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Exam 2
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100
Chemistry
Undergraduate 1
03/11/2013

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Cards

Term
What becomes a source of energy?
Definition
Heat
Term
Heat is the source of what?
Definition
Energy
Term
What do we use to supply the energy we need?
Definition
Chemical reactions.
Term
What do chemical reactions supply?
Definition
Energy
Term
What is 1 cal?
Definition
The amount of heat needed to raise the temperature of 1 g of water by 1C
Term
What is the amount of heat needed to raise the temperature of 1 g of water by 1C?
Definition
1 cal
Term
Exothermic reactions...?
Definition
Produce heat.
Term
Endothermic reactions...?
Definition
Absorb heat energy from surroundings.
Term
What type of reaction absorbs heat energy from surroundings?
Definition
Endothermic.
Term
What type of reaction produces heat?
Definition
Exothermic.
Term
Carbohydrates provide...?
Definition
4 kcal/g (4 Cal/g)
Term
Proteins provide...?
Definition
4 kcal/g (4 Cal/g)
Term
Fats provide...?
Definition
9 kcal/g (9 Cal/g)
Term
What is the rate of a reaction?
Definition
The amount of products formed from reactants in a given period of time.
Term
What is the collision theory?
Definition
Views the rate of a reaction as the result of particles colliding with certain frequency and minimum energy.
Term
Views the rate of a reaction as the result of particles colliding with certain frequency and minimum energy.
Definition
Collision theory
Term
What must reactants do for a reaction to occur?
Definition
Must collide, collide with proper orientation, and collide with sufficient energy.
Term
In an exothermic reaction who has the lower energy?
Definition
Products are lower energy than the reactants.
Term
in an endothermic reaction who has the lower energy?
Definition
In an endothermic reaction the reactants are lower energy than products.
Term
What are factors that affect reaction rates?
Definition
Concentration, temperature, or presence of a catalyst.
Term
What effect does concentration have on reaction rates.
Definition
More reactants = more collisions.
Term
What effect does temperature have on reaction rates?
Definition
Higher speeds = more collisions.
Term
What does the coefficient in a reaction equation stand for?
Definition
The number of molecultes (mols)
Term
Define equilibrium.
Definition
The rate of the reactants to products is the same as the rate of products to reactants.
Term
What is the equilibrium constant?
Definition
K = (products)/(reactants)
Term
K = (products)/(reactants)
Definition
Equilibrium constant
Term
Preferred bonding pattern for H.
Definition
H-
Term
Preferred bonding patterns for C
Definition
l
-C-
l

>C=

=C=

-C(tri)C-
Term
Preferred bonding patterns for N
Definition
..
-N -
l

..
- N -
l

:N(tri)
Term
Preferred bonding patterns for O
Definition
..
-O -
''

..
O =
''
Term
Preferred bonding patterns for S
Definition
..
- S-
''
Term
What is the VSEPR Theory?
Definition
Electron charge clouds will arrange themselves to be as far away from each other as possible.
Term
What is electronegativity?
Definition
The ability of an atom to attract bonding electrons of a covalent bond to itself.
Term
0 < 0.4 electronegativity
Definition
Nonpolar
Term
Nonpolar bond in electronegativity
Definition
0 < 0.4
Term
0.4 >
Definition
Polar
Term
Polar bond in electronegativity
Definition
0.4 >
Term
if the central atom has one or more pairs of nonbonding electrons, the molecule is...?
Definition
Polar.
Term
If the central atom has no nonbonding pairs of electrons and all other atoms connected to the central atom are identical, the molecule is...?
Definition
Nonpolar.
Term
If the central atom has no nonbonding pairs of electrons and at least one of the atoms connected to the central atom is different from the others, the molecule is...?
Definition
Polar.
Term
Chromium ions
Definition
Cr(2+ or 3+)
Term
Manganese ions
Definition
Mn 2+
Term
Iron ions
Definition
Fe 2+ or 3+
Term
Nickel ions
Definition
Ni 2+
Term
Copper ions
Definition
Cu 1+ or 2+
Term
Zinc ions
Definition
Zn 2+
Term
A combination reaction is?
Definition
Elements or simple compounds that react to make a more complicated compound.
Term
Elements or simple compounds that react to make a more complicated compound.
Definition
Combination reaction
Term
Reactant is split into simpler compounds.
Definition
Decomposition.
Term
A reaction with oxygen
Definition
Combustion.
Term
Decomposition
Definition
Reactant is split into simpler compounds.
Term
Combustion
Definition
A reaction with oxygen.
Term
Single Replacement reaction
Definition
One atom replaces another atom in a second compound (cation with cation).
Term
One atom replaces another atom in a second compound (cation with cation).
Definition
Single replacement reaction
Term
What are the diatomic elements?
Definition
H2, N2, F2, O2, I2, Cl2, Br2
Term
Double Replacement reaciton
Definition
Positive ions switch places when two ionic compounds react.
Term
Positive ions switch places when two ionic compounds react.
Definition
Double Replacement.
Term
What do saturated hydrocarbons contain?
Definition
Only carbon-carbon single bonds.
Term
Simple organic compound names.
Definition
Meth, eth, prop, but, pent, hex, hept, oct, non, dec.
Term
What are structural isomers?
Definition
Compounds with same molecular formula, but different connectivity.
Term
Compounds with same molecular formula but different connectivity.
Definition
Structural isomer.
Term
Stereoisomers are...?
Definition
Compounds which differ from each other by their arrange of atoms in space.
Term
Compounds which differ from each other by their arrange of atoms in space.
Definition
Stereoisomers.
Term
What are responsible for the spearmint and caraway seed flavor?
Definition
A pair of stereoisomerrs called carvones that are taste buds can distinguish between them
Term
Difference between spearmint and caraway is...
Definition
The stereoisomers are identical except for the arrangement of groups in space.
Term
Enantiomers are...
Definition
Mirror images, but cannot be simply flipped because of 3-dimensionality.
Term
Mirror images, but cannot be simply flipped because of 3-dimensionality.
Definition
Enantiomers.
Term
What is a chiral center?
Definition
A tetrahedral carbon bonded to four different atoms or groups of atoms. Molecules with a chiral center form mirror images that are nonsuperimposable.
Term
What are intermolecular forces?
Definition
The attractive forces between molecules.
Term
What are the attractive forces between molecules called?
Definition
Intermolecular forces.
Term
What is weaker: intermolecular forces or covalent bonds?
Definition
Intermolecular forces.
Term
What is the weakest of the forces?
Definition
London (dispersion forces)
Term
When do london forces occur?
Definition
Momentarily in all molecules when electrons become unevenly distributed over a molecule's surface.
Term
What is created in london forces?
Definition
An induced dipole.
Term
Where are london forces significant in?
Definition
Nonpolar molecules.
Term
When is a permanent dipole created?
Definition
Only in polar molecules.
Term
What must be always done in when comparing intermolecular forces?
Definition
Comparing molecules of similar molecular weight.
Term
When do dipole-dipole attractions occur?
Definition
Between the dipoles of two polar molecules.
Term
What is hydrogen bonding?
Definition
Interaction between two molecules, a donor and an acceptor.
Term
What is the hydrogen donor?
Definition
A molecule with a hydrogen atom covalently bonded to an O, N or F
Term
What is the hydrogen acceptor?
Definition
A molecule with a nonbonding pair of electrons on an O, N or F
Term
A molecule with a nonbonding pair of electrons on an O, N or F
Definition
Hydrogen acceptor
Term
A molecule with a hydrogen atom covalently bonded to an O, N or F
Definition
Hydrogen donor
Term
What is the strongest of the intermolecular forces?
Definition
Hydrogen bonding.
Term
When is something soluble?
Definition
Like dissolves like, soluble if the molecules can bond.
Term
What is the golden rule of solubility?
Definition
Molecules that have similar polarity and participate in the same types of intermolecular forces will dissolve each other.
Term
Molecules that have similar polarity and participate in the same types of intermolecular forces will dissolve each other.
Definition
What is the golden rule of solubility?
Term
Can there be cis-trans in single bonds?
Definition
No.
Term
What can have cis-trans?
Definition
Ring structures and double bonds.
Term
AB2
Definition
Linear
Term
Linear
Definition
AB2
Term
AB3
Definition
Trigonal planar
Term
Ab2N
Definition
Bent
Term
Bent
Definition
Ab2N
Term
Trigonal planar
Definition
AB3
Term
Ab4
Definition
Tetrahedral
Term
Tetrahedral
Definition
Ab4
Term
Ab3N
Definition
Pyramidal
Term
Pyramidal
Definition
Ab3N
Term
Ab2N2
Definition
Bent
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