (right end). What are the respective wavelengths of these two extremas?
Definition
violet 400 nm
red 700 nm
Term
produced by oscillating motion of electric charge
Definition
light/ radiant energy
Term
According to the Photoelectric effect and theory, quantity of e–
depends on
---- of light
Definition
intensity (brightness)
Term
According to the Photoelectric effect and theory, photons are only ejected if
Definition
light shined at or above minimum frequency on metal surface
Term
T/F: the atomic line spectrum is continuous
Definition
false
Term
as electrons absorb energy, they move to a ______, also known as the excited state
Definition
higher orbital
Term
as electrons fall back to a lower orbital, ____ is released as _____
Definition
light is released as energy
Term
when nf > ni
Definition
E > 0
Term
when ni > nf
Definition
E < 0
Term
For sig figs and problems that involve multiple calculations with only division or multiplication...
Definition
round at the very end
Term
For sig figs and problems that involve multiple calculations with addition/subtraction AND multiplication/division...
Definition
sig figs are defined at EACH step
Term
1 Å is equivalent to
Definition
1 x 10^-10 meters
Term
the principle quantum number (n) is proportional to
Definition
the average distance
of the e-
from the nucleus
Term
Angular Momentum Quantum Number (l) describes
Definition
the shape of the orbital
Term
what letters corresponds to each of the principle quantum numbers: 0, 1, 2, 3
Definition
s, p, d, f
Term
Magnetic Quantum Number (ml)
Definition
describes orientation of the orbital
Term
• All orbitals in a subshell have --- energy
Definition
same
Term
Electron Spin Quantum Number (ms)
Definition
orientation of electron
Term
Pauli Exclusion Principle states that
Definition
Each orbital can only have 2 e-

e- in same orbital have opposite spin
Term
in
1s2 2s2 2p6 3s2 3p3 electron configuration of phosphorus, which are the core electrons vs valence electrons
Definition
core: 1s2 2s2 2p6
valence: 3s2 3p3
Term
special cases in which the electron configuration of certain elements (in the d-orbital range) do not follow the trend arises from what fact regarding d-orbitals?
Definition
½ filled or completely filled d orbital is more stable
Term
aufbau principle
Definition
electrons fill from lowest to highest energy
Term
Hund's Rule
Definition
most stable orbital is where you try to get all orbitals to have same e- spin
Term
to find the debroglie wavelength...
Definition
divide planck's constant by the product of mass and velocity
Term
the element P has the ions P- and P+, place them in order of smallest ionic radius to largest
Definition
P+, P, P-
Term
Amount of energy required to completely convert
one mole of a solid ionic compound to the
constituent ions in the gas phase
Definition
lattice energy
Term
____ bonding Gives each atom a noble gas configuration
Definition
covalent
Term
what is the difference between pure covalent and polar covalent? ionic?
Definition
pure- electrons are equally shared
polar- unequally shared
ionic- opposite charges
Term
ability of an atom in a
compound to attract electrons to itself
Definition
electronegativity
Term
List the type of bonding that occurs in the respective electronegativity differences

<0.5
0.52.0
>2.0
Definition
nonpolar covalent
polar covalent
ionic
Term
when drawing lewis structures, we have to consider that ____(element) only forms two bonds and _____(element) can only form 3
Definition
Beryllium
boron
Term
three rules of naming covalent compounds
Definition
1 add prefixes for both element
2 drop mono for first element
3 add -ide suffice to second element
Term
three rules of naming ionic compounds whose cation has 1 charge
Definition
1 write metal
2 add -ide if monoatomic anion
3 write name for polyatomic anion
Term
four rules of naming ionic compounds whose cation has multiple charges
Definition
1 write metal
2 specify charge with roman numerals
3 add -ide if monoatomic anion
4 write name for polyatomic anion
Term
go over common polyatomic ion names
Definition
Term
formula for ethanol
Definition
C2H4O
Term
naming acids
Definition
anion ends in -ate, add -ic
anion ends in -ite, add -ous
Term
what molecules have a SPECIFIC number of
waters in their structure?
what indicates the number of water molecules in the compound
Definition
hydrates
prefixes
Term
what type of acid has only one hydrogen
Definition
binary acids
e.g. hydrochloric acid HCL
Term
Contain carbon and
hydrogen
Definition
organic compounds
Term
Covalently bonded to form a single ion
Definition
polyatomic ions
Term
Metals lose electrons from the ____ shell
Definition
largest
Term
how to determine the polarity of a molecule? Check what two things?
Definition
lone pairs and polar bonds. what are polar bonds?
Term
In VB theory, a single bond is represented by
Definition
1 sigma bond
Term
In VB theory, a double bond is represented by
Definition
1 sigma bond and 1 pi bond
Term
In VB theory, a triple bond is represented by
Definition
1 sigma bond and 2 pi bonds
Term
Carbon always
has a complete
octet (put in
---
where
necessary)
Definition
hydrogens
Term
In organic molecules, what element symbol is usually not written?
Definition
carbon/ Carbon-Hydrogen bond
Term
Hydrogen phosphate is?
Definition
HPO4 ^ -2
Term
Draw sulfite ion, what should you take into consideration? How many resonance structures does it have?
Definition
3
Term
To find ideal bond angles, look at electron domain geometry chart or molecular geometry chart?
Definition
based on electron domain geometry
Term
hepta
Definition
7
Term
_________________________________________________
24. What is the name of the compound formed when HI is dissolved in water?
Definition
hydroiodic acid
Term
_____________________________________________________
27. Resonance structures differ by:
Definition
. placement of electrons only
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