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exam 2 chem 1230
chem
61
Chemistry
Undergraduate 2
08/03/2016

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Cards

Term
when does a precipitate form?
Definition
when the attractive forces between ions are large
Term
what are the exceptions for I, Cl, and Br?
Definition
Ag, Hg, Pb, Cu, Ti
Term
what are the exceptions for SO4?
Definition
Ca, Sr, Ba, Pb
Term
what are always soluble?
Definition
NH4, group 1A, NO3, ClO4, Clo3, C2H3O2
Term
solution
Definition
homogenous mixture of 2+ substances
Term
solvent
Definition
major proportion
Term
solute
Definition
minor proportion
Term
colligative properties
Definition
affected by concentration of particle the solute contirbutes to the solution
Term
what are examples of colligative properties?
Definition

osmotic pressure

vapor pressure lowering

boiling point elevation

freezing point depression

 

Term
colligative molality
Definition
change in freezing point or boiling point of a solvent when solute is added
Term
what is the equation for colligative molality? (Mc)
Definition
Mc = i x m
Term
how do you find molality and what are the units?
Definition
moles of solute / kg of solvent
Term
what is i?
Definition
vant hoff factor; # of particles produced when a solute dissolves
Term
what is the equation for delta T?
Definition
delta T = Kf * Mc
Term
what is Kf?
Definition
the freezing point depression constant of solvent
Term
what are the properties of lauryl acid?
Definition
non hazardous but prolonged contact may cause skin irritation
Term
what equipment is used in experiemnt 8?
Definition

crystallization dish

graduated cylinder

beaker

thermometer

tongs

spatula

hot plate

Term
when is equilibrium established?
Definition
when the rates of the forward and reverse reactions are equal
Term
what are the properties of HCl?
Definition
corrosive, irritant, use fume hood, injures eyes and skin
Term
what are the properties of AgNO3?
Definition
dark spots
Term
what is the effect of raising temperature with respect to Le Chateliers principle?
Definition
equilibirum shifts to the higher energy side
Term
what are the reactions studied in experiment 9?
Definition

CoCl4^2- + 6 H2O -> Co(H2O)6^2+ + 4 Cl^-

Fe^3+ + SCN^- -> FeSCN^2+

Term
when are reactants favored? products?
Definition

when K is low

when K is high

Term
what are titrations?
Definition
stoichiometric volume of one reactant of known concentration (titrant) is required to react with another reactant of unknown concentration (analyte)
Term
how is the concentration of the analyte determined?
Definition
from the concentration of the titrant and stoichiometry of reaction between them
Term
what is in the buret?
Definition
titrant
Term
what is in the flask?
Definition
analyte
Term
what is in indicator
Definition
a substance that changes color near the equivalence point
Term
how is an indicator chosen?
Definition
when the equivalence point is near the end point
Term
what is the endpoint?
Definition
point at which the color change occurs
Term
what should you consider when setting up a titration?
Definition

buret measured to nearest .01 mL

make sure no air bubbles in buret tip

condition buret

fill buret below 0 mark

close stopcock

Term
what happens if you dont condition the buret?
Definition

the volume of titrant will increase

the moles of analyte will be overestimated

Term
what happens if you condition the flask with analyte?
Definition

increase in volume of titrant

overestimation of moles of analyte

Term
mass %
Definition
moles of acid / moles of base x 100
Term
how do u go from moles to mmol
Definition
1 mol = 1000 mmol
Term
what is the difference when doing conjugates?
Definition
a H+
Term
conjugate base of an acid
Definition
remove an H+
Term
conjugate acid of a base
Definition
add H+ to base
Term
what subsances are corrosive?
Definition

acetic

Nh3

Hcl

Naoh

Term
what substances are irritants?
Definition

acetic

NH3

HC;

Term
how do u find [H3O+] given pH?
Definition
H+ = 10^-pH
Term
how do u find pH given [H+]
Definition
pH = log[H+]
Term
enthalpy
Definition
amount of heat energy absorbed at constant pressure
Term
entropy
Definition
number of ways energy can be distributed in a system
Term
system
Definition
part of universe being studied
Term
surroundings
Definition
part of universe that interacts with system being studied
Term
spontaneous
Definition
lowers energy of system
Term
nonspontaneous
Definition
amount of energy supplied to cause process to occur
Term
heat of reaction
Definition
when reactants react completley at STP
Term
electrodes
Definition
metal strips
Term
cathode
Definition
reduction
Term
anode
Definition
oxidation
Term
saltbridge
Definition
allows ions to travel from one 1/2 cell to other
Term
voltmeter
Definition
calculates potential difference between oxidizing and reducing agents (mV -> V)
Term
how do you find Ecell
Definition
Ecell = Ecathode - Eanode
Term
if H < 0 and S > 0
Definition
spontaneous
Term
if H > 0 and S < 0
Definition
non spontaneous
Term
H < 0
Definition
exo
Term
H > 0
Definition
endo
Term
S < 0
Definition
spontaneous
Term
G > 0
Definition
nonspontaneous
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